Spectroscopic Analysis of NIR-Dye Sensitization in Bulk Heterojunction Polymer Solar Cells
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The photovoltaic conversion efficiency for near-infrared (NIR) sunlight is improved successfully by dye sensitization of bulk heterojunction polymer solar cells, in which the active layer was prepared by a ternary blend of poly(3-hexylthiophene), a fullerene derivative (1-(3-methoxycarbonyl)propyl-1-phenyl-[6,6]-methanofullerene), and an NIR dye, silicon phthalocyanine bis(trihexylsilyl oxide). The mechanism of the NIR-dye sensitization is studied by femtosecond transient absorption spectroscopy.
KeywordsPolymer solar cell Near-infrared dye Transient absorption spectroscopy Bulk heterojunction Photovoltaic conversion efficiency
- Green, M.A., K. Emery, Y. Hishikawa, W. Warta, and E.D. Dunlop. 2012. Solar cell efficiency tables (version 39). Progress in Photovoltaics: Research and Applications 20: 12–20.Google Scholar
- Honda, S., S. Yokoya, H. Ohkita, H. Benten, and S. Ito. 2011. Light-harvesting mechanism in polymer/fullerene/dye ternary blends studied by transient absorption spectroscopy. Journal of Physical Chemistry C 115: 11306–11317.Google Scholar