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Gold Bulletin

, Volume 51, Issue 3, pp 75–83 | Cite as

A multi-size study of gold nanoparticle degradation and reformation in ceramic glazes

  • Nathan NL. Dinh
  • Luke T. DiPasquale
  • Michael C. Leopold
  • Ryan H. Coppage
Original Paper
  • 131 Downloads

Abstract

Most traditional ceramic glazes employ high amounts of transition metal colorants that are toxic to the environment and can cause health issues in humans through surface leaching. Gold nanoparticles (Au-NPs) have been found to be environmentally friendly and non-toxic alternative metal colorant in ceramic glazes. The plasmon band observed with Au-NPs can result in vibrant solutions by manipulating NP size, shape, and concentration; however, the effects of traditional firing in both reductive and oxidative kilns on Au-NPs are poorly understood. Aside from ancient art processes whose mechanisms have not been fully explored, the use of Au-NPs as suspended ceramic glaze colorants remains somewhat unexplored. Au-NPs have been previously reported to diminish in size during sintering and possess significant differences in concentration with respect to reduction and oxidation firing atmospheres. As a means of studying possible degradation/renucleation processes within the glaze during firing, a systematic study introducing different diameter Au-NPs into the glaze materials was conducted with transmission electron microscopy and reflectance spectroscopy used to probe possible mechanisms which showed changes to Au-NP diameter and color intensity, making this work applicable to industry and art current practices.

Keywords

Gold nanoparticles Ceramics Glazes Firing Reduction Oxidation Surface plasmon resonance 

Notes

Acknowledgements

We would like to acknowledge Jeff Vick at the Visual Arts Center of Richmond, the VACR facility, and staff for use of their kilns. We would also like to greatly acknowledge Christie Lacy at the University of Richmond. We would like to thank Dr. Raymond Dominey (University of Richmond) for his insights into this work.

Funding information

This research was generously supported by funding from Camille and Henry Dreyfus Foundation - Henry Dreyfus Teacher Scholar Award (MCL), the Floyd D. and Elisabeth S. Gottwald Endowed Chair of Chemistry (MCL), and the University of Richmond’s IIS Program (NNLD) and School of Arts and Sciences (LTD).

Supplementary material

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ESM 1 (PPTX 13073 kb)

