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Journal of the Iranian Chemical Society

, Volume 16, Issue 1, pp 183–189 | Cite as

Photoluminescent, magnetic, and semiconductive properties of a terbium material

  • Qiuyan Luo
  • Longzhen Lin
  • Zhuanxia Zhang
  • Hualong Chen
  • Wentong Chen
Original Paper
  • 19 Downloads

Abstract

A terbium material is prepared under hydrothermal conditions and structurally characterized by X-ray diffraction technique. This compound is characterized by an isolated structure. Solid-state photoluminescence measurement discovers that it shows a strong emission in the green region. The sharp bands at 490, 544, 585, and 620 nm correspond to the characteristic emission 5D47FJ transitions (J = 6, 5, 4, and 3, respectively) of the Tb3+ ions. Solid-state diffuse reflectance spectrum reveals that the existence of a wide optical bandgap of 4.83 eV, indicating that it is potentially a wide band-gap semiconductor. Magnetic properties of the compound are investigated. The magnetic susceptibility obeys the Curie–Weiss law (χm = c/( T− θ)) with c = 10.55(8) K and a negative Weiss constant θ = − 1.11(7) K; this suggests the presence of an antiferromagnetic interaction in this compound.

Graphical abstract

A terbium compound has been prepared and it features an isolated structure. Solid-state photoluminescence measurement reveals that it shows a strong emission in the green region. Solid-state diffuse reflectance spectrum reveals an optical bandgap of 4.83 eV. Magnetic properties discover that it features antiferromagnetic interaction.

Keywords

Bandgap Magnetism Terbium Photoluminescence Semiconductor 

Notes

Acknowledgements

This work was supported by the NSF of China (21361013), Jiangxi Provincial Department of Education’s Item of Science and Technology (GJJ170637), the open foundation (20180008, 20150019) of the State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, and the open foundation (ST201522007) of the Key Laboratory of Jiangxi Province for Persistant Pollutants Control and Resources Recycle (Nanchang Hangkong University).

