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Applied Nanoscience

, Volume 8, Issue 3, pp 545–555 | Cite as

Multifunctional AgNPs@Wool: colored, UV-protective and antioxidant functional textiles

  • Mohd Shabbir
  • Faqeer Mohammad
Original Article
  • 26 Downloads

Abstract

Nanomaterials have great impact on textile industry for multifunctional and smart clothing as per the need of present, and further, green nanotechnology is the current hotspot of research and industrial developments. Silver nanoparticles (AgNPs) are synthesized (in situ) by using natural compounds of plant extracts (naphthoquinones, phenolics/flavonoids, polyphenols) as reducing or stabilizing agents, and simultaneously deposited on wool fabric for coloration, UV protection and antioxidant properties. UV–visible spectroscopy is used to monitor the route of biosynthesis of nanoparticles and transmission electron microscopy for morphological characteristics of synthesized AgNPs. Spherical and almost oval-shaped AgNPs were synthesized by naphthoquinones, polyphenols and flavonoids, respectively. Scanning electron microscopy (SEM) coupled with energy dispersive X-ray (EDX) spectroscopy, X-ray diffraction pattern (XRD) and Fourier transform infrared spectroscopy were used for the AgNPs@Wool fabrics characterization. SEM–EDX analysis and XRD patterns confirmed the successful deposition of silver nanoparticles on wool. Coloration characteristics in terms of color strength (K/S) and CIEL*a*b*c*h° values, UV protection abilities in terms of UV transmittance and UV protection factor, and  % antioxidant activity of AgNPs@Wool are suggestive of good-to-excellent results.

Keywords

Ag nanoparticles Reducing/stabilizing compounds Biosynthesis Coloration UV protection Antioxidant activity 

Notes

Acknowledgements

Mohd Shabbir is highly thankful to University Grants Commission, India, for financial support via BSR (Basic Scientific Research) Fellowship for meritorious students and to Prof. Ren-Cheng Tang, Soochow University, China, for extending testing facilities.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no competing interests.

