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Electrochemical degradation of textile dyes in a flow reactor: effect of operating conditions and dyes chemical structure

  • A. PieczyńskaEmail author
  • T. Ossowski
  • R. Bogdanowicz
  • E. Siedlecka
Original Paper
  • 101 Downloads

Abstract

In this study, electrochemical oxidation of five azo dyestuffs (Yellow D-5GN, Red D-B8, Ruby F-2B, Blue D-5RN, Black DN), that are widely used in the textile industry, was investigated in a flow reactor. BDD electrode with a high boron doping level (C/B = 10 000) was prepared and used. Two configurations of reactor were considered, i.e., one with the undivided cell, and the other with the cell divided by anodic and cathodic compartments. The effect of current density and the initial pH of the solution on the dyestuff degradation process was investigated. As expected, higher degradation rate was found for higher current density, while the effect of pH was marginal. Next, electrochemical oxidation of azo dyestuffs with different chemical structures was investigated. Based on the cyclic voltammetry measurements, the correlation between the dyestuff removal rate and the oxidation potential value of dyestuff was found. These results suggest that the direct oxidation of dyestuffs at the highly doped BDD anode plays a significant role in the electrochemical oxidation. Finally, the electrochemical removal of dyestuffs was carried out in two types of dyeing baths. The dyeing bath composition has a significant effect on the degradation efficiency. Chlorides in F-type dyeing bath accelerated electrochemical removal due to effective generation of Cl2/HOCl at the highly B-doped BDD anode. In contrast, OH inhibited the D-type dyestuff removal from dyeing bath, because they acted as scavengers of ·OH radicals. Highly B-doped BDD anode is promising material to F-type dyestuff treatment in industrial wastewater.

Keywords

Electrochemical degradation Flow reactor BDD Dyes Effluents 

Notes

Acknowledgements

The authors would like to acknowledge the financial support of the Polish Ministry of Science and Higher Education under the grants DS 530-8626-D596-17-1F, BMN 538-8626-B409-16, BMN 538-8375-B402-16 and BMN 538-8626-B64-15. We also want to express our gratitude to Mrs. Paulina Bojko for her help in the laboratory work.

