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Arabian Journal for Science and Engineering

, Volume 43, Issue 11, pp 5819–5836 | Cite as

A Comparative Study of Y Zeolite Catalysts Derived from Natural and Commercial Silica: Synthesis, Characterization, and Catalytic Performance

  • Najat J. Saleh
  • Bashir Y. Sherhan Al-Zaidi
  • Zainab M. Sabbar
Research Article - Chemical Engineering
  • 58 Downloads

Abstract

Hydrothermal synthesis process of the zeolite type Y and production of different forms (i.e., NaY, \(\hbox {NH}_{4}\hbox {Y}\), and HY) were accomplished. Both natural silica nanoparticles derived from rice husk (RH) and commercial Ludox as a source of silica were applied for preparing a number of type NaY zeolite catalysts. The aim of this study was to investigate the effects of adding different weight percentages of natural and/or commercial silica into either seed gel or feedstock gel on the synthesis, characterization, and catalytic performance of Y zeolite. A high purity of nanosilica (about 98.9 wt%) was generated using the precipitation method, followed by burning to reduce the metallic ingredients from rice husk ash (RHA). The thermal behavior of the RH was investigated by TGA, while the composition of nanosilica and the chemical analysis of RHA after acid treatment were analyzed by XRF. In addition, the properties of catalysts were characterized using XRD, BET, SEM, EDX, AAS, and FTIR. The catalytic activity and selectivity of prepared Y catalysts were studied using the laboratory-scale fixed-bed catalytic cracking unit throughout the \(\hbox {C}_{6}\hbox {H}_{14}\) cracking reaction at 450 \({^{\circ }}\hbox {C}\). The results indicate significant enhancements in the catalytic performance of the produced nanosilica catalyst created by adding only natural silica in both feedstock gel and seed gel for the preparation of overall Y zeolite gel.

Keywords

Rice husk Silica nanoparticles Zeolite Y preparation and characterization Catalytic cracking reaction 

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Notes

Acknowledgements

We are indebted to the Petroleum Research and Development Center—Ministry of Oil in the Republic of Iraq, for full financial support of this project. We would like to acknowledge the assistance of the laboratory staff in both Chemical Engineering Departments at the University of Technology and the University of Baghdad where the majority of this research was conducted. Our great appreciation is also given to our colleagues in the Chemical Engineering—University of Sheffield, and the glassware manufacturing plant in the University of Manchester—UK, for their assistance in providing the research facilities.

