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Synthesis and Characterization of DPP-Based Conjugated Polymers via Dehydrogenative Direct Alkenylation Polycondensation

  • Jiwon Lee
  • Hea Jung Park
  • Jung Min Joo
  • Do-Hoon HwangEmail author
Communication
  • 3 Downloads

Abstract

Two π-conjugated polymers were successfully synthesized by polycondensation via dehydrogenative direct alkenylation with Pd(II) catalyst (Pd(OAc)2) without directing groups in an atom- and step-economical and eco-friendly manner. Using the Pd(OAc)2/pyridine catalytic system, C-H activation of the C-5 position on the thiophene moiety of 3,6-di(thiophen-2′-yl)diketopyrrolopyrrole derivative was regioselective and the cross-coupled products were readily formed with trans-configuration. The optical, electrochemical, and thermal properties of the synthesized polymers were studied to investigate their potential applicability to semiconducting materials.

Keywords

diketopyrrolopyrrole direct alkenylation palladium dehydrogenation polycondensation 

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Supplementary material

13233_2019_7070_MOESM1_ESM.pdf (176 kb)
Macromolecular Research

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Copyright information

© The Polymer Society of Korea and Springer Nature B.V. 2019

Authors and Affiliations

  • Jiwon Lee
    • 1
  • Hea Jung Park
    • 1
  • Jung Min Joo
    • 1
  • Do-Hoon Hwang
    • 1
    Email author
  1. 1.Department of Chemistry and Chemistry Institute for Functional MaterialsPusan National UniversityBusanKorea

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