References

  1. Balci B, Oturan N, Cherrier R, Oturan MA (2009) Degradation of atrazine in aqueous medium by electrocatalytically generated hydroxyl radicals. A kinetic and mechanistic study. Water Res 43:1924–1934.  https://doi.org/10.1016/j.watres.2009.01.021 CrossRefGoogle Scholar
  2. Basha CA, Sendhil J, Selvakumar KV, Muniswaran PK, Lee CW (2012) Electrochemical degradation of textile dyeing industry effluent in batch and flow reactor systems. Desalination 285:188–197.  https://doi.org/10.1016/j.desal.2011.09.054 CrossRefGoogle Scholar
  3. Bogdanowicz R, Fabiańska A, Golunski L, Sobaszek M, Gnyba M, Ryl J, Darowicki K, Ossowski T, Janssens SD, Haenen K, Siedlecka EM (2013) Influence of the boron doping level on the electrochemical oxidation of the azo dyes at Si/BDD thin film electrodes. Diam Relat Mater 39:82–88.  https://doi.org/10.1016/j.diamond.2013.08.004 CrossRefGoogle Scholar
  4. Bruguera-Casamada C, Sirés I, Brillas E, Araujo RM (2017) Effect of electrogenerated hydroxyl radicals, active chlorine and organic matter on the electrochemical inactivation of Pseudomonas aeruginosa using BDD and dimensionally stable anodes. Sep Purif Technol 178:224–231.  https://doi.org/10.1016/j.seppur.2017.01.042 CrossRefGoogle Scholar
  5. Butrón E, Juárez ME, Solis M, Teutli M, González I, Nava JL (2007) Electrochemical incineration of indigo textile dye in filter-press-type FM01-LC electrochemical cell using BDD electrodes. Electrochim Acta 52:6888–6894.  https://doi.org/10.1016/j.electacta.2007.04.108 CrossRefGoogle Scholar
  6. Carneiro PA, Osugi ME, Fugivara CS, Boralle N, Furlan M, Zanoni MVB (2005) Evaluation of different electrochemical methods on the oxidation and degradation of Reactive Blue 4 in aqueous solution. Chemosphere 59:431–439.  https://doi.org/10.1016/j.chemosphere.2004.10.043 CrossRefGoogle Scholar
  7. Chen G (2004) Electrochemical technologies in wastewater treatment. Sep Purif Technol 38:11–41.  https://doi.org/10.1016/j.seppur.2003.10.006 CrossRefGoogle Scholar
  8. Degaki AH, Pereira GF, Rocha-Filho RC, Bocchi N, Biaggio SR (2013) Effect of specific active chlorine species and temperature on the electrochemical degradation of the reactive blue 19 dye using a boron-doped diamond or DSA anode in a flow reactor. Electrocatalysis 5:8–15.  https://doi.org/10.1007/s12678-013-0156-z CrossRefGoogle Scholar
  9. El-Ghenymy A, Arias C, Cabot PL, Centellas F, Garrido JA, Rodríguez RM, Brillas E (2012) Electrochemical incineration of sulfanilic acid at a boron-doped diamond anode. Chemosphere 87:1126–1133.  https://doi.org/10.1016/j.chemosphere.2012.02.006 CrossRefGoogle Scholar
  10. El-Ghenymy A, Cabot PL, Centellas F, Garrido JA, Rodríguez RM, Arias C, Brillas E (2013a) Electrochemical incineration of the antimicrobial sulfamethazine at a boron-doped diamond anode. Electrochim Acta 90:254–264.  https://doi.org/10.1016/j.electacta.2012.11.125 CrossRefGoogle Scholar
  11. El-Ghenymy A, Garrido JA, Rodríguez RM, Cabot PL, Centellas F, Arias C, Brillas E (2013b) Degradation of sulfanilamide in acidic medium by anodic oxidation with a boron-doped diamond anode. J Electroanal Chem 689:149–157.  https://doi.org/10.1016/j.jelechem.2012.11.013 CrossRefGoogle Scholar
  12. El-Ghenymy A, Centellas F, Garrido JA, Rodríguez RM, Sirés I, Cabot PL, Brillas E (2014) Decolorization and mineralization of Orange G azo dye solutions by anodic oxidation with a boron-doped diamond anode in divided and undivided tank reactors. Electrochim Acta 130:568–576.  https://doi.org/10.1016/j.electacta.2014.03.066 CrossRefGoogle Scholar
  13. Fabiańska A, Ossowski T, Stepnowski P, Stolte S, Thöming J, Siedlecka EM (2012) Electrochemical oxidation of imidazolium-based ionic liquids: the influence of anions. Chem Eng J 198–199:338–345.  https://doi.org/10.1016/j.cej.2012.05.108 CrossRefGoogle Scholar
