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Environmental Earth Sciences

, Volume 64, Issue 5, pp 1419–1431 | Cite as

A study on hydrochemical elucidation of coastal groundwater in and around Kalpakkam region, Southern India

  • S. Chidambaram
  • U. Karmegam
  • M. V. PrasannaEmail author
  • P. Sasidhar
  • M. Vasanthavigar
Original Article

Abstract

The chemical composition of 29 bore well water samples throughout the Kalpakkam region, South India, was determined to identify the major hydrogeochemical processes and the suitability of groundwater for domestic and irrigation purposes. The hydrochemical data were analyzed with reference to World Health Organization (WHO) standards and their hydrochemical facies were determined. The Piper plot shows that most of the groundwater samples fall in the field of mixed calcium–sodium–bicarbonate type followed by sodium–chloride, calcium–bicarbonate and mixed calcium–magnesium–chloride water types. The concentration of total dissolved solids exceeds the desirable limit in about 14% of samples; alkalinity values exceed the desirable limit in about 34% of the samples. The concentration of sulphate is well within the desirable limit at all the locations. The dominance of various heavy metals in the groundwater followed the sequence: Zn > Fe > Mn > Cu > Ni > Pb > Cr > Cd. Among the metal ions, the concentration of chromium and cadmium are within the permissible limit. Data are plotted on the US Salinity Laboratory diagram, which illustrates that most of the samples fall in the field of high salinity and low sodium hazard, which can be used to irrigate salt tolerant and semi-tolerant crops under favorable drainage conditions. Based on the analytical results, chemical indices like sodium adsorption ratio and residual sodium carbonate were calculated which show that most of the samples are good for irrigation.

Keywords

Hydrochemistry Coastal groundwater Major ions Heavy metals Water quality Southern India 

