Abstract
In the present study, synthesis, and characterization of carbon nanotubes (CNTs) has been carried out using fly ash, red mud, and rock sample as raw and filler material. The feed stock was used for the fabrication of bio-composite films of polyvinyl alcohol. Pyrolysis of bio-composite film produced by aqueous casting method was performed at 500 °C. The increment in particle size of the modified samples was analysed using laser particle size analyser. Oxide based composition and elemental analysis of the samples was reported using XRF. The comparison between crystalline phase and various organic and inorganic bonds present before and after modification were analysed using XRD and FTIR, respectively. The resultant carbon nanotubes were analysed for structural, morphological, and thermal stability using FESEM, TEM, Raman spectroscopy, and thermogravimetric analysis. Total pore volume, specific surface area, and the respective pore size distribution of the carbon nanotube mixture were analysed through BET analysis. Magnetic character of synthesized CNTs was analysed by using vibrating sample magnetometer. The obtained results from different characterization techniques shows successful preparation of CNTs with superior magnetic properties.
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Chikkatur, A.P.: A resource and technology assessment of coal utilization in India. Coal Initiative Reports, White Paper Series (2008)
Ahmaruzzaman, M.: A review on the utilization of fly ash. Prog. Energy Combust. Sci. 36, 327–363 (2010)
Top, S., Vapur, H.: Effect of basaltic pumice aggregate addition on the material properties of fly ash based lightweight geopolymer concrete. J. Mol. Struct. 1163, 10–17 (2018)
Ozdemir, O.D., Piskin, S.: A novel synthesis method of zeolite x from coal fly ash: alkaline fusion followed by ultrasonic-assisted synthesis method. Waste Biomass Valor. 10, 143–154 (2019)
Sahu, R.C., Patel, R., Ray, B.C.: Removal of hydrogen sulfide using red mud at ambient conditions. Fuel Process. Technol. 92, 1587–1592 (2011)
Popov, V.N.: Carbon nanotubes: properties and applications. Mater. Sci. Eng. R Rep. 43, 61–102 (2004)
Iijima, S.: Helical microtubules of graphitic carbon. Nature 354, 56–58 (1991)
Labrincha, J.A., Marques, J.I., Hajjaji, W., Senff, L., Zanelli, C., Dondi, M., Rocha, F.: Novel inorganic products based on industrial wastes. Waste Biomass Valor. 5, 385–392 (2014)
Kritikaki, A., Zaharaki, D., Komnitsas, K.: Valorization of industrial wastes for the production of glass–ceramics. Waste Biomass Valor. 7, 885–898 (2016)
Palomo, A., Grutzeck, M.W., Blanco, M.T.: Alkali-activated fly ashes a cement for the future. Cem. Concr. Res. 29, 1323–1329 (1999)
Nath, D.C.D., Bandyopadhyay, S., Gupta, S., Yu, A., Blackburn, D., White, C.: Surface-coated fly ash used as filler in biodegradable poly (vinyl alcohol) composite films: Part 1- the modification process. Appl. Surf. Sci. 256, 2759–2763 (2010)
Benito, A.M., Maniette, Y., Muñoz, E., Martínez, M.T.: Carbon nanotubes production by catalytic pyrolysis of benzene. Carbon 36, 681–683 (1998)
Sevilla, M., Lecea, C.S.M., Valdes-Solis, T., Morallon, E., Fuertes, A.B.: Solid-phase synthesis of graphitic carbon nanostructures from iron and cobalt gluconates and their utilization as electrocatalyst supports. Phys. Chem. Chem. Phys. 10, 1433–1442 (2008)
Nath, D.C., Sahajwalla, V.: Application of fly ash as a catalyst for synthesis of carbon nanotube ribbons. J. Hazard. Mater. 192, 691–697 (2011)
Oya, A., Marsh, H.: Phenomena of catalytic graphitization. J. Mater. Sci. 17, 309–322 (1982)
Zhang, Y., Wu, C., Nahil, M.A., Williams, P.: Pyrolysis-catalytic reforming /gasification of waste tires for production of carbon nanotubes and hydrogen. Energy Fuels 29, 3328–3334 (2015)
Ghaedi, A.M., Ghaedi, M., Pouranfard, A.R., Ansari, A., Avazzadeh, Z., Vafaei, A., Tyagi, I., Agarwal, S., Gupta, V.K.: Adsorption of Triamterene on multi-walled and single-walled carbon nanotubes: Artificial neural network modeling and genetic algorithm optimization. J. Mol. Liq. 216, 654–665 (2016)
Zhang, Y., Williams, P.T.: Carbon nanotubes and hydrogen production from the pyrolysis catalysis or catalytic-steam reforming of waste tyres. J. Anal. Appl. Pyrol. 122, 490–501 (2016)
