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Pd nanoparticles immobilized on the magnetic silica–chitosan nanocomposite (NiFe2O4@SiO2@CS-Pd NPs) promoted the biaryl synthesis

  • Fatemeh RafieeEmail author
  • S. Azam Hosseini
Original Paper
  • 3 Downloads

Abstract

NiFe2O4 nanoparticles have been prepared by co-precipitation procedure and coated with SiO2 following the Stöber process. Then, chitosan was covalently connected with silica to provide an excellent stabilizer and biosupport for the immobilization of Pd nanoparticles. This magnetic bionanocatalyst was characterized by Fourier transform infrared spectroscopy, field-emission scanning electron microscope, transmission electron microscope, energy-dispersive X-ray, X-ray powder detection, vibrating sample magnetometer, inductively coupled plasma atomic emission spectroscopy techniques and CHN analysis. The NiFe2O4@SiO2@CS-Pd NPs exhibited high activity for the Suzuki coupling reactions of various aryl halides with arylboronic acids. Moreover, this catalyst could be recovered magnetically and recycled for nine times without significant loss of its activity.

Keywords

Biomaterial supported catalysts Chitosan Magnetic nanoparticle support Heterogeneous catalysts Magnetic separation Biphenyls 

Notes

Acknowledgements

We gratefully acknowledge the partial financial support received from the research council of Alzahra University.

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Copyright information

© Iranian Chemical Society 2019

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of Physics-ChemistryAlzahra UniversityVanak, TehranIran

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