References

  1. Adepelumi AA, Ako BD, Ajayi TR, Afolabi O, Omotosa EJ (2009) Delineation of saltwater intrusion into the freshwater aquifer of Lekki Peninsula, Logas, Nigeria. Environ Geol 56:927–933CrossRefGoogle Scholar
  2. Adepoju-Bello AA, Ojomolade OO, Ayoola GA, Coker HAB (2009) Quantitative analysis of some toxic metals in domestic water obtained from Lagos metropolis. Nig J Pharm 42(1):57–60Google Scholar
  3. Amer AM (1995) Saltwater intrusion in coastal aquifers. Water Resour Manage 2:521–529Google Scholar
  4. Arumugham V (1994) Site characterization for location of radioactive waste repository—a case study. PhD thesis. Indian Institute of Technology, Bombay, IndiaGoogle Scholar
  5. BIS (1991) Specification for drinking water, IS:10500:1991. Bureau of Indian Standards, New DelhiGoogle Scholar
  6. Chidambaram S, Ramanathan AL, Srinivasamoorthy K, Anandhan P (2003) WATCLAST—a computer program for hydrogeochemical studies. Recent trends in Hydrogeochemistry (case studies from surface and subsurface waters of selected countries). Capital Publishing Company, New Delhi, pp 203–207Google Scholar
  7. Chidambaram S, Senthil Kumar G, Prasanna MV, John Peter A, Ramanathan AL, Srinivasamoorthy K (2009) A study on the hydrogeology and hydrogeochemistry of groundwater from different depths in a coastal aquifer: Annamalai Nagar, Tamilnadu, India. Environ Geol 57:59–73CrossRefGoogle Scholar
  8. Domenico PA, Schwartz FW (1998) Physical and chemical hydrogeology, 2nd edn. Wiley, New York, p 506Google Scholar
  9. Doneen LD (1964) Notes on water quality in agriculture. Published as a water science and engineering paper, 4001, Department of water science and engineering, University of CaliforniaGoogle Scholar
  10. Eaton EM (1950) Significance of carbonate in irrigation water. Soil Sci 69:123–133CrossRefGoogle Scholar
  11. Elampoornam T, Rajmohan N, Abirami L (1999) Hydrochemical studies of artesian well waters in Cauvery Deltaic Area, South India. Indian J Environ Health 41(2):107–114Google Scholar
  12. Freeze AR, Cherry JA (1979) Groundwater. Prentice–Hall, Inc Englewood cliffs, New Jersey, p 604Google Scholar
  13. Friberg L, Nordberg GF, Vouk VB (1986) Handbook of the toxicology of metals, vol 2. Elsevier, Amsterdam, pp 130–184Google Scholar
  14. Gibbs RJ (1970) Mechanisms controlling world’s water chemistry. (Science: 1089–1090)Google Scholar
  15. Guidelines for drinking water quality (1996) World Health Organisation. Geneva, p 186Google Scholar
  16. Guidelines for drinking water quality (2004) 3rd edn. Vol 1 Recommendations, World Health Organisation, Geneva, p. 515Google Scholar
  17. Gupta S, Mahato A, Roy P, Datta JK (2008) Geochemistry of groundwater, Burdwan District, West Bengal, India. Environ Geol 53:1271–1282CrossRefGoogle Scholar
  18. Jacks G (1973) Chemistry of groundwater in a district in Southern India. J Hydrol 18:185–200CrossRefGoogle Scholar
  19. Jain CK, Bandyopadhyay A, Bhadra A (2010) Assessment of groundwater quality for drinking purposes, District Nainital, Uttarakhand, India. Environ Monit Assess 166:663–676CrossRefGoogle Scholar
  20. Marcovecchio JE, Botte SE, Freije RH (2007) Heavy metals, major metals, trace elements. In: Nollet LM (ed) Handbook of water analysis, 2nd edn. CRC Press, London, pp 275–311Google Scholar
  21. Melloul LC, Goldenberg AJ (1998) Early-indicator signals of groundwater contamination: the case of seawater encroachment. Environ Geol 33(4):279–288CrossRefGoogle Scholar
  22. Mondal NC, Singh VP, Singh VS, Saxena VK (2010) Determining the interaction between groundwater and saline water through groundwater major ions chemistry. J Hydrol 388:100–111CrossRefGoogle Scholar
  23. Ozler HM (2003) Hydrochemistry and salt-water intrusion in the Van aquifer, East Turkey. Environ Geol 43:759–775Google Scholar
  24. Piper AM (1944) A graphical procedure in the geochemical interpretation of water analysis. Trans Am Geophys Union 25:914–923Google Scholar
  25. Prasanna MV, Chidambaram S, Shahul Hameed A, Srinivasamoorthy K (2010) Study of evaluation of groundwater in Gadilam basin using hydrogeochemical and isotope data. Environ Monit Assess 168:63–90CrossRefGoogle Scholar
  26. Rajmohan N, Elango L, Elampoornam T (1997) Seasonal and spatial variation in magnesium and chloride concentration in groundwater of Nagai Quaid E Millethh District in Tamilnadu. Indian J Environ Prot 17(6):448–453Google Scholar
  27. Rao NS (2006) Seasonal variation of groundwater quality of Srikakulam district, Andhra Pradesh, India. Environ Geol 49:413–429CrossRefGoogle Scholar
  28. Richard LA (1954) Diagnosis and improvement of saline and alkali soil. U.S. Department of Agricultural Handbook, No. 60, p 160Google Scholar
  29. Romic M, Romic D (2003) Heavy metal distribution in agricultural topsoils in urban area. Environ Geol 43: 795–805Google Scholar
  30. Schoeller H (1965) Qualitative evaluation of groundwater resources. In: Methods and techniques of groundwater investigations and development. UNESCO, pp 54–83Google Scholar
  31. Sharma SK, Singh V, Chandel CPS (2004) Groundwater pollution problem and evaluation of physic-chemical properties of groundwater. Environ Ecol 22(Suppl 2):319–324Google Scholar
  32. Singh V, Chandel CPS (2006) Analysis of wastewater of Jaipur City for agricultural use. Res J Chem Environ 10(1):30–33Google Scholar
  33. Singh VS, Saxena VK (2004) Assessment of utilization groundwater resources in a coastal shallow aquifer. In: Proceeding of the 2nd Asia Pacific Association of Hydrology & Water Resources Conferences, Singapore, vol II, pp 357–364Google Scholar
  34. Singh VS, Saxena VK, Prakash BA, Mondal NC, Jain SC (2004) Augmentation of groundwater resources in saline ingress coastal deltaic area. NGRI-Tech. report. No. NGRI-2004-GW-422, pp 1–61Google Scholar
  35. Srinivasa Gowd S, Pradip GK (2008) Distribution of heavy metals in surface water of Ranipet industrial area in Tamilnadu, India. Environ Monit Assess 136:197–207CrossRefGoogle Scholar
  36. Sriniwas CH, Tiska RS, Venkateshwar C, Rao MSS, Reddy RR (2000) Studies on groundwater quality of Hyderabad. Pollut Res 19(2):285–289Google Scholar
  37. Standard Methods for the Examination of Water and Wastewater (19th edn) (1998) American Public Health Association/American Water Works Association/Water Environment Federation, Washington, DCGoogle Scholar
  38. Stuyfzand PJ (1989) Non point sources of trace elements in potable groundwater in the Netherlands. In: Proceedings 18th TWSA Water Workings. Testing and Research Institute, KIWAGoogle Scholar
  39. Subba Rao N (2008) Iron content in groundwaters of Visakhapatnam environs, Andhra Pradesh, India. Envirn Monit Assess 136:437–447CrossRefGoogle Scholar
  40. Sujatha D, Rajeswara RB (2003) Quality characterization of groundwater in the south-eastern part of the Ranga Reddy district, Andhra Pradesh, India. Environ Geol 44(5):579–586CrossRefGoogle Scholar
  41. Terzic J, Markovic T, Pekas Z (2008) Influence of sea-water intrusion and agricultural production on the Blato aquifer, Island of Korcula, Croatia. Environ Geol 54:719–729CrossRefGoogle Scholar
  42. Vodela JK, Renden JA, Lenz SD, Mchel Henney WH, Kemppainen BW (1997) Drinking water contaminants. Pollut Sci 76:1474–1492Google Scholar
  43. WHO (1996) Guidelines for drinking water, vol 2, Recommendations. World Health Organization, GenevaGoogle Scholar
  44. WHO (2004) Guidelines for drinking water quality, vol 1. Recommendations, 3rd edn. WHO, Geneva, p 515Google Scholar
  45. WHO/UNEP GEMS (1989) Global fresh water quality; published on behalf of the World Health Organization/United Nations Environment Programme, Oxford, Blackwell ReferenceGoogle Scholar
  46. Wilcox LV (1955) Classification and use of irrigation water. US Department of Agriculture, Washington, p 969Google Scholar

Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • S. Chidambaram
    • 1
  • U. Karmegam
    • 1
  • M. V. Prasanna
    • 2
    Email author
  • P. Sasidhar
    • 3
  • M. Vasanthavigar
    • 1
  1. 1.Department of Earth SciencesAnnamalai UniversityChidambaramIndia
  2. 2.Department of Applied GeologySchool of Engineering and Science, Curtin UniversitySarawakMalaysia
  3. 3.SRI, IGCARKalpakkamIndia

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