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2-methyl-1,4-benzodioxan-substituted bis(NHC)PdX2 complexes: Synthesis, characterization and the catalytic activity in the direct arylation reaction of some 2-alkyl-heterocyclic compounds

  • Yetkin Gök
  • Aydın Aktaş
  • Yakup Sarı
  • Hülya Erdoğan
Original Paper
  • 6 Downloads

Abstract

Almost in all fields of chemistry, the C–C cross-coupling reactions such as the direct arylation reaction have attracted much attention and have advanced quickly in recent years due to the importance of environment-friendly properties. This study contains the synthesis of the 2-methyl-1,4-benzodioxan-substituted bis(NHC)PdX2 complexes and their catalytic activity in direct arylation reaction. The bis(NHC)PdX2 complexes have been prepared from the 2-methyl-1,4-benzodioxan-substituted Ag(I)NHC complexes via transmetallation method. The bis(NHC)PdX2 complexes have been characterized using 1H NMR, 13C NMR, FT-IR spectroscopy and elemental analysis techniques. The bis(NHC)PdX2 complexes have been examined as catalysts in the direct arylation reactions with 2-n-butylfuran, 2-n-butylthiophene and 2-isopropylthiazole, and have demonstrated excellent activity in these reactions.

Keywords

N-Heterocyclic carbenes Direct arylation Butylfuran Butylthiophene 2-Isopropylthiazole 

Notes

Acknowledgements

This work was financially supported by Inönü University Research Fund (IUBAP 2011/21) and the authors acknowledge İnönü University Scientific and Technology Center for the elemental analyses of the compounds.

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Copyright information

© Iranian Chemical Society 2018

Authors and Affiliations

  1. 1.Department of Chemistry 44280, Faculty of Scienceİnönü UniversityMalatyaTurkey

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