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Facile synthesis of Zn3(VO4)2/FeVO4 heterojunction and study on its photocatalytic and electrochemical properties

  • Muhammad Munir SajidEmail author
  • Naveed Akthar Shad
  • Yasir Javed
  • Sadaf Bashir Khan
  • Nasir AminEmail author
  • Zhengjun Zhang
  • Zahid Imran
  • Muhammad Imran Yousuf
Original Article
  • 5 Downloads

Abstract

First time, a novel Zn3(VO4)2/FeVO4 heterojunction nanophotocatalyst has been prepared using the slightly modified hydrothermal method by varying precursor ratios of iron and zinc salts. The physio-chemical characterizations of as-prepared nanocomposites were carried out by XRD, FESEM, EDS, XPS, BET, UV–Vis, PL, CV and EIS. Effect of molar ratio showed that Zn3(VO4)2/FeVO4 nanocomposite with molar ratio 1:1 exhibited excellent photocatalytic activity than pure single Zn3(VO4)2 and FeVO4 photocatalysts by completely degrading the Rhodamine-B (Rh-B) dye solution at pH-3. The Zn3(VO4)2/FeVO4 composite was also used for the electrochemical identification of ascorbic acid and glucose. This study provides first-hand information about the potential of vanadate-based nanocomposites for the photocatalytic degradation of organic pollutants and electrochemical sensing of various analytes.

Keywords

Vanadate nanocomposites Crystal structure Phase transformations Hydrothermal method Rhodamine-B (Rh-B) Photocatalysis 

Notes

Acknowledgements

The authors are grateful to Dr. Zhengjun Zhang, Tsinghua University, Beijing, China for supporting characterization techniques and keen interest.

Funding

The authors did not receive financial support for this work from any agency.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© King Abdulaziz City for Science and Technology 2019

Authors and Affiliations

  1. 1.Department of PhysicsGovernment College University Allama Iqbal RoadFaisalabadPakistan
  2. 2.Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic EngineeringShenzhen UniversityShenzhenChina
  3. 3.Department of PhysicsUniversity of AgricultureFaisalabadPakistan
  4. 4.Institute for Advanced Study, Shenzhen UniversityShenzhenChina
  5. 5.Advanced Key Laboratory for New Ceramics, School of Materials ScienceEngineering, Tsinghua UniversityBeijingChina
  6. 6.Department of PhysicsComsat University IslamabadIslamabadPakistan
  7. 7.Department of Applied SciencesNational Textile UniversityFaisalabadPakistan

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