References

  1. Adjé FA, Lozano YF, Le Gernevé C, Lozano PR, Meudec E, Adima AA, Gaydou EM (2012) Phenolic acid and flavonol water extracts of Delonix regia red flowers. Ind Crops Prod 37:303–310CrossRefGoogle Scholar
  2. Ahmed S, Ahmad M, Swami BL, Ikram S (2016) A review on plants extract mediated synthesis of silver nanoparticles for antimicrobial applications: a green expertise. J Adv Res 7:17–28CrossRefGoogle Scholar
  3. Azab SS, Abdel-Daim M, Eldahshan OA (2013) Phytochemical, cytotoxic, hepatoprotective and antioxidant properties of Delonix regia leaves extract. Med Chem Res 22:4269–4277CrossRefGoogle Scholar
  4. Bar H, Bhui DK, Sahoo GP, Sarkar P, Pyne S, Misra A (2009) Green synthesis of silver nanoparticles using seed extract of Jatropha curcas. Colloids Surf A Physicochem Eng Asp 348:212–216CrossRefGoogle Scholar
  5. Chandran SP, Chaudhary M, Pasricha R, Ahmad A, Sastry M (2006) Synthesis of gold nanotriangles and silver nanoparticles using Aloevera plant extract. Biotechnol Prog 22:577–583CrossRefGoogle Scholar
  6. Chandrasekhar N, Vinay SP (2017) Yellow colored blooms of Argemone mexicana and Turnera ulmifolia mediated synthesis of silver nanoparticles and study of their antibacterial and antioxidant activity. Appl Nanosci.  https://doi.org/10.1007/s13204-017-0624-5 Google Scholar
  7. Dauthal P, Mukhopadhyay M (2013) Biosynthesis of palladium nanoparticles using Delonix regia leaf extract and its catalytic activity for nitro-aromatics hydrogenation. Ind Eng Chem Res 52:18131–18139CrossRefGoogle Scholar
  8. Ebrahimi I, Parvinzadeh Gashti M (2015) Extraction of juglone from Pterocarya fraxinifolia leaves for dyeing, anti-fungal finishing, and solar UV protection of wool. Color Technol 131:451–457CrossRefGoogle Scholar
  9. Edison TJI, Sethuraman MG (2012) Instant green synthesis of silver nanoparticles using Terminalia chebula fruit extract and evaluation of their catalytic activity on reduction of methylene blue. Process Biochem 47:1351–1357CrossRefGoogle Scholar
  10. El-Rafie MH, El-Naggar ME, Ramadan MA, Fouda MM, Al-Deyab SS, Hebeish A (2011) Environmental synthesis of silver nanoparticles using hydroxypropyl starch and their characterization. Carbohydr Polym 86:630–635CrossRefGoogle Scholar
  11. Feng XX, Zhang LL, Chen JY, Zhang JC (2007) New insights into solar UV-protective properties of natural dye. J Clean Prod 15:366–372CrossRefGoogle Scholar
  12. Hebeish A, El-Naggar ME, Fouda MM, Ramadan MA, Al-Deyab SS, El-Rafie MH (2011) Highly effective antibacterial textiles containing green synthesized silver nanoparticles. Carbohydr Polym 86:936–940CrossRefGoogle Scholar
  13. Iravani S (2011) Green synthesis of metal nanoparticles using plants. Green Chem 13:2638–2650CrossRefGoogle Scholar
  14. Islam S, Shabbir M, Mohammad F (2017) Insights into the functional finishing of textile materials using nanotechnology. In: Muthu SS (ed) Textiles and clothing sustainability. Springer, Singapore, pp 97–115CrossRefGoogle Scholar
  15. Khan MN, Khan TA, Khan Z, Al-thabaiti SA (2015) Green synthesis of biogenic silver nanomaterials using Raphanus sativus extract, effects of stabilizers on the morphology, and their antimicrobial activities. Bioprocess Biosyst Eng 38:2397–2416CrossRefGoogle Scholar
  16. Kumar V, Yadav SK (2009) Plant-mediated synthesis of silver and gold nanoparticles and their applications. J Chem Technol Biotechnol 84:151–157CrossRefGoogle Scholar
  17. Kumar KM, Mandal BK, Sinha M, Krishnakumar V (2012) Terminalia chebula mediated green and rapid synthesis of gold nanoparticles. Spectrochim Acta Mol Biomol Spectrosc 86:490–494CrossRefGoogle Scholar
  18. Li S, Shen Y, Xie A, Yu X, Qiu L, Zhang L, Zhang Q (2007) Green synthesis of silver nanoparticles using Capsicum annuum L. extract. Green Chem 9:852–858CrossRefGoogle Scholar
  19. Mittal AK, Chisti Y, Banerjee UC (2013) Synthesis of metallic nanoparticles using plant extracts. Biotechnol Adv 31:346–356CrossRefGoogle Scholar
  20. Mongkholrattanasit R, Kryštůfek J, Wiener J, Viková M (2011) Dyeing, fastness, and UV protection properties of silk and wool fabrics dyed with eucalyptus leaf extract by the exhaustion process. Fibres Text East Eur 19:94–99Google Scholar
  21. Perelshtein I, Applerot G, Perkas N, Grinblat J, Gedanken A (2012) A one-step process for the antimicrobial finishing of textiles with crystalline TiO2 nanoparticles. Chem A Eur J 18:4575–4582CrossRefGoogle Scholar