Yao, D., Zhang, Y., Williams, P.T., Yanga, H., Chen, H.: Co-production of hydrogen and carbon nanotubes from real-world waste plastics: Influence of catalyst composition and operational parameters. Appl. Catal. B Environ. 221, 584–597 (2018)
Zhang, Y., Nahil, M.A., Wu, C., Williams, P.T.: Pyrolysis-catalysis of waste plastic using a nickel-stainless-steel mesh catalyst for high-value carbon products. Environ. Technol. 38, 1–9 (2017)
Liu, X., Zhang, Y., Nahil, M.A., Williams, P.T., Wu, C.: Development of Ni- and Fe- based catalysts with different metal particle sizes for the production of carbon nanotubes and hydrogen from thermo-chemical conversion of waste plastics. J. Anal. Appl. Pyrol. 125, 32–39 (2017)
Ghaedi, M., Naderi, S., Montazerozohori, M., Taghizadeh, F., Asghari, A.: Chemically modified multiwalled carbon nanotube carbon paste electrode for copper determination. Arab. J. Chem. 10, S2934–S2943 (2017)
Dunens, O.M., MacKenzie, K.J., Harris, A.T.: Synthesis of multiwalled carbon nanotubes on fly ash derived catalysts. Environ. Sci. Technol. 43, 7889–7894 (2009)
Krivoruchko, O.P., Maksimova, N.I., Zaikovskii, V.I., Salanov, A.N.: Study of multiwalled graphite nanotubes and filaments formation from carbonized products of polyvinyl alcohol via catalytic graphitization at 600–800 °C in nitrogen atmosphere. Carbon 38, 1075–1082 (2000)
Nath, D.C.D., Bandyopadhyay, S., Boughton, P., Yu, A., Blackburn, D., White, C.: High-strength biodegradable poly(vinyl alcohol)/fly ash composite films. J. Appl. Polym. Sci. 17, 114–121 (2010)
Schlittler, R.R., Seo, J.W., Gimzewski, J.K., Durkan, C., Saifullah, M.S.M., Welland, M.E.: Single crystals of single-walled carbon nanotubes formed by self-assembly. Science 292, 1136–1139 (2001)
Wright, A.F., Lehmann, M.S.: The structure of quartz at 25 and 590 °C determined by neutron diffraction. J. Solid State Chem. 36, 371–380 (1981)
Nath, D.C.D., Sahajwalla, V.: Growth mechanism of carbon nanotubes produced by pyrolysis of a composite film of poly (vinyl alcohol) and fly ash. Appl. Phys. A 104, 539–544 (2011)
Kaußen, F.M., Friedrich, B.: Phase characterization and thermochemical simulation of (landfilled) bauxite residue (“red mud”) in different alkaline processes optimized for aluminum recovery. Hydrometallurgy 176, 49–61 (2018)
Workman Jr., J., Weyer, L.: Practical Guide and Spectral Atlas for Interpretive Near-Infrared Spectroscopy, 2nd edn. CRC Press, Boca Raton (2012)
Chatterjee, A., Hu, X., Lam, F.L.Y.: Catalytic activity of an economically sustainable fly-ash-metal-organic- framework composite towards biomass valorization. Catal. Today 314, 137–146 (2018)
Nath, H., Sahoo, A.: Red mud and its applicability in fluoride abatement. Mater. Today Proc. 5, 2207–2215 (2018)
Gueon, D., Hwang, J.T., Yang, S.B., Cho, E., Sohn, K., Yang, D., Moon, J.H.: Spherical macroporous carbon nanotube particles with ultrahigh sulfur loading for lithium−sulfur battery cathodes. ACS Nano 12, 226–233 (2018)
Cançado, L.G., Takai, K., Enoki, T., Endo, M., Kim, Y.A., Mizusaki, H., Jorio, A., Coelho, L.N., Magalhães-Paniago, R., Pimenta, M.A.: General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy. Appl. Phys. Lett. 88, 163106 (2006)
Shan, R., Lin, W.W., Yin, L.F., Tian, C.S., Sang, H., Sun, L., Zhou, S.M.: Coercivity and magnetization reversal mechanism in ferromagnet/ antiferromagnet bilayers: correlation with microstructure of ferromagnetic layers. Phys. Rev. B 71, 064402 (2005)
Zuo, X., Wu, C., Zhang, W., Gao, W.: Magnetic carbon nanotubes for self-regulating temperature hyperthermia. RSC Adv. 8, 11997–12003 (2018)
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This work is partially supported by a Grant (DST/TM/WTI/WIC/2K17/84(G)) from DST (Department of Science and Technology), New Delhi. Any opinions, findings, and conclusions expressed in this paper are those of the authors and do not necessarily reflect the views of DST, New Delhi.
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Singh, R., Volli, V., Lohani, L. et al. Synthesis of Carbon Nanotubes from Industrial Wastes Following Alkali Activation and Film Casting Method. Waste Biomass Valor 11, 4957–4966 (2020). https://doi.org/10.1007/s12649-019-00827-2
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DOI: https://doi.org/10.1007/s12649-019-00827-2