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Hydrochemical changes and groundwater grouping data by multivariate statistical methods within one karst system: recharge–discharge zone (Eastern Serbia case study)

  • Ljiljana VasićEmail author
  • Dragana Živojinović
  • Vladana Rajaković-Ognjanović
Original Article
  • 36 Downloads
Part of the following topical collections:
  1. Special Issue: Research in Karst Environments

Abstract

To define changes in hydrochemical composition from the recharge to the discharge zone of the complex Kučaj–Beljanica karst massif, located in eastern Serbia, on a quarterly basis within one hydrologic year, a physico-chemical analysis was performed, along with the determination of ions (cations and anions) and isotope 13C content in rainwater, surface and groundwater (cold, sub-thermal and thermal). The multiparameter analysis of parameters was also used to determine the best combination and grouping of similar hydrochemical characteristics, as well as to determine the dependence of chemical parameters of the water, which may indicate the predominant complex geochemical underground processes. The results showed that the Ca2+ and dissolved oxygen O2 content in water decreases with circulation depth; while, the content of all other observed elements increases as a result of complex geochemical processes that occur within the complex karst environment.

Keywords

Karst Statistical analysis Ion composition Mean residence time 

Notes

Acknowledgements

Research presented in this paper was supported by projects from the Ministry of Education, Science and Technological Development, the Republic of Serbia: Project No. OI 176022 (“Groundwater Potential as the Basis for its Sustainable Utilization”) and Project No. TR 37005.

