Advertisement

Nanosized Fe3O4–curcumin conjugates for adsorption of heavy metals from seawater samples

  • Ali MehdiniaEmail author
  • Reza Mirzaeipour
  • Ali Jabbari
Original Paper
  • 6 Downloads

Abstract

Magnetic nanoparticles (MNPS) functionalized by curcumin (Cur) was synthesized with a simple co-precipitation method and used for removal of Cu(ІІ), Cd(ІІ) and Co(ІІ) in natural water samples. The Cur-coated MNPS were characterized by XRD, EDX, FT-IR, FE-SEM and TEM techniques. TEM result showed the particle size of < 20 nm for the synthesized material. The optimum extraction conditions were obtained as sample pH in the range of 6.5–7.5 and the sorbent mass of about 6 mg for the metals. The fast extraction times (≤ 3 min) were obtained for sorption of Cu (II), Cd(ІІ) and Co(ІІ). The complete elution from the sorbent surface was carried out using 0.5 mL HNO3 solution (0.1 mol L−1). The detection limit of the method was found to be lower than 0.5 ng L−1 for the analytes. The analytical curve was linear from 0.4 to 70 µg L−1 for Cu(ІІ) and Cd(ІІ), and 1.5–50 µg L−1 for Co(ІІ) with an correlation coefficients of > 0.991 and a relative standard deviation of 1.3% (n = 6).

Keywords

Heavy metals Curcumin Magnetic extraction Nanocomposite Removal 

References

  1. 1.
    P.H. Pacheco, R.A. Gil, S.E. Cerutti, P. Smichowski, L.D. Maertiez, Talanta 85, 2290 (2011)CrossRefGoogle Scholar
  2. 2.
    L. Okenicova, M. Zemberyova, S. Prochazkova, Environ. Chem. Lett. 14, 67 (2016)CrossRefGoogle Scholar
  3. 3.
    A.M. Abdel-Aty, N.S. Ammar, H.H. Abdel-Ghafar, R.K. Ali, J. Adv. Res. 4, 367 (2013)CrossRefGoogle Scholar
  4. 4.
    A. Karatepe, M. Soylak, J. AOAC. Int. 97, 1689 (2014)CrossRefGoogle Scholar
  5. 5.
    H. Yu, J. Pang, M. Wu, Q. Wu, C. Huo, Anal. Sci. 30, 1081 (2014)CrossRefGoogle Scholar
  6. 6.
    N.V. Alves, N.M.M. Coelho, Microchem. J. 109, 16 (2013)CrossRefGoogle Scholar
  7. 7.
    E.M. Mahmoud, A.A. Yakout, H. Abdel-Aal, M.M. Osman, Bioresour. Technol. 134, 324 (2013)CrossRefGoogle Scholar
  8. 8.
    J.N. Bianchin, E. Martendai, R. Mior, V.N. Alves, C.S.T. Araujo, N.M.M. Coelho, E. Carasek, Talanta 78, 333 (2009)CrossRefGoogle Scholar
  9. 9.
    B. Volesky, Trends Biotechnol. 5, 96 (1987)CrossRefGoogle Scholar
  10. 10.
    W.S. Wan Ngah, L.C. Teong, M.A.K.M. Hanafiah, Carbohydr. Polym. 83, 1446 (2011)CrossRefGoogle Scholar
  11. 11.
    H.A.M. Baccelo, S.C.R. Santos, C.M.S. Botelho, Chem. Eng. J. 303, 575 (2016)CrossRefGoogle Scholar
  12. 12.
    M. Wysokowski, L. Klapiszewski, D. Moszyński, P. Bartczak, T. Szatkowski, I. Majchrzak, K. Siwińska-Stefańska, V.V. Bazhenov, T. Jesionowski, Mar. Drugs. 12, 2245 (2014)CrossRefGoogle Scholar
  13. 13.
    L. Baldino, S. Cardea, E. Reverchon, J. Taiwan. Inst. Chem. Eng. 71, 518 (2017)CrossRefGoogle Scholar
  14. 14.
    K.I. Priyadarsini, D.K. Maity, G.H. Naik, M.S. Kumar, M.K. Unnikrishnan, J.G. Satav, H. Mohan, Radic. Biol. Med. 35, 475 (2003)CrossRefGoogle Scholar
  15. 15.
    R. Jain, A. Haque, A. Verma, J. Mol. Liq. 230, 600 (2017)CrossRefGoogle Scholar
  16. 16.
    J. Rajesh, M. Rajasekaran, G. Rajagopal, P. Athappan, Spectrochim. Acta A. 97, 223 (2012)CrossRefGoogle Scholar
  17. 17.
    M. Prohl, U.S. Schubert, W. Weigand, M. Gottschchaldt, Coord. Chem. Rev. 307, 32 (2016)CrossRefGoogle Scholar
  18. 18.
    L.D. Tran, N.M.T. Hong, T.T. Mai, H.V. Tran, N.T. Nguayen, T.M. Tran et al., Colloids Surf. A 371, 104 (2010)CrossRefGoogle Scholar
  19. 19.
    X. Zhu, X. Chang, Y. Cui, X. Zeo, D. Yang, Z. Hu, Microchem. J. 86, 189 (2007)CrossRefGoogle Scholar
  20. 20.
    R. Bhandari, P. Gupta, T. Dziubla, J.Z. Hilt, Mater. Sci. Eng. C. 67, 59 (2016)CrossRefGoogle Scholar
  21. 21.
    S. Wanninger, V. Lorenz, A. Subhan, F.T. Edelmann, Chem. Soc. Rev. 44, 4986 (2015)CrossRefGoogle Scholar
  22. 22.
    A. Mehdinia, Z. Shoormeij, A. Jabbari, Microchim. Acta 184, 1529 (2017)CrossRefGoogle Scholar
  23. 23.
    Y. Liu, M. Chen, H. Yongmei, Chem. Eng. J. 218, 46 (2013)CrossRefGoogle Scholar
  24. 24.
    Y.G. Zhao, H.Y. Shen, S.D. Pan, M.Q. Hu, J. Hazard. Mater. 182, 295 (2010)CrossRefGoogle Scholar
  25. 25.
    Y. Huang, A.A. Keller, Water. Res. 80, 159 (2015)CrossRefGoogle Scholar
  26. 26.
    D. Dupont, W. Brullot, M. Bloemen, T. Verbiest, K. Binnemans, ACS. Appl. Mater. Interfaces 6, 4980 (2014)CrossRefGoogle Scholar
  27. 27.
    S. Ozdemir, M.S. Yalcin, E. Kilinc, M. Soylak, Microchim. Acta 185, 73 (2018)CrossRefGoogle Scholar
  28. 28.
    Z. Shaleri Kardar, F. Shemirani, M.H. Beyki, Res. Chem. Intermed. 43, 4079 (2017)CrossRefGoogle Scholar
  29. 29.
    S. Sadeghi, E. Aboobakri, Microchim. Acta 178, 89 (2012)CrossRefGoogle Scholar

Copyright information

© Iranian Chemical Society 2019

Authors and Affiliations

  1. 1.Department of Marine Living Science, Ocean Science Research CenterIranian National Institute for Oceanography and Atmospheric scienceTehranIran
  2. 2.Department of Chemistry, Faculty of ScienceK. N. Toosi University of TechnologyTehranIran

Personalised recommendations