References

  1. 1.
    Q.Q. Zhang, L.L. Wu, X.Y. Cao, X.B. Chen, W.H. Fang, M. Dolg, Angew. Chem. Int. Ed. 56, 7986 (2017)CrossRefGoogle Scholar
  2. 2.
    S. Chorazy, K. Kumar, K. Nakabayashi, B. Sieklucka, S. Ohkoshi, Inorg. Chem. 56, 5239 (2017)CrossRefGoogle Scholar
  3. 3.
    R. Ban, X.P. Sun, J.W. Wang, P.T. Ma, C. Zhang, J.Y. Niu, J.P. Wang, Dalton Trans. 46, 5856 (2017)CrossRefGoogle Scholar
  4. 4.
    Z.Y. Li, B. Zhai, S.Z. Li, G.X. Cao, F.Q. Zhang, X.F. Zhang, F.L. Zhang, C. Zhang, Cryst. Growth Des. 16, 4574 (2016)CrossRefGoogle Scholar
  5. 5.
    G.E. Gomez, E.V. Brusau, A.M. Kaczmarek, C. Mellot-Draznieks, J. Sacanell, G. Rousse, R. Van Deun, C. Sanchez, G.E. Narda, G.J.A.A.S. Illia, Eur. J. Inorg. Chem. 17, 2321 (2017)CrossRefGoogle Scholar
  6. 6.
    L.Y. Zhang, L.P. Lu, M.L. Zhu, S.S. Feng, CrystEngComm 19, 1953 (2017)CrossRefGoogle Scholar
  7. 7.
    M.B. Coban, A. Amjad, M. Aygun, H. Kara, Inorg. Chim. Acta 455, 25 (2017)CrossRefGoogle Scholar
  8. 8.
    J.W. Rong, W.W. Zhang, J.F. Bai, RSC Adv. 6, 103714 (2016)CrossRefGoogle Scholar
  9. 9.
    H.J. Zhang, R.Q. Fan, Y.W. Dong, W. Chen, X. Du, P. Wang, Y.L. Yang, CrystEngComm 18, 3711 (2016)CrossRefGoogle Scholar
  10. 10.
    P.R. Matthes, J. Eyley, J.H. Klein, A. Kuzmanoski, C. Lambert, C. Feldmann, K. Muller-Buschbaum, Eur. J. Inorg. Chem. 5, 826 (2015)CrossRefGoogle Scholar
  11. 11.
    T.P. Latendresse, N.S. Bhuvanesh, M. Nippe, J. Am. Chem. Soc. 139, 8058 (2017)CrossRefGoogle Scholar
  12. 12.
    S.S. Zheng, W.K. Dong, Y. Zhang, L. Chen, Y.J. Ding, New J. Chem. 41, 4966 (2017)CrossRefGoogle Scholar
  13. 13.
    J. Jung, M. Puget, O. Cador, K. Bernot, C.J. Calzado, B. Le Guennic, Inorg. Chem. 56, 6788 (2017)CrossRefGoogle Scholar
  14. 14.
    X.C. Huang, X.H. Zhao, D. Shao, X.Y. Wang, Dalton Trans. 46, 7232 (2017)CrossRefGoogle Scholar
  15. 15.
    W. Wang, D.F. Peng, H.L. Zhang, X.H. Yang, C.F. Pan, Opt. Commun. 395, 24 (2017)CrossRefGoogle Scholar
  16. 16.
    Rigaku, CrystalClear Version 1.35 (Rigaku Corporation, Tokyo, 2002)Google Scholar
  17. 17.
    Siemens, SHELXTL™ Ver. 5 Reference Manual (Siemens Energy & Automation Inc., Madison, 1994)Google Scholar
  18. 18.
    N. Goel, N. Kumar, Inorg. Chim. Acta 463, 14 (2017)CrossRefGoogle Scholar
  19. 19.
    B.L. An, X.D. Huang, J.M. Zhang, X.Y. Zhu, J.Q. Xu, J. Lumin. 187, 340 (2017)CrossRefGoogle Scholar
  20. 20.
    H. Xiang, M.X. Lin, D.F. Jian, S.S. Guo, Y.X. Gong, J. Li, Y. Li, Inorg. Chem. Commun. 79, 33 (2017)CrossRefGoogle Scholar
  21. 21.
    C.B. Han, Y.L. Wang, Q.Y. Liu, Chin. J. Struct. Chem. 36, 705 (2017)Google Scholar
  22. 22.
    W. Qian, Z.-Q. Zhu, K. Zhang, J. Zhu, Chin. J. Struct. Chem. 36, 236 (2017)Google Scholar
  23. 23.
    Y. Wan, W. Sun, J. Liu, Z. Liu, Inorg. Chem. Commun. 80, 53 (2017)CrossRefGoogle Scholar
  24. 24.
    H. Guo, S. Zhu, D. Cai, C. Liu, Inorg. Chem. Commun. 41, 29 (2014)CrossRefGoogle Scholar
  25. 25.
    W. Zhou, M. Gu, Y. Ou, C. Zhang, X. Zhang, L. Zhou, H. Liang, Inorg. Chem. 56, 7433 (2017)CrossRefGoogle Scholar
  26. 26.
    S. Viswanathan, A. Bettencourt-Dias, Inorg. Chem. Commun. 9, 444 (2006)CrossRefGoogle Scholar
  27. 27.
    T. Horiuchi, N. Iki, H. Hoshino, C. Kabutob, S. Miyano, Tetrahedron Lett. 48, 821 (2007)CrossRefGoogle Scholar
  28. 28.
    F.Q. Huang, K. Mitchell, J.A. Ibers, Inorg. Chem. 40, 5123 (2001)CrossRefGoogle Scholar
  29. 29.
    P. Dürichen, W. Bensch, Eur. J. Solid State Inorg. Chem. 34, 1187 (1997)Google Scholar
  30. 30.
    R. Tillinski, C. Rumpf, C. Näther, P. Duerichen, I. Jess, S.A. Schunk, W. Bensch, Z. Anorg. Allg. Chem. 624, 1285 (1998)CrossRefGoogle Scholar
  31. 31.
    A.V. Morozkin, A.V. Garshev, A.V. Knotko, V.O. Yapaskurt, O. Isnard, J.L. Yao, R. Nirmala, S. Quezado, S.K. Malik, J. Solid State Chem. 251, 33 (2017)CrossRefGoogle Scholar
  32. 32.
    D.Y. Ma, J.X. Xiao, H.F. Guo, Y.Q. Liang, J.J. Yan, W.J. Lin, W.Q. Ding, Chin. J. Struct. Chem. 35, 361 (2016)Google Scholar

Copyright information

© Iranian Chemical Society 2018

Authors and Affiliations

  • Qiuyan Luo
    • 1
  • Longzhen Lin
    • 1
  • Zhuanxia Zhang
    • 1
  • Hualong Chen
    • 1
  • Wentong Chen
    • 1
    • 2
    • 3
  1. 1.Institute of Applied Chemistry, School of Chemistry and Chemical EngineeringJinggangshan UniversityJi’anChina
  2. 2.Key Laboratory of Jiangxi Province for Persistant Pollutants Control and Resources RecycleNanchang Hangkong UniversityNanchangChina
  3. 3.State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhouChina

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