References

  1. Cattell RB (1966) The scree test for the number of factors. Multivar Behav Res 1:245–276CrossRefGoogle Scholar
  2. Cloutier V, Lefebvre R, Therrien R, Savard MM (2008) Multivariate statistical analysis of geochemical data as indicative of the hydrogeochemical evolution of groundwater in a sedimentary rock aquifer system. J Hydrol 353:294–313CrossRefGoogle Scholar
  3. Drever JI (1997) The geochemistry of natural waters, 3rd edn. Prentice-Hall, Upper Saddle RiverGoogle Scholar
  4. Field A (2005) Discovering statistics using SPSS. SAGE Publications Ltd., LondonGoogle Scholar
  5. Fleming G (1975) Computer simulation techniques in hydrology. Elsevier, Scientific Publishing Co., AmsterdamGoogle Scholar
  6. Ghosh A, Mondal S (2019) Application of multivariate statistics towards the geochemical evaluation of fluoride enrichment in groundwater at Shilabati river bank, West Bengal, India. Environ Eng Res 24(2):279–288.  https://doi.org/10.4491/eer.2018.178 CrossRefGoogle Scholar
  7. Güler C, Thyne GD, McCray JE, Turner AK (2002) Evaluation of graphical and multivariate statistical methods for classification of water chemistry data. Hydrogeol J 10:455–474CrossRefGoogle Scholar
  8. Hamil S, Arab S, Chaffai A, Baha M, Arab A (2018) Assessment of surface water quality using multivariate statistical analysis techniques: a case study from Ghrib dam, Algeria. Arab J Geosci 11:754CrossRefGoogle Scholar
  9. Hamzah FM, Jaafar O, Jani WNFA, Abdullah SMS (2016) Multivariate analysis of physical and chemical parameters of marine water quality in the straits of Johor, Malaysia. J Environ Sci Technol 9(6):427–436CrossRefGoogle Scholar
  10. Helena BA, Vega M, Barrado E, Pardo R, Fernandez L (1999) A case of hydrochemical characterization of an alluvial aquifer influenced by human activities. Water Air Soil Pollut 112:365–387CrossRefGoogle Scholar
  11. Huang P, Han S (2016) Assessment by multivariate analysis of groundwater-surface water interactions in the Coal-mining Exploring District, China. Earth Sci Res J 20(1):G1–G8.  https://doi.org/10.15446/esrj.v20n1.37601 CrossRefGoogle Scholar
  12. Huang F, Vasić L, Wu X, Jianhua C, Milanović S (2019) Hydrochemical features and their controlling factors in the Kucaj-Beljanica Massif, Serbia. Environ Earth Sci 78:498.  https://doi.org/10.1007/s12665-019-8452-4 CrossRefGoogle Scholar
  13. Jemcov I (2008) Bilans karstnih izdanskih voda i optimizacija rešenja njihovog zahvata na primerima iz Srbije, Doctoral dissertation, Department for hydrogeology, Faculty of Mining and Geology, BelgradeGoogle Scholar
  14. Kaiser HF (1960) The application of electronic computers to factor analysis. Educ Psychol Measur 20:141–151CrossRefGoogle Scholar
  15. Karimi H, Raeisi E, Zare M (2005) Physicochemical time series of karst springs as a tool to differentiate the source of spring water. Carbonates Evaporites 20(2):138–147.  https://doi.org/10.1007/BF03175457 CrossRefGoogle Scholar
  16. Milanović S (2010) Formiranje fizičkog modela karstne izdani na primeru Beljanice (istočna Srbija), Doctoral dissertation, Department for hydrogeology, Faculty of Mining and Geology, BelgradeGoogle Scholar
  17. Pinneker EV (1984) Underground hydrosphere. Nauka, Novosibirsk, p 157 (in Russian) Google Scholar
  18. Pinneker EV (1985) Strategy for the management of groundwater quality, hydrogeology in the service of man, groundwater quality management, vol 3, no 154. IAHS publ, Cambridge, pp 1–6Google Scholar
  19. Singh KP, Malik A, Mohan D, Sinha S, Singh VK (2005) Chemometric data analysis of pollutants in wastewater—a case study. Anal Chim Acta 532(1):15–25CrossRefGoogle Scholar
  20. Stevanović Z (1981) Hidrogeološke karakteristike karsta Kučajsko-beljaničkog masiva sa aspekta mogućnosti korišćenja izdanskih voda za vodosnabdevanje. Master thesis, Department for hydrogeology, Faculty of Mining and Geology, BelgradeGoogle Scholar
  21. Stevanović Z (1991) Hidrogeologija karsta Karpato-balkanida istočne Srbije i mogućnosti vodosnabdevanja, Monograph. Department for hydrogeology, Faculty of Mining and Geology, BelgradeGoogle Scholar
  22. Stevanović Z, Papić P (2008) The origin of groundwater. In: Dimkić M, Brauch HJ, Kavanaugh M (eds) Groundwater management in large river basins. IWA Publishing, London, pp 218–246Google Scholar
  23. Stojković J (2013) Hidrogeohemijska valorizacija esencijalnih mikroelemenata мineralnih voda Srbije. Doctoral dissertation. Department for hydrogeology, Faculty of Mining and Geology, BelgradeGoogle Scholar
  24. Tabachnick BG, Fidell LS (2007) Using multivariate statistics, 5th edn. Pearson Education, BostonGoogle Scholar
  25. Vasić L (2017) Geneza i uslovi cirkulacije voda kompleksnih karstnih sistema Kučajsko-beljaničkog masiva. Doctoral dissertation, Department for hydrogeology, Faculty of Mining and Geology, BelgradeGoogle Scholar
  26. Živojinović DZ (2013) Razvoj i primena hemometrijskih metoda za klasifikaciju i procenu kvaliteta vode. Doctoral dissertation, Faculty of Technology and Metallurgy, BelgradeGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2020

Authors and Affiliations

  • Ljiljana Vasić
    • 1
    Email author
  • Dragana Živojinović
    • 2
  • Vladana Rajaković-Ognjanović
    • 3
  1. 1.Faculty of Mining and GeologyUniversity of BelgradeBelgradeSerbia
  2. 2.Faculty of Technology and MetallurgyUniversity of BelgradeBelgradeSerbia
  3. 3.Faculty of Civil EngineeringUniversity of BelgradeBelgradeSerbia

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