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Environmental Earth Sciences

, Volume 67, Issue 2, pp 385–394 | Cite as

Chemical changes in fluid composition due to CO2 injection in the Altmark gas field: preliminary results from batch experiments

  • Farhana HuqEmail author
  • Philipp Blum
  • Michael A. W. Marks
  • Marcus Nowak
  • Stefan B. Haderlein
  • Peter Grathwohl
Special Issue

Abstract

Dissolution–precipitation phenomena induced by CO2 injection to Altmark Permian sandstone were observed through laboratory experiments carried out under simulated reservoir conditions (125 °C and 50 bars of pressure). The rock sample was collected from the Altmark gas reservoir, which is being considered for enhanced gas recovery. Two sets of experiments were performed with pulverized rock samples in a closed batch reactor with either pure water (run 1) or 3 M aqueous NaCl solution (run 2) and reacted with injected CO2 for 3, 5, and 9 days. The liquid samples were analyzed by inductively coupled plasma optical emission spectroscopy and total reflection X-ray fluorescence, where the latter proved to be a feasible alternative to conventional analytical techniques, especially since only small sample volumes (about 10 μl) are needed. Chemical analysis for both fluids (water and NaCl brine) indicated a significant dissolution of calcite and anhydrite in the solution, which might be a crucial process during CO2 injection. The brine solution enhanced the dissolution of calcite and anhydrite compared to pure water at the beginning of the reaction. Moreover, the progressive higher Si4+/Al3+ molar ratios (in average by a factor of 3) in the brine experiments indicated quartz dissolution. Thermodynamic calculations of mineral saturation indices highlighted the dissolution of the Ca-bearing minerals, which was in agreement with experimental results. Modeling enabled an evaluation of the dissolution processes of minerals in a low-salinity region, yet hindrances to model more saline conditions emphasize the need for further laboratory studies in order to parameterize models for deep aquifer conditions.

Keywords

Batch experiment CO2 injection Altmark Permian sandstone Mineral saturation index Enhanced gas recovery 

Abbreviations

NaAlSi3O8

Albite

CaSO4

Anhydrite

BaSO4

Barite

CaCO3

Calcite

(Mg,Fe)3(Si,Al)4O10(OH)2(Mg,Fe)3(OH)6

Chlorite

NaAlCO3(OH)2

Dawsonite

(K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2,(H2O)]

Illite

KAlSi3O8

K-feldspar

SiO2

Quartz

FeCO3

Siderite

Notes

Acknowledgments

This study was funded by BMBF (Federal Ministry of Education and Research) through the research group BA-5389 “CO2 Large Scale Enhanced Gas Recovery in the Altmark Natural Gas Field (CLEAN)” within the framework of the geoscientific research and development program “GEOTECHNOLOGIEN” (Publication number-1960). The authors would like to thank GDF SUEZ E&P DEUTSCHLAND GmbH for the samples. Sara Ladenburger, Thomas Wendel, and Sabine Flaiz are thanked for their assistances, respectively, in the TXRF, hydrogeochemistry, and ICP-OES laboratory at the University of Tübingen. Dr. Heinrich Taubald is specially thanked for his contribution in XRF measurement. We also thank Barbara Beckingham and two anonymous reviewers for their helpful suggestions.

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Copyright information

© Springer-Verlag 2012

Authors and Affiliations

  • Farhana Huq
    • 1
    Email author
  • Philipp Blum
    • 2
  • Michael A. W. Marks
    • 3
  • Marcus Nowak
    • 3
  • Stefan B. Haderlein
    • 1
  • Peter Grathwohl
    • 1
  1. 1.Center for Applied GeosciencesUniversity of TuebingenTübingenGermany
  2. 2.Institute for Applied GeosciencesKarlsruhe Institute of TechnologyKarlsruheGermany
  3. 3.Department of GeosciencesUniversity of TuebingenTübingenGermany

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