Arabian Journal for Science and Engineering

, Volume 41, Issue 6, pp 2229–2237 | Cite as

Arsenic and Boron Removal by Electrocoagulation with Aluminum Electrodes

  • Berrin Zeliha Can
  • Recep BoncukcuoğluEmail author
  • Alper Erdem Yılmaz
  • Baybars Ali Fil
Research Article - Chemistry


Some boron deposits in Turkey contain considerable amounts of arsenic. Arsenic in the boron deposits can create a great risk due to its environmental effects on surface and underground waters. Water sources containing more than a certain concentration of boron and arsenic have negative effects on plants, animals and human beings. Thus, their removals are necessary. In this paper, the removal of arsenic (As) and boron (B) from aqueous solutions by electrocoagulation using aluminum (Al) electrode material was investigated. Specifically, the effects of initial pH, initial arsenic and boron concentrations and operating time on the performance of EC were investigated. Experiments were carried out with different pHs ranging from 2 to 8. Results showed that initial pH was highly effective on the efficiency and high removal efficiencies were observed at initial pH of 4.0 for both arsenic and boron. Initial arsenic and boron concentration affected the removal efficiencies. Arsenic removal efficiency decreased with increasing boron concentration, and boron removal efficiency decreased with increasing arsenic concentration. The results also showed that boron ions prevented to arsenic removal and boron ions competed with arsenic ions. This situation led to the low arsenic and boron removal.


