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Choline Based Basic Ionic Liquid (BIL)/Acidic DES Mediated Cellulose Rich Fractionation of Agricultural Waste Biomass and Valorization to 5-HMF

  • Shalini Arora
  • Neeraj GuptaEmail author
  • Vasundhara SinghEmail author
Original Paper
  • 17 Downloads

Abstract

The present work demonstrates the efficient alkaline pre-treatment method to obtain a cellulose rich fraction from agricultural waste biomass using low cost and biocompatible aqueous choline hydroxide [Ch]OH, a basic ionic liquid (BIL) and the conversion of isolated cellulose into 5-(hydroxymethyl) furfural, catalyzed by various homogeneous acidic deep eutectic solvents (DES).

Graphical Abstract

(a) Low cost, mild biodegradable choline hydroxide (basic ionic liquid). (b) White cellulose fibers without bleaching process. (c) Recyclable and recoverable catalysts. And (d) High yield and purity of 5-HMF.

Keywords

Agriculture waste Choline hydroxide Choline chloride/p-TSA Choline chloride/oxalic acid Choline chloride/citric acid Cellulose 5-HMF 

Notes

Acknowledgements

The authors are thankful Punjab engineering college (Deemed to be University), Chandigarh for necessary facility and SAIF-CIL Punjab University, Chandigarh for spectroscopic analysis.

Compliance with Ethical Standards

Conflict of interest

There are no conflicts to declare.

Supplementary material

12649_2019_603_MOESM1_ESM.docx (136 kb)
Supplementary material 1 Experimental procedures for extraction of cellulose, hemi-cellulose, lignin, synthesis of HMF from cellulose, comparison table for 5-HMF.Characterization details of all isolated lignocellulosic components and 5-HMF, etc. (DOCX 135 KB)

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Department of Applied Sciences (Chemistry)Punjab Engineering College (Deemed to be University)ChandigarhIndia
  2. 2.School of Chemistry, Faculty of Basic SciencesShoolini UniversitySolanIndia

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