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Arabian Journal for Science and Engineering

, Volume 43, Issue 7, pp 3547–3556 | Cite as

Application of SBA-15/Diphenyl Carbazon/SDS Nanocomposite as Solid-Phase Extractor for Simultaneous Determination of Cu(II) and Zn(II) Ions

  • Ali Mirabi
  • Ali Shokuhi Rad
  • Faranak Divsalar
  • Hassan Karimi-Maleh
Research Article - Chemistry

Abstract

In the present study, trace quantities of copper(II) and zinc(II) ions in natural water, herbal and food samples was separated, preconcentrated and determined by a new nanocomposite. The nanocomposite was prepared by immobilization of diphenylcarbazone on SBA-15 nanoparticles coated with anionic surfactant sodium dodecyl sulfate. In order to investigate the effectiveness and size of the surface, SBA-15 nanoparticles and nanocomposites were analyzed by Brunauer–Emmett–Teller technique, transmission electron microscope, elemental analysis map, energy-dispersive X-ray spectroscopy, thermogravimetric analysis and elemental analysis CHNS. The effective factors such as pH, adsorbent amount, extraction time, eluent concentration and acid recovery volume were investigated and optimized for quantitative determination of Cu(II) and Zn(II) ions. Figures of merit such as precision, accuracy, limit of detection, enhancement factor and enrichment factor were obtained with good results. The linear range of the calibration graph was between 0.5 and 100 ng \(\hbox {mL}^{-1}\) for Cu(II) and between 1 and 500 ng \(\hbox {mL}^{-1}\) for Zn(II), and the detection limit was calculated to be 0.21 and \(0.93\,\hbox {ng} \,\hbox {mL}^{-1}\), respectively. Relative standard deviations of Cu and Zn were calculated to be 1.54 and 1.31%, respectively.

Keywords

SBA-15 Copper and zinc determination Preconcentration Nanocomposites Solid-phase extraction 

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Notes

Acknowledgements

The authors thank the research council at Islamic Azad University of Qaemshahr for Financial Support.

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Copyright information

© King Fahd University of Petroleum & Minerals 2017

Authors and Affiliations

  1. 1.Department of Chemistry, Qaemshahr BranchIslamic Azad UniversityQaemshahrIran
  2. 2.Department of Chemical Engineering, Qaemshahr BranchIslamic Azad UniversityQaemshahrIran
  3. 3.Department of ChemistryGraduate University of Advanced TechnologyKermanIran

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