References

  1. 1.
    Hashmi ASK, Hutchings GJ (2006) Gold catalysis. Angew Chem Int Ed 45:7896–7936.  https://doi.org/10.1002/anie.200602454 CrossRefGoogle Scholar
  2. 2.
    Carrettin S, Blanco MC, Corma A, Hashmi ASK (2006) Heterogeneous gold-catalysed synthesis of phenols. Adv Synth Catal 348:1283–1288.  https://doi.org/10.1002/adsc.200606099 CrossRefGoogle Scholar
  3. 3.
    Leopold MC, Doan TT, Mullaney MJ, Loftus AF, Kidd CM (2015) Electrochemical characterization of self-assembled monolayers on gold substrates derived from thermal decomposition of monolayer-protected cluster films. J Appl Electrochem 45:1069–1084.  https://doi.org/10.1007/s10800-015-0880-6 CrossRefGoogle Scholar
  4. 4.
    Wayu MB, Pannell MJ, Leopold MC (2016) Layered xerogel films incorporating monolayer-protected cluster networks on platinum-black-modified electrodes for enhanced sensitivity in first-generation uric acid biosensing. ChemElectroChem 3:1245–1252.  https://doi.org/10.1002/celc.201600164 CrossRefGoogle Scholar
  5. 5.
    Christopher Corti, Richard Holliday (2010) Purple of Cassius gold enamels. In: Gold: science and applications. Taylor & Francis Group, Boca Raton, pp 350–357Google Scholar
  6. 6.
    F. Springer (1963) Glazes. In: Industrial ceramics. Chapman & Hall, pp 647–650Google Scholar
  7. 7.
    El-Brolossy TA, Abdallah T, Mohamed MB et al (2008) Shape and size dependence of the surface plasmon resonance of gold nanoparticles studied by Photoacoustic technique. Eur Phys J Spec Top 153:361–364.  https://doi.org/10.1140/epjst/e2008-00462-0 CrossRefGoogle Scholar
  8. 8.
    Eustis S, El-Sayed AM (2006) Why gold nanoparticles are more precious than pretty gold: noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes. Chem Soc Rev 35:209–217.  https://doi.org/10.1039/B514191E CrossRefGoogle Scholar
  9. 9.
    Haslbeck S, Martinek K-P, Stievano L, Wagner FE (2007) Formation of gold nanoparticles in gold ruby glass: the influence of tin. In: Lippens P-E, Jumas J-C, Génin J-MR (eds) ICAME 2005. Springer Berlin Heidelberg, pp 89–94Google Scholar
  10. 10.
    Blosi M, Albonetti S, Gatti F, Baldi G, Dondi M (2012) Au–Ag nanoparticles as red pigment in ceramic inks for digital decoration. Dyes Pigments 94:355–362.  https://doi.org/10.1016/j.dyepig.2012.01.006 CrossRefGoogle Scholar
  11. 11.
    González AL, Noguez C, Beránek J, Barnard AS (2014) Size, shape, stability, and color of plasmonic silver nanoparticles. J Phys Chem C 118:9128–9136.  https://doi.org/10.1021/jp5018168 CrossRefGoogle Scholar
  12. 12.
    Gole A, Murphy CJ (2004) Seed-mediated synthesis of gold nanorods: role of the size and nature of the seed. Chem Mater 16:3633–3640.  https://doi.org/10.1021/cm0492336 CrossRefGoogle Scholar
  13. 13.
    Rioux D, Meunier M (2015) Seeded growth synthesis of composition and size-controlled gold–silver alloy nanoparticles. J Phys Chem C 119:13160–13168.  https://doi.org/10.1021/acs.jpcc.5b02728 CrossRefGoogle Scholar
  14. 14.
    Lambertson RH, Lacy CA, Gillespie SD et al (2017) Gold nanoparticle colorants as traditional ceramic glaze alternatives. J Am Ceram Soc:3943–3951.  https://doi.org/10.1111/jace.14928
  15. 15.
    Thanh NTK, Maclean N, Mahiddine S (2014) Mechanisms of nucleation and growth of nanoparticles in solution. Chem Rev 114:7610–7630.  https://doi.org/10.1021/cr400544s CrossRefGoogle Scholar
  16. 16.
    Nguyen DT, Kim D-J, So MG, Kim K-S (2010) Experimental measurements of gold nanoparticle nucleation and growth by citrate reduction of HAuCl4. Adv Powder Technol 21:111–118.  https://doi.org/10.1016/j.apt.2009.11.005 CrossRefGoogle Scholar
  17. 17.
    Cavalcante PMT, Dondi M, Guarini G, Raimondo M, Baldi G (2009) Colour performance of ceramic nano-pigments. Dyes Pigments 80:226–232.  https://doi.org/10.1016/j.dyepig.2008.07.004 CrossRefGoogle Scholar
  18. 18.
    Kargar F, Shahtaheri SJ, Golbabaei F, Barkhordari A, Rahimi-Froushani A, Khadem M (2013) Evaluation of occupational exposure of glazers of a ceramic industry to cobalt blue dye. Iran J Public Health 42:868–875Google Scholar
  19. 19.