  14. Fabiańska A, Bogdanowicz R, Zięba P, Ossowski T, Gnyba M, Ryl J, Zielinski A, Janssens SD, Haenen K, Siedlecka EM (2013) Electrochemical oxidation of sulphamerazine at boron-doped diamond electrodes: influence of boron concentration. Phys Status Solidi 210:2040–2047.  https://doi.org/10.1002/pssa.201300094 CrossRefGoogle Scholar
  15. Fabiańska A, Białk-Bielińska A, Stepnowski P, Stolte S, Siedlecka EM (2014) Electrochemical degradation of sulfonamides at BDD electrode: kinetics, reaction pathway and eco-toxicity evaluation. J. Hazard Mater 280:579–587CrossRefGoogle Scholar
  16. Fabiańska A, Ofiarska A, Fiszka-Borzyszkowska A, Stepnowski P, Siedlecka EM (2015) Electrodegradation of ifosfamide and cyclophosphamide at BDD electrode: decomposition pathway and its kinetics. Chem Eng J 276:274–282.  https://doi.org/10.1016/j.cej.2015.04.071 CrossRefGoogle Scholar
  17. Feng Y, Lv J, Liu J, Gao N, Peng H, Chen Y (2011) Influence of boron concentration on growth characteristic and electro-catalytic performance of boron-doped diamond electrodes prepared by direct current plasma chemical vapor deposition. Appl Surf Sci 257:3433–3439.  https://doi.org/10.1016/j.apsusc.2010.11.041 CrossRefGoogle Scholar
  18. Luong JHT, Male KB, Glennon JD (2009) Boron-doped diamond electrode: synthesis, characterization, functionalization and analytical applications. Analyst 134:1965–1979.  https://doi.org/10.1039/b910206j CrossRefGoogle Scholar
  19. Martínez-Huitle C, Brillas E (2009) Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods : a general review. Appl Catal B Environ 87:105–145.  https://doi.org/10.1016/j.apcatb.2008.09.017 CrossRefGoogle Scholar
  20. Martínez-Huitle CA, Ferro S (2006) Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect processes. Chem Soc Rev 35:1324–1340.  https://doi.org/10.1039/b517632h CrossRefGoogle Scholar
  21. Moreira FC, Boaventura RAR, Brillas E, Vilar VJP (2017) Electrochemical advanced oxidation processes: a review on their application to synthetic and real wastewaters. Appl Catal B Environ 202:217–261.  https://doi.org/10.1016/j.apcatb.2016.08.037 CrossRefGoogle Scholar
  22. Murugananthan M, Latha SS, Bhaskar Raju G, Yoshihara S (2011) Role of electrolyte on anodic mineralization of atenolol at boron doped diamond and Pt electrodes. Sep Purif Technol 79:56–62.  https://doi.org/10.1016/j.seppur.2011.03.011 CrossRefGoogle Scholar
  23. O’Neill C, Hawkes FR, Hawkes DL, Lourenço ND, Pinheiro HM, Delée W (1999) Colour in textile effluents: sources, measurement, discharge consents and simulation: a review. J Chem Technol Biotechnol 74:1009–1018. https://doi.org/10.1002/(SICI)1097-4660(199911)74:11<1009::AID-JCTB153>3.0.CO;2-NCrossRefGoogle Scholar
  24. Oller I, Malato S, Sánchez-Pérez JA (2011) Combination of advanced oxidation processes and biological treatments for wastewater decontamination–a review. Sci Total Environ 409:4141–4166.  https://doi.org/10.1016/j.scitotenv.2010.08.061 CrossRefGoogle Scholar
  25. Palma-Goyes RE, Guzmán-Duque FL, Peñuela G, González I, Nava JL, Torres-Palma RA (2010) Electrochemical degradation of crystal violet with BDD electrodes: effect of electrochemical parameters and identification of organic by-products. Chemosphere 81:26–32.  https://doi.org/10.1016/j.chemosphere.2010.07.020 CrossRefGoogle Scholar
  26. Panizza M, Cerisola G (2009) Direct and mediated anodic oxidation of organic pollutants. Chem Rev 109:6541–6569.  https://doi.org/10.1021/cr9001319 CrossRefGoogle Scholar
  27. Pereira GF, Rocha-Filho RC, Bocchi N, Biaggio SR (2012) Electrochemical degradation of bisphenol A using a flow reactor with a boron-doped diamond anode. Chem Eng J 198–199:282–288.  https://doi.org/10.1016/j.cej.2012.05.057 CrossRefGoogle Scholar
