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Environmental Earth Sciences

, Volume 73, Issue 2, pp 649–662 | Cite as

Investigating arsenic (As) occurrence and sources in ground, surface, waste and drinking water in northern Mongolia

  • Martin PfeifferEmail author
  • Gunsmaa Batbayar
  • Jürgen Hofmann
  • Konrad Siegfried
  • Daniel Karthe
  • Sonja Hahn-Tomer
Thematic Issue

Abstract

Elevated levels of arsenic in drinking water are found in several parts of Asia. Prolonged intakes of even low concentrations typically have serious health effects. This research paper integrates results of various studies on arsenic contamination of ground, surface, waste and drinking water in north-central Mongolia. Samples were analyzed with the ARSOlux biosensor and the Arsenator field test kit as well as different spectrometric methods (ICP-MS, ICP-OES). Altogether 309 samples were tested for their arsenic concentration, 44 of them with more than one technique. In the study region, the enrichment of heavy metals in surface waters is often linked to mining and coal combustion. The highest concentration of arsenic (As) was detected in the effluent of a gold mine (up to 2,820 μg L−1) and in the ash basin of a thermal power plant (up to 1,170 μg L−1). Five of 54 drinking water samples and 16 of 184 river samples were found to contain As levels above the World Health Organization (WHO) maximum permissible limit (10 μg L−1), with a maximum of 300 μg L−1 As. In addition, elevated levels of uranium were detected. The degree and extent of As concentrations exceeding WHO standards were previously unknown and demonstrate the necessity for a more intensive screening as well as possible interventions concerning the intake of arsenic-contaminated drinking water. Preliminary results indicate that the ARSOlux biosensor technology is well suited for a precise quantification of arsenic content at low detection limits in regions where access to central laboratories is difficult.

Keywords

Arsenic pollution Drinking water Gold mining Mongolia Upper Selenga River Basin 

Notes

Acknowledgments

This research was financially supported by the German Ministry of Education and Research (BMBF) (BMBF project No. 03300762) and the German Academic Exchange Service (DAAD) (Scholarship D 10 00351 for MP and No. A/12/97034 for GB). Special gratitude is owned to Prof. Dr. Galbadrakh Ragchaa, Department of Physics at National University of Mongolia, for use of his laboratory and help with literature research. We are grateful to Mr. Batzorig L., Vice Director of the Mongolian Central Geological Laboratory, and to Dr. Jürgen Mattusch of the Department Analytical Chemistry of the UFZ Leipzig. Special thanks are due to Ms. Gerel Osor (Mongolian University of Science and Technology, Darkhan) for conducting the regular monitoring since 2006 and to Andreas Koelsch (UFZ Leipzig) for producing the ARSOlux biosensors for our measuring campaign. We appreciate the help of Gongor Sergelen and Buyankhand Batsengee (National University of Mongolia) with the organization of the study and thank our Mongolian driver Batchuluun Tserendorj. The adjuvant comments on the manuscript by Eva Osterwalder (UFZ Leipzig) and four anonymous reviewers are gratefully acknowledged.

Supplementary material

12665_2013_3029_MOESM1_ESM.pdf (55 kb)
Supplementary material 1 (PDF 54 kb)
12665_2013_3029_MOESM2_ESM.pdf (26 kb)
Supplementary material 2 (PDF 26 kb)

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Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  • Martin Pfeiffer
    • 1
    Email author
  • Gunsmaa Batbayar
    • 1
    • 2
  • Jürgen Hofmann
    • 3
  • Konrad Siegfried
    • 4
  • Daniel Karthe
    • 2
  • Sonja Hahn-Tomer
    • 4
  1. 1.School of Geography and GeologyNational University of MongoliaUlaanbaatarMongolia
  2. 2.Department Aquatic Ecosystem Analysis and ManagementHelmholtz Centre for Environmental ResearchMagdeburgGermany
  3. 3.Department EcohydrologyLeibniz Institute of Freshwater Ecology and Inland FisheriesBerlinGermany
  4. 4.Department of Environmental MicrobiologyHelmholtz Centre for Environmental ResearchLeipzigGermany

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