Photodegradation of amaranth in aqueous solution catalyzed by immobilized nanoparticles of titanium dioxide

Original Paper

Abstract

The use of suspensions of nanoparticles of titanium dioxide in photocatalytic degradation of dye solution has disadvantages of inconvenient separation of fine particles for reuse and limited penetration of light for effective degradation. These problems can be minimized by supporting titanium dioxide on various inert supports. The present study involves the preparation of immobilized titanium dioxide films by three different techniques and characterization of the prepared films. The immobilized films of nanocrystals of titanium dioxide were prepared using sol–gel technique, polyvinyl alcohol–formaldehyde binder and acrylic emulsion. The photocatalytic performance of the prepared films for degradation of amaranth dye has also been evaluated and compared. Combination of photodegradation and adsorption processes induces strong beneficial effects on removal of dyes. Addition of high adsorption capacity activated carbon to photoactive titanium dioxide in photodegradation of dyes improves the efficiency of dye mineralization. The activated carbon has also been immobilized along with titanium dioxide in the present work to examine the dual effect of photodegradation and adsorption in the removal of amaranth. The films formed with the help of polyvinyl alcohol–formaldehyde binder showed better dye degradation capabilities.

Keywords

Activated carbon Photocatalysis Polyvinyl alcohol–formaldehyde binder Titanium dioxide 

Notes

Acknowledgments

The authors also wish to extend their sincere gratitude to all who assisted in promoting the present work.

References

  1. Arabatzis IM, Antonaraki S, Stergiopoulos T, Hiskia A, Papaconstantinou E, Bernard MC, Falaras P (2002) Preparation, characterization and photocatalytic activity of nanocrystalline thin film TiO2 catalysts towards 3, 5-dichlorophenol degradation. J Photochem Photobiol A 149:237–245CrossRefGoogle Scholar
  2. Černigoj U (2007) Photodegradation of organic pollutants in aqueous solutions catalyzed by immobilized titanium dioxide: Novel routs towards higher efficiency. PhD. Dissertation, University of Nova Gorica, Nova GoricaGoogle Scholar
  3. Divya N, Bansal A, Jana AK (2009) Surface modification, characterization and photocatalytic performance of nano-sized titania modified with silver and bentonite clay. Bull Chem Reaction Eng Catal 4(2):43–53Google Scholar
  4. Fox MA, Dulay MT (1993) Heterogeneous photocatalysis. Chem Rev 93:341–357CrossRefGoogle Scholar
  5. Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochem Photobiol C 1:1–21CrossRefGoogle Scholar
  6. Gupta KK, Jassal M, Agrawal AK (2008) Sol–gel derived titanium dioxide finishing of cotton fabric for self cleaning. Indian J Fib Tex Res 33:443–450Google Scholar
  7. Habibi MH, Esfahani MN, Egerton TA (2007) Photochemical characterization and photocatalytic properties of a nanaostructure composite TiO2 film. Int J Photoenergy 13653:1–8CrossRefGoogle Scholar
  8. Hashimoto K, Irie H, Fujishima A (2005) TiO2 photocatalysis: a historical overview and future prospects. Jpn J Appl Phys 44:8269–8285CrossRefGoogle Scholar
  9. Hoffmann MR, Martin SR, Choi W, Bahnemann DW (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95:69–96CrossRefGoogle Scholar
  10. Houas A, Lachheb H, Ksibi M, Elaloui E, Guillard C, Hermann JM (2001) Photocatalytic degradation pathway of methylene blue in water. Appl Catal B 31:145–157CrossRefGoogle Scholar
  11. Jain R, Sikarwar S (2008) Photodestruction and COD removal of toxic dye erioglaucine by TiO2-UV process: Influence of operational parameters. Int J Phy Sci 3(12):299–305Google Scholar
  12. Kaur S, Singh V (2007) TiO2 mediated photocatalytic degradation studies of reactive red 198 by UV irradiation. J Haz Mat 141:230–236CrossRefGoogle Scholar
  13. Keshmiri M, Mohseni T, Troczynski T (2004) Development of novel TiO2 sol–gel derived composites and its photocatalytic activities for trichloroethylene oxidation. Appl Catal B 53:209–219CrossRefGoogle Scholar
  14. Kumar J, Bansal A (2010) Photocatalytic degradation of amaranth dye over immobilized nano-crystals of TiO2. In: International Conference on Energy and Environment, Cambridge, 129–133Google Scholar
  15. Mills A, Le Hunte S (1997) An overview of semiconductor photocatalysis. J Photochem Photobiol A 108:1–35CrossRefGoogle Scholar
  16. Noorjahan M, Reddy MP, Kumari VD, Lavedrine B, Boule P, Subrahmanyam M (2003) Photocatalytic degradation of H-acid over a novel TiO2 thin film fixed bed reactor and in aqueous suspension. J Photochem Photobiol A 156:179–187CrossRefGoogle Scholar
  17. Oskam G, Nellore A, Lee P, Searson PC (2003) The growth kinetics of TiO2 nanoparticles from titanium (IV) alkoxide at high water/titanium ratio. J Phys Chem B 107:1734–1738CrossRefGoogle Scholar
  18. Pirkanniemi K, Sillanpää M (2002) Heterogeneous water phase catalysis as an environmental application: a review. Chemosphere 48:1047–1060CrossRefGoogle Scholar
  19. Su C, Hong BY, Tseng CM (2004) Preparation and characterization of thin film TiO2 dip coated on non-conductive substrate prepared from tetraethyl orthotitanate precursor. Catal Today 96:119–126CrossRefGoogle Scholar
  20. Tryba B, Morawski AW, Inagaki M (2003a) Application of TiO2-mounted activated carbon to the removal of phenol from water. Appl Catal B 18:281–291Google Scholar
  21. Tryba B, Morawski AW, Inagaki M (2003b) A new route for preparation of TiO2-mounted activated carbon. Appl CatalB 46:203–208CrossRefGoogle Scholar
  22. Valtierra JM, Cardenas MS, Reyes CF, Calixto S (2006) Formation of smooth and rough TiO2 thin films on fiberglass by sol–gel method. J Mex Chem Soc 50(1):8–13Google Scholar
  23. Vautier M, Guillard C, Herrman JM (2001) Photocatalytic degradation of dyes in water: case study of indigo and indigo carmine. J Catal 201(1):46–59CrossRefGoogle Scholar
  24. Vilhunen S, Sillanpää M (2009) Atomic layer deposited (ALD) TiO2 and TiO2-x-Nx thin film photocatalysts in salicylic acid decomposition. Wat Sci Technol 60:2471–2475CrossRefGoogle Scholar
  25. Vilhunen S, Bosund M, Kääriäinen ML (2009) Atomic layer deposited TiO2 films in photodegradation of aqueous salicylic acid. Sep Pur Technol 66:130–134Google Scholar
  26. Yoshiya K, Shin-ya M, Hiroshi K, Bunsho O (2002) Design, preparation and characterization of highly active metal oxide photocatalysts. Springer, New YorkGoogle Scholar

Copyright information

© CEERS, IAU 2012

Authors and Affiliations

  1. 1.Department of Chemical EngineeringDr. B.R. Ambedkar National Institute of TechnologyJalandharIndia

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