Aluminum electrode Arsenic removal Boron removal Electrocoagulation 


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  1. 1.
    Helvacı, C.: Mining, dressing and marketing problems of borate minerals. In: Presented at the 6th International Industrial Minerals Symposium,  İzmir, (2007)Google Scholar
  2. 2.
    Koca S., Savas M., Koca H.: Flotation of colemanite from realgar. Miner. Eng. 16, 479–482 (2003)CrossRefGoogle Scholar
  3. 3.
    Duban, A.: Investigation of mineral processing of colemanite ore including arsenic minerals in the Emet region. Master, Institute of Science and Technology,  İstanbul University,  İstanbul, Turkey (2004)Google Scholar
  4. 4.
    Basha C.A., Selvi S.J., Ramasamy E., Chellammal S.: Removal of arsenic and sulphate from the copper smelting industrial effluent. Chem. Eng. J. 141, 89–98 (2008)CrossRefGoogle Scholar
  5. 5.
    WHO: Guidelines for Drinking Water Quality, Third edn.. WHO, Geneva (2006)Google Scholar
  6. 6.
    Yilmaz A.E., Boncukcuoğlu R., Kocakerim M.M., Yilmaz M.T., Paluluoğlu C.: Boron removal from geothermal waters by electrocoagulation. J. Hazard. Mater. 153, 146–151 (2008)CrossRefGoogle Scholar
  7. 7.
    Vasudevan S., Sheela S.M., Lakshmi J., Sozhan G.: Optimization of the process parameters for the removal of boron from drinking water by electrocoagulation—a clean technology. J. Chem. Technol. Biotechnol. 85, 926–933 (2010)CrossRefGoogle Scholar
  8. 8.
    Vasudevan S., Lakshmi J.: Electrochemical removal of boron from water: adsorption and thermodynamic studies. Can. J. Chem. Eng. 90, 1017–1026 (2012)CrossRefGoogle Scholar
  9. 9.
    Vasudevan S., Lakshmi J., Sozhan G.: Electrochemically assisted coagulation for the removal of boron from water using zinc anode. Desalination 310, 122–129 (2013)CrossRefGoogle Scholar
  10. 10.
    Gomes J.A.G., Daida P., Kesmez M., Weir M., Moreno H., Parga J.R., Irwin G., McWhinney H., Grady T., Peterson E., Cocke D.L.: Arsenic removal by electrocoagulation using combined Al–Fe electrode system and characterization of products. J. Hazard. Mater. 139, 220–231 (2007)CrossRefGoogle Scholar
  11. 11.
    Vasudevan S., Lakshmi J., Sozhan G.: Studies relating to removal of arsenate by electrochemical coagulation: optimization, kinetics, coagulant characterization. Sep. Sci. Technol. 45, 1313–1325 (2010)CrossRefGoogle Scholar
  12. 12.
    Vasudevan S., Lakshmi J., Sozhan G.: Studies on the removal of arsenate by electrochemical coagulation using aluminum alloy anode. Clean 38, 506–515 (2010)Google Scholar
  13. 13.
    Vasudevan S., Lakshmi J., Sozhan G.: Studies on the removal of arsenate from water through electrocoagulation using direct and alternating current. Desalination Water Treat. 48, 163–173 (2012)CrossRefGoogle Scholar
  14. 14.
    Xu Y., Jiang J.Q., Quill K., Simon J., Shettle K.: Electrocoagulation: a new approach for the removal of boron containing wastes. Desalination Water Treat. 2, 131–138 (2009)CrossRefGoogle Scholar
  15. 15.
    Daneshvar N., Ashassi Sorkhabi H., Kasiri M.B.: Decolorization of dye solution containing Acid Red 14 by electrocoagulation with a comparative investigation of different electrode connections. J. Hazard. Mater. 112, 55–62 (2004)CrossRefGoogle Scholar
  16. 16.
    Vasudevan S., Oturan M.: Electrochemistry: as cause and cure in water pollution—an overview. Environ. Chem. Lett. 12, 97–108 (2014)CrossRefGoogle Scholar
  17. 17.
    Chen G.: Electrochemical technologies in wastewater treatment. Sep. Purif. Technol. 38, 11–41 (2004)CrossRefGoogle Scholar
  18. 18.
    Ihos M., Negrea A., Lupa L., Ciopec M., Negrea P.: Comparative study of As (III) removal efficiency from water by electrocoagulation and conventional coagulation. Chem. Bull. Politehnica 50, 87–90 (2005)Google Scholar
  19. 19.
    Nielson K., Smith D.W.: Ozone-enhanced electroflocculation in municipal wastewater treatment. J. Environ. Eng. Sci. 4, 65–76 (2005)CrossRefGoogle Scholar
  20. 20.
    Ghosh D., Solanki H., Purkait M.K.: Removal of Fe(II) from tap water by electrocoagulation technique. J. Hazard. Mater. 155, 135–143 (2008)CrossRefGoogle Scholar
  21. 21.
    Jotin R., Ibrahim S., Halimoon N.: Electro coagulation for removal of chemical oxygen demand in sanitary landfill leachate. Int. J. Environ. Sci. 3, 921–930 (2012)Google Scholar
  22. 22.
    Yilmaz A.E., Boncukcuoglu R., Bayar S., Fil B.A., Kocakerim M.M.: Boron removal by means of chemical precipitation with calcium hydroxide and calcium borate formation. Korean J. Chem. Eng. 29, 1382–1387 (2012)CrossRefGoogle Scholar
  23. 23.
    Holak W.: Gas-sampling technique for arsenic determination by atomic absorption spectrophotometry. Anal. Chem. 41, 1712–1713 (1969)CrossRefGoogle Scholar
  24. 24.
    Can B.Z., Boncukcuoglu R., Yilmaz A.E., Fil B.A.: Effect of some operational parameters on the arsenic removal by electrocoagulation using iron electrodes. J. Environ. Health Sci. Eng. 12, 1–10 (2014)CrossRefGoogle Scholar
  25. 25.
    Macedonio F., Drioli E.: Pressure-driven membrane operations and membrane distillation technology integration for water purification. Desalination 223, 396–409 (2008)CrossRefGoogle Scholar
  26. 26.
    Ali I., Khan T., Asim M.: Removal of Arsenic from Water by Electrocoagulation and Electrodialysis Techniques. Sep. Purif. Rev. 40, 25–42 (2011)CrossRefGoogle Scholar
  27. 27.
    Holt P.K., Barton G.W., Wark M., Mitchell C.A.: A quantitative comparison between chemical dosing and electrocoagulation. Colloid Surf. A 211, 233–248 (2002)CrossRefGoogle Scholar
  28. 28.
    Amooey A., Ghasemi S., Mirsoleimani-azizi S., Gholaminezhad Z., Chaichi M.: Removal of Diazinon from aqueous solution by electrocoagulation process using aluminum electrodes. Korean J. Chem. Eng. 31, 1016–1020 (2014)CrossRefGoogle Scholar
  29. 29.
    Chowdhury, Z.; Kommineni, S.; Narasimhan, R.; Brereton, J.; Amy, G.; Sinha, S.: Implementation of arsenic treatment systems--part 1, Process selection. American Water Works Association Research Foundation and American Water Works Association, USA (2002)Google Scholar
  30. 30.
    Chowdhury, Z.; Kommineni, S.; Narasimhan, R.; Brereton, J.; Amy, G.; Sinha, S.: Implementation of arsenic treatment systems--part 2, Process selection. American Water Works Association Research Foundation and American Water Works Association, USA (2002)Google Scholar
  31. 31.
    Bayar, S.; Yilmaz, A.E.; Boncukcuoğlu, R.; Fìl, B.A.; Kocakerìm, M.M.: Effects of operational parameters on cadmium removal from aqueous solutions by electrochemical coagulation. Desalination Water Treat. 51, 2635–2643 (2013).Google Scholar

Copyright information

© King Fahd University of Petroleum & Minerals 2015

Authors and Affiliations

  • Berrin Zeliha Can
    • 1
  • Recep Boncukcuoğlu
    • 2
    Email author
  • Alper Erdem Yılmaz
    • 2
  • Baybars Ali Fil
    • 3
  1. 1.8st Regional Directorate of State Hydraulic Works (DSİ)ErzurumTurkey
  2. 2.Department of Environmental Engineering, Engineering FacultyAtatürk UniversityErzurumTurkey
  3. 3.Department of Environmental Engineering, Engineering-Architecture FacultyBalikesir UniversityBalikesirTurkey

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