  22. Pfundstein B, El Desouky SK, Hull WE, Haubner R, Erben G, Owen RW (2010) Polyphenolic compounds in the fruits of Egyptian medicinal plants (Terminalia bellerica, Terminalia chebula and Terminalia horrida): characterization, quantitation and determination of antioxidant capacities. Phytochem 71:1132–1148CrossRefGoogle Scholar
  23. Rao B, Tang RC (2017) Green synthesis of silver nanoparticles with antibacterial activities using aqueous Eriobotrya japonica leaf extract. Adv Nat Sci Nanosci Nanotechnol 8:015014CrossRefGoogle Scholar
  24. Ravindra S, Mohan YM, Reddy NN, Raju KM (2010) Fabrication of antibacterial cotton fibres loaded with silver nanoparticles via “Green Approach”. Colloids Surf A Physicochem Eng Asp 367:31–40CrossRefGoogle Scholar
  25. Re R, Pellegrini N, Proteggente A, Pannala A, Yang M, Rice-Evans C (1999) Antioxidant activity applying an improved ABTS radical cation decolorization assay. Free Radic Biol Med 26:1231–1237CrossRefGoogle Scholar
  26. Rekaby M, Salem AA, Nassar SH (2009) Eco-friendly printing of natural fabrics using natural dyes from alkanet and rhubarb. J Text I 100:486–495CrossRefGoogle Scholar
  27. Shabbir M, Islam S, Bukhari MN, Rather LJ, Khan MA, Mohammad F (2016a) Application of Terminalia chebula natural dye on wool fiber-evaluation of color and fastness properties. Text Cloth Sustain 2:1–9CrossRefGoogle Scholar
  28. Shabbir M, Rather LJ, Islam S, Bukhari MN, Shahid M, Khan MA, Mohammad F (2016b) An eco-friendly dyeing of woolen yarn by Terminalia chebula extract with evaluations of kinetic and adsorption characteristics. J Adv Res 7:473–482CrossRefGoogle Scholar
  29. Shah AT, Din MI, Bashir S, Qadir MA, Rashid F (2015) Green synthesis and characterization of silver nanoparticles using Ferocactus echidne extract as a reducing agent. Anal Lett 48:1180–1189CrossRefGoogle Scholar
  30. Shahid M, Cheng XW, Tang RC, Chen G (2017a) Silk functionalization by caffeic acid assisted in situ generation of silver nanoparticles. Dyes Pigm 137:277–283CrossRefGoogle Scholar
  31. Shahid M, Zhou Y, Tang RC, Chen G, Wani WA (2017b) Colourful and antioxidant silk with chlorogenic acid: process development and optimization by central composite design. Dyes Pigm 138:30–38CrossRefGoogle Scholar
  32. Shanmugam C, Sivasubramanian G, Parthasarathi B, Baskaran K, Balachander R, Parameswaran VR (2016) Antimicrobial, free radical scavenging activities and catalytic oxidation of benzyl alcohol by nano-silver synthesized from the leaf extract of Aristolochia indica. Appl Nanosci 6(5):711–723CrossRefGoogle Scholar
  33. Shrivastava S, Bera T, Roy A, Singh G, Ramachandrarao P, Dash D (2007) Characterization of enhanced antibacterial effects of novel silver nanoparticles. Nanotechnol 18:225103CrossRefGoogle Scholar
  34. Song JY, Kim BS (2009) Rapid biological synthesis of silver nanoparticles using plant leaf extracts. Bioprocess Biosyst Eng 32:79CrossRefGoogle Scholar
  35. Song JY, Jang HK, Kim BS (2009) Biological synthesis of gold nanoparticles using Magnolia kobus and Diopyros kaki leaf extracts. Process Biochem 44:1133–1138CrossRefGoogle Scholar
  36. Sun SS, Tang RC (2011) Adsorption and UV protection properties of the extract from honeysuckle onto wool. Ind Eng Chem Res 50:4217–4224CrossRefGoogle Scholar
  37. Tang B, Zhang M, Hou X, Li J, Sun L, Wang X (2012) Coloration of cotton fibers with anisotropic silver nanoparticles. Ind Eng Chem Res 51:12807–12813CrossRefGoogle Scholar
  38. Teng C, Yu M (2003) Preparation and property of poly (ethylene terephthalate) fibers providing ultraviolet radiation protection. J Appl Polym Sci 88:1180–1185CrossRefGoogle Scholar
  39. Umadevi M, Shalini S, Bindhu MR (2012) Synthesis of silver nanoparticle using D. carota extract. Adv Nat Sci Nanosci Nanotechnol 3:025008CrossRefGoogle Scholar
  40. Vankar PS, Shukla D (2012) Biosynthesis of silver nanoparticles using lemon leaves extract and its application for antimicrobial finish on fabric. Appl Nanosci 2(2):163–168CrossRefGoogle Scholar
  41. Wagener S, Dommershausen N, Jungnickel H, Laux P, Mitrano D, Nowack B, Schneider G, Luch A (2016) Textile functionalization and its effects on the release of silver nanoparticles into artificial sweat. Environ Sci Technol 50:5927–5934CrossRefGoogle Scholar
  42. Zemljič LF, Volmajer J, Ristić T, Bracic M, Sauperl O, Kreže T (2014) Antimicrobial and antioxidant functionalization of viscose fabric using chitosan–curcumin formulations. Text Res J 84:819–830CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of ChemistryJamia Millia IslamiaNew DelhiIndia

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