References

  1. 1.
    Bekkum, H.V.; Flanigen, E.M.; Jacobs, P.A.; Jansen, J.C.: Introduction to Zeolite Science and Practice, 2nd edn. Elsevier, New York (2001)Google Scholar
  2. 2.
    Barrer, R.M.: Hydrothermal Chemistry of Zeolites. Academic, London, New York (1982)Google Scholar
  3. 3.
    Ribeiro, F.R.; Rodrigues, A.: Zeolites: Science and Technology, pp. 327–338. Martinus Nijhoff, Leiden (1984)CrossRefGoogle Scholar
  4. 4.
    Chou, Y.U.: Synthesis, Characterization and Catalysis of Mesoporous ZSM-5 Catalysts. Ph.D. thesis, School of Chemical Engineering and Analytical Science, University of Manchester, UK (2006)Google Scholar
  5. 5.
    McCormick, A.V.; Bell, A.T.; Radke, C.J.: Multinuclear NMR investigation of the formation of aluminosilicate anions. J. Phys. Chem. 93(5), 1741–1744 (1989)CrossRefGoogle Scholar
  6. 6.
    Prasetyoko, D.; Ramli, Z.; Endud, S.; Hamdan, H.; Sulikowski, B.: Conversion of rice husk ash to zeolite beta. Waste Manage 26, 1173–1179 (2006)CrossRefGoogle Scholar
  7. 7.
    Wittayakun, J.; Khemthong, P.; Prayoonpokarach, S.: Synthesis and characterization of zeolite Y from rice husk silica. Korean J. Chem. Eng. 25(4), 861–864 (2008)CrossRefGoogle Scholar
  8. 8.
    Mohamed, R.M.; Mkhalid, I.A.; Barakat, M.A.: Rice husk ask as a renewable source for the production of zeolite NaY and its characterization. Arab. J. Chem. 8, 48–53 (2015)CrossRefGoogle Scholar
  9. 9.
    Sheng, H.; Shan, J.; Jinfu, W.; Zhanwen, W.; Young, J.: Young, Silica White Obtained from Rice Husk in a Fluidized Bed, pp. 232–238. Elsevier B. V., Amsterdam (2001)Google Scholar
  10. 10.
    Sidheswaran, P.; Bhat, A.N.: Recovery of amorphous silica in pure form from rice husk. Trans. Indian Ceram. Soc. 55(4), 93–96 (1996)CrossRefGoogle Scholar
  11. 11.
    Saudi, H.A.; Salem, S.M.; Mohammad, S.S.; Mostafa, A.G.; Hassaan, M.Y.: Utilization of pure silica extracted from rice husk and FTIR structural analysis of the prepared glasses. Am. J. Phys. Appl. 3(3), 97–105 (2015)Google Scholar
  12. 12.
    Rafiee, E.; Shahebrahimi, S.; Feyzi, M.; Shaterzadeh, M.: Optimization of synthesis and characterization of nanosilica produced from rice husk (a common waste material). Int. Nano Lett. 2(1), 29 (2012)CrossRefGoogle Scholar
  13. 13.
    Adam, F.; Appaturi, J.N.; Iqbal, A.: The utilization of rice husk silica as a catalyst: review and recent progress. Catalysis Today 190, 2–14 (2012)CrossRefGoogle Scholar
  14. 14.
    Jyoti, P.N.: Preparation and Characterization of Bioactive Silica-based Ceramics Derived from Rice Husk Ash. Ph.D. thesis, Department of Ceramic Eng. - National Institute of Technology, Rourkela (2010)Google Scholar
  15. 15.
    Anggoro, D.D.; Purbasari, A.: The optimization of production zeolite Y catalyst from RHA by response surface methodology. Reaktor 12(3), 14–18 (2009)Google Scholar
  16. 16.
    Rahman, M.M.; Hasnida, N.; Wan Nik, W.B.: Preparation of zeolite Y using local raw material rice husk as a silica source. J. Sci. Res. 1(2), 285–291 (2009)Google Scholar
  17. 17.
    Saceda, J.J.F.; De Leon, R.L.; Rintramee, K.; Prayoonpokarach, S.; Wittayakun, J.: Properties of silica from rice husk and rice husk ash and their utilization for zeolite Y synthesis. Quimica Para Um Mundo Melhor 34(8), 1394–1397 (2011)Google Scholar
  18. 18.
    Rahman, M.M.; Awang, M.B.; Yusof, A.M.: Preparation of pure silica oxide (\(\text{ SiO }_{2})\) and zeolite-Y from rice husk as an ion exchange for emergency water treatment system using in flood affected area. Adv. Mater. Res. Trans. Tech Publ. Switz. 445, 821–826 (2012)Google Scholar
  19. 19.
    Mohamed, R.M.M.; Mkhalid, I.A.A.; Salam, M.A.; Barakat, M.A.A.; Salam, M.Abdel: Zeolite Y from rice husk ash encapsulated with \(\text{ Ag-TiO }_{2}\): characterization and applications for photocatalytic degradation catalysts. Desalin. Water Treat. 51(40–42), 7562–7569 (2013)CrossRefGoogle Scholar
  20. 20.
    Rosman, N.; Harun, Z.; Bin Wahab, M.S.; Hubadillah, S.K.; Aminudin, N.N.: Phase transformation of rice husk ash in the synthesis of NaY zeolite: effect of ageing in short crystalline duration. Aust. J. Basic Appl. Sci. 8(15), 152–159 (2013)Google Scholar
  21. 21.
    Salama, T.M.; Ali, I.O.; Gumaa, H.A.; Lateef, M.A.; Bakr, M.F.: Novel synthesis of NaY zeolite from rice husk silica: modification with Zno and Zns for antibacterial application. Chem. Sci. J. 7(1), 1–9 (2016)CrossRefGoogle Scholar
  22. 22.
