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One-pot synthesized porphyrin-based polymer supported gold nanoparticles as efficient catalysts for alkyne hydration and alcohol oxidation in water

  • Jian Chen
  • Ju Zhang
  • Dajian ZhuEmail author
  • Tao LiEmail author
Original Paper
  • 40 Downloads

Abstract

The construction of porous organic polymer from 5,10,15,20-tetraphenylporphyrin (TPP) was described using one-pot Friedel-Crafts alkylation reaction. Au was simultaneously loaded on the porphyrin-based polymer denoted as Au/KAPs(DCM-TPP). This polymer-supported Au was fully characterized by many physicochemical methods. It was found to possess BET surface area of 796 m2 g−1, good thermal stability above 250 °C and Au nanoparticles with an average size of 8 nm. It was used as an efficient heterogeneous catalyst for alkyne hydration and alcohol oxidation in water. This Au catalyst exhibited excellent catalytic efficiency and recycling performance without loss of activity at least five times. A new strategy to synthesize polymer-supported Au nanoparticle catalyst was finally provided.

Keywords

Porphyrin-based polymer Gold nanoparticles Alkyne hydration Alcohol oxidation 

Notes

Acknowledgements

We are also grateful to the Analytical and Testing Center of Huazhong University of Science and Technology, ATC School of Chemistry and Chemical Engineering, HUST, Wuhan, China.

Funding information

This work was supported by the National Natural Science Foundation of China (21473064) and Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education Foundation (CHCL15001).

Supplementary material

13404_2018_249_MOESM1_ESM.doc (4.2 mb)
ESM 1 (DOC 4.19 MB)

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Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  1. 1.Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhanChina
  2. 2.Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemical EngineeringHuanggang Normal UniversityHuanggang CityChina

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