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Macromolecular Research

, Volume 24, Issue 10, pp 851–855 | Cite as

Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films

  • Ok-Joo Lee
  • Valérie Maraval
  • Anne-Marie Caminade
  • Kyungwha Chung
  • King Hang Aaron Lau
  • Kwanwoo Shin
  • Jean-Pierre Majoral
  • Wolfgang Knoll
  • Dong Ha Kim
Feature Article

Abstract

We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.

Keywords

bisdendron layer-by-layer self-assembly multilayer thin films surface plasmon resonance spectroscopy 

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References

  1. (1).
    S. Ameen, M. Song, D.-G. Kim, Y.-B. Im, H.-K. Seo, Y. S. Kim, and H.-S. Shin, Macromol. Res., 20, 30 (2012).CrossRefGoogle Scholar
  2. (2).
    K. R. Yoon, H. Lee, B. K. Rhee, and C. Jung, Macromol. Res., 12, 581 (2004).CrossRefGoogle Scholar
  3. (3).
    G. Decher, Science, 277, 1232 (1997).CrossRefGoogle Scholar
  4. (4).
    G. Decher, J. D. Hong, and J. Schmitt, Thin Solid Films, 210, 831 (1992).CrossRefGoogle Scholar
  5. (5).
    F. Caruso, R. A. Caruso, and H. Möhwald, Science, 282, 1111 (1998).CrossRefGoogle Scholar
  6. (6).
    P. T. Hammond, Adv. Mater., 16, 1271 (2004).CrossRefGoogle Scholar
  7. (7).
    C. Jiang and V. V. Tsukruk, Adv. Mater., 18, 829 (2006).CrossRefGoogle Scholar
  8. (8).
    B.-S. Kim, K.-D. Suh, and B. Kim, Macromol. Res., 16, 76 (2008).CrossRefGoogle Scholar
  9. (9).
    B. Lee, S. Kim, and J. Cho, Macromol. Res., 19, 635 (2011).CrossRefGoogle Scholar
  10. (10).
    S. W. Hong, J. H. Jeong, D. Y. Lee, and Y. Byun, Macromol. Res., 21, 911 (2013).CrossRefGoogle Scholar
  11. (11).
    Y.-S. Yang, Y.-M. Jeon, C.-W. Lee, W.-C. Chang, J.-G. Kim, M.-S. Gong, B.-K. Choi, and S.-W. Joo, Macromol. Res., 14, 251 (2006).CrossRefGoogle Scholar
  12. (12).
    A.-M. Caminade, A. Maraval, and J.-P. Majoral, Eur. J. Inorg. Chem., 2006, 887 (2006).CrossRefGoogle Scholar
  13. (13).
    V. Maraval, A. Maraval, G. Spataro, A.-M. Caminade, J.-P. Majoral, D. H. Kim, and W. Knoll, New J. Chem., 30, 1731 (2006).CrossRefGoogle Scholar
  14. (14).
    E. M. Arnett and R. Reich, J. Am. Chem. Soc., 102, 5892 (1980).CrossRefGoogle Scholar
  15. (15).
    V. Bütün, S. P. Armes, and N. C. Billingham, Macromolecules, 34, 1148 (2001).CrossRefGoogle Scholar
  16. (16).
    The boiling point of CH3I is about 43 °C.Google Scholar
  17. (17).
    T. D. Lazzara, K. H. A. Lau, A. I. Abou-Kandil, A.-M. Caminade, J.-P. Majoral, and W. Knoll, ACS Nano, 4, 3909 (2010).CrossRefGoogle Scholar
  18. (18).
    M. Kim, S. Schmitt, J. Choi, J. Krutty, and P. Gopalan, Polymers, 7, 1346 (2015).CrossRefGoogle Scholar

Copyright information

© The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2016

Authors and Affiliations

  • Ok-Joo Lee
    • 1
    • 7
  • Valérie Maraval
    • 2
  • Anne-Marie Caminade
    • 2
  • Kyungwha Chung
    • 3
  • King Hang Aaron Lau
    • 4
  • Kwanwoo Shin
    • 5
  • Jean-Pierre Majoral
    • 2
  • Wolfgang Knoll
    • 6
  • Dong Ha Kim
    • 3
  1. 1.Max Planck Institute for Polymer ResearchMainzGermany
  2. 2.Laboratoire de Chimie de Coordination, CNRSToulouse CedexFrance
  3. 3.Department of Chemistry and Nano Science, Division of Molecular and Life Sciences, College of Natural SciencesEwha Womans UniversitySeoulKorea
  4. 4.Department of Pure and Applied ChemistryUniversity of StrathclydeGlasgowUK
  5. 5.Department of Chemistry, Interdisciplinary Program of Integrated BiotechnologySogang UniversitySeoulKorea
  6. 6.AIT Austrian Institute of TechnologyViennaAustria
  7. 7.Korean Intellectual Property Office, Gov. Complex DaejeonDaejeonKorea

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