    Azizi, S.N.; Ghasemi, S.; Kavian, S.: Synthesis and characterization of NaX nanozeolite using stem sweep as silica source and application of Ag-modified nanozeolite in electrocatalytic reduction of \(\text{ H }_{2}\text{ O }_{2}\). Biosens. Bioelectron. 62, 1–7 (2014)CrossRefGoogle Scholar
  23. 23.
    Abbasian, S.; Taghizadeh, M.: Effects of microwave and ultrasonic-assisted aging on the synthesis of H-ZSM-5 nanozeolite and its catalytic performance in methanol dehydration. Int. J. Chem. Reactor Eng. 12(1), 355–362 (2014)CrossRefGoogle Scholar
  24. 24.
    Mirzababaei, S.N.; Taghizadeh, M.; Alizadeh, E.: Synthesis of surfactant-modified ZSM-5 nanozeolite for the removal of nickel (II) from aqueous solution. Desalin. Water Treat. 57(26), 12204–12215 (2015)CrossRefGoogle Scholar
  25. 25.
    Zhu, M.X.; Fu, Y.; Yin, H.; Feng, Y.; Shen, L.; Wang, A.; Li, J.; Ni, W.; Xie, X.: Selective chlorination of Toluene to \(p\)-Chlorotoluene catalyzed by nanosized zeolite K-L catalysts. J. Nanosci. Nanotechnol. 15(8), 6150–6159 (2015)CrossRefGoogle Scholar
  26. 26.
    Esmaeili, A.; Far, F.M.: Synthesis of granular nanozeolite NaA from Phragmites australis for removal of total petroleum hydrocarbon. Water Qual. Res. J. Can. 51(4), 307–320 (2016)CrossRefGoogle Scholar
  27. 27.
    Al-Zaidi, B.Y.; Holmes, R.J.; Garforth, A.A.: Study of the relationship between framework cation levels of Y zeolites and behavior during calcination, steaming, and n-Heptane cracking processes. Ind. Eng. Chem. Res. 51(19), 6648–6657 (2012)CrossRefGoogle Scholar
  28. 28.
    Kumar, A.; Mohanta, K.; Kumar, D.; Parkash, Om: Properties and industrial applications of rice husk: a review. Int. J. Emerg. Technol. Adv. Eng. 2(10), 86–90 (2012)Google Scholar
  29. 29.
    Nittaya, T.; Apinon, N.: Preparation of nanosilica powder from rice husk ash by precipitation method. Chiang Mai J. Sci. 35, 206–211 (2008)Google Scholar
  30. 30.
    Krishnarao, R.; Subrahmanyam, J.; Kumar, T.J.: Studies on the formation of black particles in rice husk silica ash. J. Eur. Ceram. Soc. 21(1), 99–104 (2001)CrossRefGoogle Scholar
  31. 31.
    Real, C.; Alcala, D.; Maria, C.; Jose, M.: Preparation of silica from rice husks. J. Am. Ceram. Soc. 79(8), 2012–2016 (2008)CrossRefGoogle Scholar
  32. 32.
    Ikram, N.; Akhter, M.: X-ray diffraction analysis of silicon prepared from rice husk ash. J. Mater. Sci. 23(7), 2379–2381 (1988)CrossRefGoogle Scholar
  33. 33.
    Ojha, k; Pradhan, N.C.; Samanta, A.N.: Zeolite from fly ash: synthesis and characterization. Bull. Mater. Sci. 27(6), 555–564 (2004)CrossRefGoogle Scholar
  34. 34.
    Scott, M.A.; Kathleen, A.C.; Brabir, K.D.: Handbook of Zeolite Science and Technology. Marcel Dekker Inc., New York (2003)Google Scholar
  35. 35.
    Matti, A.H.; Surchi, K.M.: Comparison the properties of zeolite NaY synthesized by different procedures. Int. J. Innov. Res. Sci. 3(6), 2319–8753 (2014)Google Scholar
  36. 36.
    Sharma, P.; Yeo, J.; Kim, D.K.; Cho, C.H.: Organic additive free synthesis of mesoporous naon-crystalline NaA zeolite using high concentration inorganic precursors. J. Mater. Chem. 22, 2838 (2012)CrossRefGoogle Scholar
  37. 37.
    Das, S.K.; Mahanta, S.P.; Bania, K.K.: Oxidative coupling of 2-naphthol by zeolite-Y supported homo- and hetero-metallic trinuclear acetate clusters. RSC Adv. 4, 51496–51509 (2014)CrossRefGoogle Scholar
  38. 38.
    Deka, J.; Satyanarayana, L.; Karunakar, G.V.; Bhattacharyya, P.K.; Bania, K.K.: Chiral modification of copper exchanged zeolite-Y with cinchonidine and its application in the asymmetric Henry reaction. The Royal Society of. R. Soc. Chem. 44, 20949–20963 (2015)Google Scholar
  39. 39.
    Liu, J.; Ying, P.; Xin, Q.; Li, C.: Basic sites of Y zeolite characterized by the adsorption of boric acid trim-ethyl ester. Zeolites 19, 197–199 (1997)CrossRefGoogle Scholar
  40. 40.
    Ramsaran, A.: Desilicated ZSM-5 Zeolite as Catalyst for the Dehydration of Ethanol. Ph.D. Thesis – Concordia University (1996)Google Scholar
  41. 41.
    Weitkamp, J.; Puppe, L.: Catalysis and Zeolites: Fundamentals and Applications. Springer, New York (1999)CrossRefGoogle Scholar
  42. 42.
    Kotrel, S.; Knözinger, H.; Gates, B.C.: The Haag–Dessau mechanism of protolytic cracking of Alkanes. Microporous Mesoporous Mater. 35–36(3), 11–20 (2000)CrossRefGoogle Scholar

Copyright information

© King Fahd University of Petroleum & Minerals 2017

Authors and Affiliations

  • Najat J. Saleh
    • 1
  • Bashir Y. Sherhan Al-Zaidi
    • 1
  • Zainab M. Sabbar
    • 1
  1. 1.Chemical Engineering DepartmentThe University of TechnologyBaghdadIraq

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