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Waste and Biomass Valorization

, Volume 9, Issue 10, pp 1945–1954 | Cite as

Preparation of Double Carboxylic Corn Stalk Gels and Their Adsorption Properties Towards Rare Earths (III)

  • Fuchun Wang
  • Junmei Zhao
  • Huizhou Liu
  • Yuan Luo
  • Wankun WangEmail author
Original Paper

Abstract

A novel biosorbent, corn stalk gels with double carboxylic groups synthesized by two oxidation steps (the double carboxylic groups modified adsorbent is abbreviated as DCCS-2), was prepared, characterized, and applied for the recovery of rare earths (III) from the nitric media. For the whole lanthanides, it exhibits a distinct “tetrad effect” with the increase of atomic numbers. Taking Nd(III) as a representative element, the adsorption capacity, kinetics, selectivity and mechanism were investigated. Thermodynamics and kinetic fittings were found to abide by Langmuir and pseudo-second-order rate equations and the corresponding parameters were calculated. The maximum adsorption capacity was calculated to be 2.44 mol/kg at 298 K for DCCS-2. Results showed that the double carboxylic groups played an important role for improving the adsorption capacity, e.g. the adsorption capacity of Nd(III) by DCCS-2 increased to 53.5 times compared to the raw corn stalk. Furthermore, DCCS-2 also shows a good selectivity between Nd(III) and many non-rare earth metal ions. The cation exchange is proposed to be the possible adsorption mechanism.

Keywords

Adsorption Rare earths Waste biomass NaIO4 NaClO 

Abbreviations

RCS

The raw corn stalk powder without chemical treatment

NaOH-CS

The activated corn stalk treated by NaOH solution

CCS-1

The modified corn stalk gels treated by NaOH and then by H2O2 solution

CCS-2

The modified corn stalk gels treated by NaOH and then by NaClO solution

DACS

The modified corn stalk gels treated by NaOH and then by NaIO4 solution

DCCS-1

The modified corn stalk gels treated by NaOH, then by NaIO4 and then by H2O2 solution

DCCS-2

The modified corn stalk gels treated by NaOH, then by NaIO4 and then by NaClO solution

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51504073 and 51404081), the Joint Research Program of the Science and Technology Department of Guizhou Province [Grant Nos. QianKeHe LH (2014) 7373 and QianKeHe LH (2014) 7372], the Research Program of the Education Department of Guizhou Province [Grant No. QianJiaoKeHe KY (2015) 433], the Research Program of Talented Scholars of Guizhou Institute of Technology (Grant No. XJG20141104).

Supplementary material

12649_2017_9954_MOESM1_ESM.doc (482 kb)
Supplementary material 1 (DOC 482 KB)

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Copyright information

© Springer Science+Business Media Dordrecht 2017

Authors and Affiliations

  • Fuchun Wang
    • 1
  • Junmei Zhao
    • 2
  • Huizhou Liu
    • 2
  • Yuan Luo
    • 1
  • Wankun Wang
    • 1
    Email author
  1. 1.Key Laboratory of Light Metal Materials Processing Technology of Guizhou Provinces, School of Materials and Metallurgical EngineeringGuizhou Institute of TechnologyGuiyangChina
  2. 2.Key Laboratory of Green Process and Engineering, Institute of Process EngineeringChinese Academy of SciencesBeijingChina

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