  28. Pieczyńska A, Ofiarska A, Borzyszkowska AF, Białk-Bielińska A, Stepnowski P, Stolte S, Siedlecka EM (2015) A comparative study of electrochemical degradation of imidazolium and pyridinium ionic liquids: a reaction pathway and ecotoxicity evaluation. Sep Purif Technol.  https://doi.org/10.1016/j.seppur.2015.10.045 Google Scholar
  29. Samet Y, Agengui L, Abdelhédi R (2010) Electrochemical degradation of chlorpyrifos pesticide in aqueous solutions by anodic oxidation at boron-doped diamond electrodes. Chem Eng J 161:167–172.  https://doi.org/10.1016/j.cej.2010.04.060 CrossRefGoogle Scholar
  30. Sanroman MA, Pazos M, Ricart MT, Cameselle C (2004) Electrochemical decolourisation of structurally different dyes. Chemosphere 57:233–239.  https://doi.org/10.1016/j.chemosphere.2004.06.019 CrossRefGoogle Scholar
  31. Santos V, Morão A, Pacheco MJ, Ciríaco L, Lopes A (2008) Electrochemical degradation of azo dyes on bdd : effect of chemical structure and operating conditions on the combustion efficiency. J Environ Eng Manag 18:193–204Google Scholar
  32. Siedlecka EM, Mrozik W, Kaczyński Z, Stepnowski P (2008) Degradation of 1-butyl-3-methylimidazolium chloride ionic liquid in a Fenton-like system. J Hazard Mater 154:893–900.  https://doi.org/10.1016/j.jhazmat.2007.10.104 CrossRefGoogle Scholar
  33. Siedlecka EM, Stolte S, Nienstedt A, Ossowski T, Stepnowski P (2013) Electrocatalytic oxidation of 1-Butyl-3-methylimidazolium chloride: effect of the electrode material. Int J Electrochem Sci 8:5560–5574Google Scholar
  34. Sirés I, Brillas E (2014) BDD electrochemical reactors. In: Evaluation of electrochemical reactors as a new way to environmental protection. Research Signpost, Kerala, pp 59–78Google Scholar
  35. Soloman PA, Basha CA, Velan M, Ramamurthi V, Koteeswaran K, Balasubramanian N (2009) Electrochemical degradation of remazol black B dye effluent. CLEAN - Soil Air Water 37:889–900.  https://doi.org/10.1002/clen.200900055 CrossRefGoogle Scholar
  36. Tsantaki E, Velegraki T, Katsaounis A, Mantzavinos D (2012) Anodic oxidation of textile dyehouse effluents on boron-doped diamond electrode. J Hazard Mater 207–208:91–96.  https://doi.org/10.1016/j.jhazmat.2011.03.107 CrossRefGoogle Scholar
  37. Velegraki T, Balayiannis G, Diamadopoulos E, Katsaounis A, Mantzavinos D (2010) Electrochemical oxidation of benzoic acid in water over boron-doped diamond electrodes: statistical analysis of key operating parameters, kinetic modeling, reaction by-products and ecotoxicity. Chem Eng J 160:538–548.  https://doi.org/10.1016/j.cej.2010.03.065 CrossRefGoogle Scholar
  38. Wächter N, Pereira GF, Rocha RC, Bocchi N, Biaggio SR (2015) Comparative Electrochemical Degradation of the Acid Yellow Anodes in a Flow Reactor 10:1361–1371Google Scholar
  39. Yavuz Y, Canan G, Bakır O (2007) Electrochemical degradation and toxicity reduction of CI. Basic Red 29 solution and textile wastewater by using diamond anode. J Hazard Mater 145:100–108.  https://doi.org/10.1016/j.jhazmat.2006.10.090 CrossRefGoogle Scholar

Copyright information

© Islamic Azad University (IAU) 2018

Authors and Affiliations

  • A. Pieczyńska
    • 1
    Email author
  • T. Ossowski
    • 2
  • R. Bogdanowicz
    • 3
  • E. Siedlecka
    • 1
  1. 1.Department of Environmental Technology, Faculty of ChemistryUniversity of GdańskGdańskPoland
  2. 2.Department of Analytical Chemistry, Faculty of ChemistryUniversity of GdańskGdanskPoland
  3. 3.Department of Metrology and Optoelectronics, Faculty of Electronics, Telecommunications and InformaticsGdansk University of TechnologyGdanskPoland

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