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VV-hemorphin-5 analogue for trace copper determination in water samples

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Abstract

Natural and anthropogenic sources produce mainly metal ions which can be accumulated in sediments that have a significant environmental impact on local areas, especially for their river water quality. The environmental analysis applies chemical sensors having the inherent ability to detect in real-time analytes as cations, anions, or small molecules in water systems. In this regards, the aim of our work was the development of a simple and rapid electrochemical method for selectively copper determination in water samples using non-toxic and easy degradable peptide molecules such as a hemorphin analogue. Analytical characterizations as sensibility, linear dynamic range (LDR), the limit of detection (LOD), and limit of quantification (LOQ) have been also discussed. The results revealed that the peptide sensor provided electrochemical and sensing excellent response with a low limit of detection (0.188 ng ml−1). The precision of the method proposal evaluated by the relative standard deviation is 0.7%.

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Acknowledgements

Financial support from Bulgarian National Scientific Fund project КП-06-OПP 03/3 of the Ministry of Education and Science, Bulgaria is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Analytical Chemistry, University of Chemical Technology and Metallurgy, Sofia, Bulgaria

    Stela Georgieva

  2. Department of Organic Chemistry, University of Chemical Technology and Metallurgy, Sofia, Bulgaria

    Petar Todorov & Petia Peneva

  3. National Institute of Geophysics, Geodesy and Geography, Department of Geography, Bulgarian Academy of Sciences (NIGGG-BAS), str. “Acad. G.Bonchev”, bl.3, Sofia, 1113, Bulgaria

    Marian Varbanov & Kristina Gartsiyanova

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  1. Stela Georgieva
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  2. Petar Todorov
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  3. Petia Peneva
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  4. Marian Varbanov
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  5. Kristina Gartsiyanova
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Correspondence to Stela Georgieva.

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Georgieva, S., Todorov, P., Peneva, P. et al. VV-hemorphin-5 analogue for trace copper determination in water samples. J IRAN CHEM SOC 17, 2885–2894 (2020). https://doi.org/10.1007/s13738-020-01968-1

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  • DOI: https://doi.org/10.1007/s13738-020-01968-1

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