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Polarographic determination of benzotriazoles and their sorption behavior on granular activated carbon

  • A. N. AbabnehEmail author
  • M. A. Abu-Dalo
  • C. Horn
  • M. T. Hernandez
Original Paper
  • 29 Downloads

Abstract

Because of their persistence and unknown environmental risks, the widespread occurrence of benzotriazoles has been gaining increased attention. A highly selective, rapid, and economical method—differential pulse polarography—was developed and applied for the quantitation of commercially significant methylbenzotriazole isomers in environmental samples of relevance to wastewater treatment, non-point source pollution and acid mine drainage. Differential pulse polarography was able to accurately measure aqueous methylbenzotriazole, as well as the methylbenzotriazole fraction that sorbed to activated sludge biomass, subsurface sediments, and activated carbon. Granular activated carbons were characterized for their ability to sequester benzotriazoles from aqueous environments using differential pulse polarography and high-performance liquid chromatography. Langmuir, Freundlich, Toth and Redlich–Peterson isotherm models were compared for their ability to describe benzotriazole partitioning to granular activated carbons under a relatively wide range of water quality conditions. Sorption behavior of 5-methylbenzotriazole was best-described by a Redlich–Peterson isotherm model, where water quality parameters were varied in the following range pH (1 < pH < 5), temperature (5 °C < T < 25 °C), and in the following ranges of an ionic strength (0.005 < M < 0.02). 4- and 5-methylbenzotriazole concentrations determined by differential pulse polarography correlated well with those concentrations measured by high-performance liquid chromatography through an environmentally significant range (0.4–30 mg/L). Using a static mercury drop electrode, the method detection limit was 50 and 40 μg/L for 4- and 5-methylbenzotriazole, respectively. The developed DPP polarographic method was found to be simple, rapid, and it can be applied directly to environmental samples without filtration, extraction, and centrifugation.

Keywords

Benzotriazole Polarography Corrosion inhibitors Sorption 

Notes

Acknowledgements

This experimental work was supported in part by a career award to the fourth author from the United States National Science Foundation (NSF). The Award Number is 9702165.

