Ultrafast removal of heavy metals by tin oxide nanowires as new adsorbents in solid-phase extraction technique

  • R. AlizadehEmail author
  • R. K. Kazemi
  • M. R. Rezaei
Original Paper


In the present research, the removal of lead(II) and copper(II) from aqueous solutions is studied, using SnO2 nanowires as new adsorbent on solid-phase extraction disk and compared with pine core and buttonwood as biosorbents. Batch adsorption experiments were performed as a function of pH, adsorption time, solute concentration and adsorbent dose for biosorbents. Also, the pH, transfer rate of solution and metal concentration were selected as experimental parameters for the removal of heavy metals by SnO2 nanowires. All of the parameters were optimized by experimental design method for sorbents. The experimental equilibrium adsorption data are tested for the Langmuir and Freundlich equations. Results indicate the following order to fit the isotherms: Langmuir > Freundlich, in case of lead and copper ions. The removal of Cu(II) and Pb(II) was performed by selected sorbents in the presence of interferences ions. This led to no remarkable decrease in the removal efficiency of SnO2 nanowires. Using the SnO2 nanowires in the wastewater treatment indicated 96.8 and 85.28% removal efficiency in only 7 min for Pb(II) and Cu(II), respectively. SnO2 nanowires were found as reusable sorbent. Therefore, SnO2 nanowires have a good potential for application in environmental protection.


Factorial design Isotherms SnO2 nanowires Solid-phase extraction Ultrafast heavy metal removal 



The authors thank Iran National Science Foundation (INSF) for supporting the project (93012503) and Iran Nanotechnology Initiative Council.

Supplementary material

13762_2017_1481_MOESM1_ESM.docx (260 kb)
Supplementary material 1 (DOCX 260 kb)
13762_2017_1481_MOESM2_ESM.xlsx (23 kb)
Supplementary material 2 (XLSX 23 kb)