    Uzairu JAOA, Gimba CE (2010) Heavy metal assessment of some soft plastic toys imported into Nigeria from China. J Environ Chem Ecotoxicol 2:126–130Google Scholar
  20. 20.
    Constant C, Ogden S (1996) The Potter’s Palette. Iola, Wisconsin, Krause Publications, Inc.Google Scholar
  21. 21.
    Sheets RW (1997) Extraction of lead, cadmium and zinc from overglaze decorations on ceramic dinnerware by acidic and basic food substances. Sci Total Environ 197:167–175.  https://doi.org/10.1016/S0048-9697(97)05431-4 CrossRefGoogle Scholar
  22. 22.
    Galvez M, Vanable L, Forman JA et al (2004) Childhood lead poisoning from commercially manufactured French ceramic dinnerware. Morb Mortal Wkly Rep 53:584–586Google Scholar
  23. 23.
    Ahmad MI, Abdelfatah S, Al-Meer S (2017) Health and safety concerns: quantitative studies of leaching of metals from glazed surfaces of traditional ceramic potteries. Int J Public Health Res 5:13Google Scholar
  24. 24.
    Carbert J (1980) Gold-based enamel colours. Gold Bull 13:144–150.  https://doi.org/10.1007/BF03215460 CrossRefGoogle Scholar
  25. 25.
    Connor EE, Mwamuka J, Gole A et al (2005) Gold nanoparticles are taken up by human cells but do not cause acute cytotoxicity. Small 1:325–327.  https://doi.org/10.1002/smll.200400093 CrossRefGoogle Scholar
  26. 26.
    Whitmore PM, Baile C (1997) Further studies on transparent glaze fading: chemical and appearance kinetics. J Am Institude Conserv 36:207–230CrossRefGoogle Scholar
  27. 27.
    Dabbousi BO, Rodriguez-Viejo J, Mikulec FV, Heine JR, Mattoussi H, Ober R, Jensen KF, Bawendi MG (1997) (CdSe)ZnS core−shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites. J Phys Chem B 101:9463–9475.  https://doi.org/10.1021/jp971091y CrossRefGoogle Scholar
  28. 28.
    Evanoff DD, Chumanov G (2005) Synthesis and optical properties of silver nanoparticles and arrays. ChemPhysChem 6:1221–1231.  https://doi.org/10.1002/cphc.200500113 CrossRefGoogle Scholar
  29. 29.
    Fu YH, Kuznetsov AI, Miroshnichenko AE, Yu YF, Luk’yanchuk B (2013) Directional visible light scattering by silicon nanoparticles. Nat Commun 4:1527.  https://doi.org/10.1038/ncomms2538 CrossRefGoogle Scholar
  30. 30.
    Kang Y, Liang D, Mehra S, Huo Y, Chen Y, Christoforo MG, Salleo A, Harris JS (2015) Efficiency enhancement of gallium arsenide photovoltaics using solution-processed zinc oxide nanoparticle light scattering layers. J Nanomater 2015:e263734 . doi:  https://doi.org/10.1155/2015/263734, 1, 6
  31. 31.
    Han S-H, Lee S, Shin H, Suk Jung H (2011) A quasi-inverse opal layer based on highly crystalline TiO2 nanoparticles: a new light-scattering layer in dye-sensitized solar cells. Adv Energy Mater 1:546–550.  https://doi.org/10.1002/aenm.201100084 CrossRefGoogle Scholar
  32. 32.
    Jana NR, Gearheart L, Murphy CJ (2001) Seeding growth for size control of 5−40 nm diameter gold nanoparticles. Langmuir 17:6782–6786.  https://doi.org/10.1021/la0104323 CrossRefGoogle Scholar
  33. 33.
    Kimling J, Maier M, Okenve B, Kotaidis V, Ballot H, Plech A (2006) Turkevich method for gold nanoparticle synthesis revisited. J Phys Chem B 110:15700–15707.  https://doi.org/10.1021/jp061667w CrossRefGoogle Scholar
  34. 34.
    Shimizu T, Teranishi T, Hasegawa S, Miyake M (2003) Size evolution of alkanethiol-protected gold nanoparticles by heat treatment in the solid state. J Phys Chem B 107:2719–2724.  https://doi.org/10.1021/jp026920g CrossRefGoogle Scholar
  35. 35.
    Carter B, Norton G (2013) Combustion furnaces. In: Ceramic materials: science and engineering. Springer, New York, pp 144–145CrossRefGoogle Scholar
  36. 36.
    J Hirschhorn (1969) Introduction to powder metallurgy. American Powder Metallurgy Institute, New YorkGoogle Scholar
  37. 37.
    Espe W, Knoll M, Wilder M (1950) Getter Materials. Electronics 23:80–86Google Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Nathan NL. Dinh
    • 1
  • Luke T. DiPasquale
    • 1
  • Michael C. Leopold
    • 1
  • Ryan H. Coppage
    • 1
  1. 1.Department of Chemistry, Gottwald Center for the SciencesUniversity of RichmondRichmondUSA

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