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Simulation of acid weathering on natural and artificial building stones according to the current atmospheric SO2/NO x rate

  • S. Gibeaux
  • C. Thomachot-Schneider
  • S. Eyssautier-Chuine
  • B. Marin
  • P. Vazquez
Thematic Issue
  • 175 Downloads
Part of the following topical collections:
  1. Stone in the Architectural Heritage: from quarry to monuments – environment, exploitation, properties and durability

Abstract

The building stones are affected by pollution. Since 1980s, the actions to reduce the greenhouse gas emissions led to the inversion of the SO2/NO x proportions in the atmosphere. This study aims at estimating the effects of nitrogen and sulfur compounds on stones by assessing the changes of three building limestones and one reconstituted stone submitted to acid attacks. Two of these stones were already contaminated with sulfates, while the two others were fresh quarried. Two different types of accelerated aging tests were used: (1) the exposition to two mixed acid and saturated atmospheres (HNO3 and H2SO3) to simulate the ancient and current pollutants ratio and (2) the immersion in a mixed acid solution (HNO3 and H2SO4) and in rainwater (pH 5 and 5.9), with and without agitation to simulate stagnant water and storm runoff water. Macroscopic, binocular and SEM observations, variations of color, weight, porosity, salt content and dissolved calcium were assessed over time. The sulfur amount influences the esthetic alterations such as color changes due to the salt precipitation and the oxidation of metallic compounds. During the immersion tests, the dissolution in the acid solution was more efficient than in the rainwater, due to the combination of the acidity and the karst effects. In the mixed acid atmospheres, the behavior of the porous network depends on the pore size distribution while in the immersion tests it is the open porosity. The high initial sulfur content of the contaminated stones increases the dissolution rate and limits the crystallization.

Keywords

SO2/NOx Acid rain Acid deposition Aging laboratory tests Building limestone Reconstituted stone 

Notes

Acknowledgements

The authors want to thank Xavier Drothiere, Alexandra Conreux and Julien Hubert for their technical and analytical support.

Funding

This study was funded by “Reims Métropole” with the project IFEPAR and the University of Reims-Champagne Ardenne and the “Ville de Reims” with the Project REMITHERM, and “Grand Est” with the project FLUTE.

Compliance with ethical standards

Conflict of interest

The authors confirm that there is no conflict of interest in this research.

Informed consent

Informed consent was obtained from all individual participants included in the study.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Groupe d’Etudes sur les Géomatériaux et les Environnements Naturels, Anthropiques et Archéologiques (GEGENAA, EA 3795Université de Reims Champagne-ArdenneReimsFrance

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