References

  1. Abu-Dalo M (2003) Electrochemical characterization of benzotriazole derivatives and their behaviour in industrial waste treatment (Ph.D. thesis). Department of Civil, Environmental and Architectural Engineering, University of Colorado, BoulderGoogle Scholar
  2. Abu-Dalo MA, O’Brien I, Hernandez M (2018) Effects of substitutions on the biodegradation potential of benzotriazole derivatives. Mater Sci Eng 305:012020Google Scholar
  3. Alexander M (1973) Nonbiodegrable and other recalcitrant molecules. Biotechnol Bioeng 15:611–647CrossRefGoogle Scholar
  4. Allen SJ, Gan Q, Matthews R (2003) Comparison of optimized isotherm models for basic dye adsorption by kudzu, P.A. Johnson. Biores Technol 88:143–151CrossRefGoogle Scholar
  5. Alotaibi MD, Patterson BM, McKinley AJ, Reeder AY, Furness AJ, Donn MJ (2015) Fate of benzotriazole and 5-methylbenzotriazole in recycled water recharged into an anaerobic aquifer: column studies. Water Res 70:184–195CrossRefGoogle Scholar
  6. American Public Health Association, American Water Works Association (1995) Standard methods for the examination of water and wastewater. American Public Health Association, WashingtonGoogle Scholar
  7. Cancilla DA, Martinez J, Aggelen GCV (1998) Detection of aircraft deicing/anti-icing fluid additives in a perched water monitoring well at an international airport. Environ Sci Technol 32:3834–3835CrossRefGoogle Scholar
  8. Chern M, Chien YW (2002) Adsorption of nitrophenol onto activated carbon beds: isotherms and breakthrough curves. Water Res 36:647–655CrossRefGoogle Scholar
  9. Coburn C, Hudgens R, Mullen M (1999). Environmental effects of engine coolant additives. SAE technical paper 1999-01-0137.  https://doi.org/10.4271/1999-01-0137
  10. Cornell J, Pillard DA, Hernandez M (2000) Comparative measures of the toxicity of component chemicals in aircraft deicing fluid. Environ Toxicol Chem 19(6):1465–1472CrossRefGoogle Scholar
  11. Corsi SR, Geis SW, Loyo-Rosales JE, Rice CP (2006) Aquatic toxicity of nine aircraft deicer and anti-icer formulations and relative toxicity of additive package ingredients alkylphenol ethoxylates, and 4,5-methyl-1H-benzotriazoles. Environ Sci Technol 40(23):7409–7415CrossRefGoogle Scholar
  12. Gruden CL (2000) Fate and Toxicity of aircraft deicing fluid additives through anaerobic digester. Department of Civil, Environmental, and Architectural Engineering, University of Colorado, BoulderGoogle Scholar
  13. Harrison S, Woodroff GL (1965) The determination of benzotriazole in inhibited glycol products. Analyst 90:44–49CrossRefGoogle Scholar
  14. Hartwell SI (1995) Toxicity of aircraft deicer and anti-icer solutions to aquatic organisms. Environ Toxicol Chem 14(8):1375–1386CrossRefGoogle Scholar
  15. Hernandez M, Abu-Dalo M (2008) Removing metals from solutions using metal binding compounds and sorbents Therefore, US Patent # 7,361,279, Issued Apr 2008Google Scholar
  16. Hickey R (1998) Design and operation of a full-scale anaerobic fluidized bed reactor at the Albany County Airport. Treatment of De-Icing Waste at Albany Count Airport, AlbanyGoogle Scholar
  17. Ho YS, Porter JF, McKay G (2002) Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: copper, nickel and lead single component systems. Water Air Soil Pollut 141:1–33CrossRefGoogle Scholar
  18. Kiss A, Fries E (2009) Occurrence of benzotriazoles in the rivers Main, Hengstbach, and Hegbach (Germany). Environ Sci Pollut Res.  https://doi.org/10.1007/s11356-009-0179-4 Google Scholar
  19. Kolpin DW, Furlong ET, Meyer MT, Thurman EM, Zaugg SD, Barber LB, Buxton HT (2002) Pharmaceuticals, hormones, and other organic wastewater contaminants in US streams, 1999–2000: a national reconnaissance. Environ Sci Technol 36(6):1202–1211CrossRefGoogle Scholar
  20. Liu YS, Ying GG, Shareef A, Kookana RS (2011) Simultaneous determination of benzotriazoles and ultraviolet filters in ground water, effluent and biosolid samples using gas chromatography–tandem mass spectrometry. J Chromatogr A 1218(31):5328–5335CrossRefGoogle Scholar
  21. Loos R, Gawlik BM, Locoro G, Rimaviciute E, Contini S, Bidoglio G (2009) EU-wide survey of polar organic persistent pollutants in European river waters. Environ Pollut 157:561–568CrossRefGoogle Scholar
  22. Lund H, Kwee S (1968) Electroorganic preparations. XXV. Polarography and reduction of benzotriazole and related compounds. Acta Chem Scand 22(9):2879–2889CrossRefGoogle Scholar
  23. Pillard DA, Cornell JS, Dufresne DL, Hernandez MT (2001) Toxicity of benzotriazole and benzotriazole derivatives to three aquatic species. Water Res 35(2):557–560CrossRefGoogle Scholar
  24. Porter JF, McKay G, Choy KH (1999) The prediction of sorption binary mixture of acidic dyes using single- and mixed-isotherm variants of the ideal adsorbed solute theory. Chem Eng Sci 54:5863–5885CrossRefGoogle Scholar
  25. Puttanna K, Nanje Gowda NM, Prakasa Rao EVS (1999) Evaluation of nitrification inhibitors for use under tropical conditions. Commun Soil Sci Plant Anal 30(3&4):519–524CrossRefGoogle Scholar
  26. Redlich O, Peterson DL (1959) A useful adsorption isotherm. J Phys Chem 63:1024–1026CrossRefGoogle Scholar
  27. Sulej AM, Polkowska Ż, Astel A, Namieśnik J (2013) Analytical procedures for the determination of fuel combustion products, anti-corrosive compounds, and de-icing compounds in airport runoff water samples. Talanta 117:158–167CrossRefGoogle Scholar
  28. USEPA (1999) Airport deicing operations study: draft effluent guidelines. EPA 821-D-899-002. Office of Water, WashingtonGoogle Scholar
  29. Van Leerdam JA, Hogenboom AC, van der Kooi MME, de Voogt P (2009) Determination of polar 1H-benzotriazoles and benzothiazoles in water by solid-phase extraction and liquid chromatography LTQ FT Orbitrap mass spectrometry. Int J Mass Spectrom 282(3):99–107CrossRefGoogle Scholar
  30. Weiss S, Reemtsma T (2005) Determination of benzotriazole corrosion inhibitors from aqueous environmental samples by liquid chromatography-electrospray ionization-tandem mass spectrometry. Anal Chem 77(22):7415–7420CrossRefGoogle Scholar
  31. Weiss S, Jakobs J, Reemtsma T (2006) Discharge of three benzotriazole corrosion inhibitors with municipal waste water and improvements by membrane bioreactor treatment and ozonation. Environ Sci Technol 40:7193–7199CrossRefGoogle Scholar

Copyright information

© Islamic Azad University (IAU) 2018

Authors and Affiliations

  • A. N. Ababneh
    • 1
    Email author
  • M. A. Abu-Dalo
    • 2
  • C. Horn
    • 3
  • M. T. Hernandez
    • 3
  1. 1.Department of Civil EngineeringJordan University of Science and TechnologyIrbidJordan
  2. 2.Chemistry DepartmentJordan University of Science and TechnologyIrbidJordan
  3. 3.Department of Civil, Environmental, and Architectural EngineeringUniversity of Colorado at BoulderBoulderUSA

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