  1. Alizadeh R (2016) Chlorophenol’s ultra-trace analysis in environmental samples by chitosan-zinc oxide nanorod composite as a novel coating for solid phase micro-extraction combined with high performance liquid chromatography. Talanta 146:831–838CrossRefGoogle Scholar
  2. Alizadeh R, Najafi NM (2013) Quantification of PAHs and chlorinated compounds by novel solid-phase microextraction based on the arrays of tin oxide nanorods. Environ Monit Assess 185:7353–7363CrossRefGoogle Scholar
  3. Alizadeh R, Kashkoei PK, Kazemipour M (2016) Zinc oxide-copper oxide nanoplates composite as coating for solid phase microextraction combined with high performance liquid chromatography-UV detection for trace analysis of chlorophenols in water and tomato juice samples. Anal Bioanal Chem 408:3727–3736CrossRefGoogle Scholar
  4. Awual MR, Ismael M, Khaleque MA, Yaita T (2014) Ultra-trace copper(II) detection and removal from wastewater using novel meso-adsorbent. J Ind Eng Chem 20:2332–2340CrossRefGoogle Scholar
  5. Boonyapookana B, Parkpian P, Techapinyawat S, Delaune RD, Jugsujinda A (2005) Phytoaccumulation of lead by sunflower (Helianthus annuus), tobacco (Nicotiana tabacum), and vetiver (Vetiveria zizanioides). J Environ Sci Health Part A 40:117–137CrossRefGoogle Scholar
  6. Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manage 92:407–418CrossRefGoogle Scholar
  7. Goel J, Kadirvelu K, Rajagopal C, GARG VK (2005) Removal of lead(II) by adsorption using treated granular activated carbon: batch and column studies. J Hazard Mater 125:211–220CrossRefGoogle Scholar
  8. Hsieh S-H, Horng J-J (2007) Adsorption behavior of heavy metal ions by carbon nanotubes grown on microsized Al2O3 particles. J Univ Sci Technol Beijing Miner Metall Mater 14:77–84Google Scholar
  9. Johari A, Bhatnagar MC, Rana V (2012) Growth, characterization and I-V characteristics of tin oxide (SnO < inf > 2</inf >) nanowires. Adv Mater Lett 3:515–518CrossRefGoogle Scholar
  10. Jung W, Jeon B-H, Cho D-W, Roh H-S, Cho Y, Kim S-J, Lee DS (2015) Sorptive removal of heavy metals with nano-sized carbon immobilized alginate beads. J Ind Eng Chem 26:364–369CrossRefGoogle Scholar
  11. Kamal O, Pochat-Bohatier C, Sanchez-Marcano J (2017) Development and stability of gelatin cross-linked membranes for copper (II) ions removal from acid waters. Sep Purif Technol 183:153–161CrossRefGoogle Scholar
  12. Kim H, Cho J (2008) Hard templating synthesis of mesoporous and nanowire SnO2 lithium battery anode materials. J Mater Chem 18:771–775CrossRefGoogle Scholar
  13. Kiran B, Kaushik A (2008) Cyanobacterial biosorption of Cr(VI): application of two parameter and Bohart Adams models for batch and column studies. Chem Eng J 144:391–399CrossRefGoogle Scholar
  14. Kumar M, Gogoi A, Kumari D, Borah R, Das P, Mazumder P, Tyagi VK (2017) Review of perspective, problems, challenges, and future scenario of metal contamination in the urban environment. J Hazard Toxic Radioact Waste 21:04017007CrossRefGoogle Scholar
  15. Lasat MM (2002) Phytoextraction of toxic metals. J Environ Qual 31:109–120CrossRefGoogle Scholar
  16. Lata S, Samadder SR (2016) Removal of arsenic from water using nano adsorbents and challenges: a review. J Environ Manage 166:387–406CrossRefGoogle Scholar
  17. Li N, Zhang L, Chen Y, Tian Y, Wang H (2011) Adsorption behavior of Cu(II) onto titanate nanofibers prepared by alkali treatment. J Hazard Mater 189:265–272CrossRefGoogle Scholar
  18. Lupan O, Chow L, Chai G, Roldan B, Naitabdi A, Schulte A, Heinrich H (2007) Nanofabrication and characterization of ZnO nanorod arrays and branched microrods by aqueous solution route and rapid thermal processing. Mater Sci Eng B 145:57–66CrossRefGoogle Scholar
  19. Lupan O, Chow L, Chai G, Schulte A, Park S, Heinrich H (2009) A rapid hydrothermal synthesis of rutile SnO2 nanowires. Mater Sci Eng B 157:101–104CrossRefGoogle Scholar
  20. Mishra SP, Singh VK, Tiwari D (1996) Radiotracer technique in adsorption study: part XIV. Efficient removal of mercury from aqueous solutions by hydrous zirconium oxide. Appl Radiat Isot 47:15–21CrossRefGoogle Scholar
  21. Pan B, Pan B, Zhang W, Lv L, Zhang Q, Zheng S (2009) Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters. Chem Eng J 151:19–29CrossRefGoogle Scholar
  22. Rao GP, Lu C, Su F (2007) Sorption of divalent metal ions from aqueous solution by carbon nanotubes: a review. Sep Purif Technol 58:224–231CrossRefGoogle Scholar
  23. Rikka VR, Sameera I, Bhatia R, Prasad V (2015) Synthesis, characterization and field emission properties of tin oxide nanowires. Mater Chem Phys 166:26–30CrossRefGoogle Scholar
  24. Shahidi A, Khashei-Siuki A, Zeraatkar Z (2016) Performance assessment of natural adsorbent using barberry root in the removal of chromium from aqueous environment (case study: groundwater resource of Birjand). J Environ Stud 41:827–840Google Scholar
  25. Simonovic RM, Pecev TG, Dimitrov CM (2007) Accumulation of chromium in plants grown on soil contaminated by leather industry generated waste water. Oxid Commun 30:708–713Google Scholar
  26. Singha B, Das SK (2012) Removal of Pb(II) ions from aqueous solution and industrial effluent using natural biosorbents. Environ Sci Pollut Res 19:2212–2226CrossRefGoogle Scholar
  27. Stafiej A, Pyrzynska K (2007) Adsorption of heavy metal ions with carbon nanotubes. Sep Purif Technol 58:49–52CrossRefGoogle Scholar
  28. Toprak R, Girgin I (2000) Removal of chromium from leather industry waste water by activated clinoptilolite. Turk J Eng Environ Sci 24:343–351Google Scholar
  29. Tran HA, Rananavare SB (2011) Synthesis and characterization of N- and P- doped tin oxide nanowires. In: Proceedings of the IEEE conference on nanotechnology, pp 144–149Google Scholar
  30. Weerasinghe A, Ariyawnasa S, Weerasooriya R (2008) Phyto-remediation potential of Ipomoea aquatica for Cr(VI) mitigation. Chemosphere 70:521–524CrossRefGoogle Scholar

Copyright information

© Islamic Azad University (IAU) 2017

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of ScienceUniversity of QomQomIran
  2. 2.Department of Environment, Faculty of Nature Resources and EnvironmentUniversity of BirjandBirjandIran

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