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Magnetic and Electrical Properties of Glass and Glass-Ceramics Based on Weathered Basalt

  • G. A. KhaterEmail author
  • Bassem S. Nabawy
  • Junfeng Kang
  • Yunlong Yue
  • M. A. Mahmoud
Original Paper


A total of six glass batches (WB100-WB50) based primarily on weathered basalt with successive addition of bypass cement dust (with the weight content 0–50%) were melted at 1450 °C and cast into glass specimens then crystallized into glass-ceramic through applying heat treatment at 1000 °C for 2 h. The dielectric constant (ε’), dielectric loss (ε”) and electric conductivity (σ) of both the glass and glass-ceramic samples were measured by applying the alternating current (AC) field and scanned at 1500 points in frequency range 50 Hz up to 7.5 MHz. A relatively high conductivity was assigned for the glass sample WB60 at the low frequency (50HZ) with value 1.85 μS/cm and for the glass-ceramic samples WB100 at higher frequencies (7.5 MHz) with value 3440 μS/cm. Besides, magnetic properties of the glass-ceramics were measured using a hysteresis magnetic loop technique up to 20 kg. The highest magnetization is assigned for samples WB100 and WB60 with value 3.074 and 2.914 emu/g, respectively; whereas the lowest values assigned for samples WB50 with value 0.209 emu/g. In order to achieve the best characterization of the obtained mixtures and to explain their electric and magnetic behavior as a function of the applied frequencies and magnetic field, various experimental techniques were applied in this study including, DTA, XRD, and SEM. The DTA indicated a gradual increase in the exothermic temperature by increasing the bypass content from WB100 to WB50. XRD analysis indicated that major crystalline phases are diopside, anorthite, wollastonite, gehlenite, magnetite and hematite. SEM indicated that the best crystal size is obtained for the samples WB60 and WB70.


Weathered basalt Glass Glass-ceramic Dielectric Magnetic Semiconductors 


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This work was done within the framework of the research project No. 10060401 entitled “Utilization of Sinai Basaltic Rocks for the Production of Construction Materials” sponsored by the National Research Centre.


  1. 1.
    Hallmann L, Ulmer P, Kern M (2018) Effect of microstructure on the mechanical properties of lithium disilicate glass-ceramics. J Mech Behav Biomed Mater 82:355–370CrossRefGoogle Scholar
  2. 2.
    Bona DA (2005) Characterizing ceramics and the interfacial adhesion to resin: II - the relationship of surface treatment, bond strength, interfacial toughness and fractography. J Appl Oral Sci 13:101–109CrossRefGoogle Scholar
  3. 3.
    Gajek M, Lis J, Partyka J, Wójczyk M (2011) Floor tile glass-ceramic glaze for improvement of the resistance to surface abrasion. J Mater Sci Eng 18:1–4Google Scholar
  4. 4.
    Richard AE, Chris F, Dane V (1987) Weathering of basalt: changes in rock chemistry and mineralogy, J. Clays and Clay Min 35(3):161CrossRefGoogle Scholar
  5. 5.
    Nabawy BS (2014) Estimating porosity and permeability using digital image analysis (DIA) technique for highly porous sandstones. Arab J Geo Sci 7(3):889–898CrossRefGoogle Scholar
  6. 6.
    Litus IN, Sinitsyn SE, Artemenko, AA (2008) Zemljansky, Noise-Attenuating and Sound-Proof Materials on the Basis of Basalt Fibers, Plasticheskiye Massy N1, 25–27Google Scholar
  7. 7.
    Khater GA, Shehata, MR, Hamzawy EM, Mahmoud MA (2017) Preparation of glass-ceramic materials from basaltic rocks and by-pass cement dust (2017) glass tech.: Eur.J.Glass Sci.Tech. A, 58 (1), 17–25Google Scholar
  8. 8.
    Sołtys M, Górny A, Pisarska J, Pisarski WA (2018) Electrical and optical properties of glasses and glass-ceramics. J Non-Cryst Sol 498:352CrossRefGoogle Scholar
  9. 9.
    Zanotto ED (2010) A bright future for glass-ceramics. J Am Ceram Soc Bull 89(8):19Google Scholar
  10. 10.
    El-Shennawi AWA (1983) The use of differential thermal analysis in the study of glass-ceramics. J Ain Shams Sci Bull 24:225Google Scholar
  11. 11.
    Thakur RL, Thiagarajan S (1966) Studies in catalyzed crystallization of glasses. J Inst Bull 13(2):33Google Scholar
  12. 12.
    Devekey RC, Majumdar (1970) Nucleation and crystallization studies of some glasses in CaO-MgO-Al2O3-SiO2 system. Miner Mag 37:771CrossRefGoogle Scholar
  13. 13.
    Pavlushkin NM (1979) Principals of glass ceramics technology (2nd ed), Stroiizdat, MoscowGoogle Scholar
  14. 14.
    Omar AA, El-Shennawi AWA (1971) Crystallization of some molten Egyptian basaltic rocks and corresponding glass, U.A.R., J Geol 15(1):65Google Scholar
  15. 15.
    Salama S.N., Darwish H., Abo-Mosallam H.A.,(2005) Crystallization and properties of glass based on diopside-Ca-Tschermake’s-fluorapatite system, J.Eur. Ceram.Soc.25, 1133CrossRefGoogle Scholar
  16. 16.
    Flemming LR, Luth RW, MAS SI (2002) NMR study of diopside-Ca-Tschermak clinopyroxenes: detecting both tetrahedral and octahedral Al substitution. J Am Mineral 87:25CrossRefGoogle Scholar
  17. 17.
    Douglas RM (1958) The crystal structure of anorthite. J Am Miner 43(5–6):517Google Scholar
  18. 18.
    Cooper RD, Fanselow JB, Pocker DB (1996) The mechanism of oxidation of a basaltic glass: chemical diffusion of network-modifying cations. J Geochimica et Cosmochimica Acta 60:3253CrossRefGoogle Scholar
  19. 19.
    Khater GA, Nabawy BS, Kang J, Mahmoud MA (2019) Dielectric properties of basaltic glass and glass-ceramics: modeling and applications as insulators and semiconductors. Silicon 11(2):579–592CrossRefGoogle Scholar
  20. 20.
    Mostafa MS, Afifi N, Gaber A, Abozeid EF (2003) Electrical resistivity of some basalt and granite samples from Egypt. Egypt J Sol 26(1):25–32Google Scholar
  21. 21.
    Ciobanu CL, Verdugo-Ihl MR, Slattery A, Cook NJ, Ehrig K, Courtney-Davies L, Wade BP (2019) Silician magnetite: Si–Fe-Nanoprecipitates and other mineral inclusions in magnetite from the Olympic dam deposit, South Australia. Minerals 9(5):311CrossRefGoogle Scholar
  22. 22.
    Yang X, Heidelbach F (2012) Grain size effect on the electrical conductivity of clinopyroxene. Contrib Mineral Petrol 163(6):939–947CrossRefGoogle Scholar
  23. 23.
    Yang X, Keppler H, McCammon C, Ni H (2012) Electrical conductivity of orthopyroxene and plagioclase in the lower crust. Contrib Mineral Petrol 163(1):33–48CrossRefGoogle Scholar
  24. 24.
    Li HM, Ra CHH, Zhang H, Yoo WJ, Lee KW, Kim JD (2009) Frequency and temperature dependence of the dielectric properties of a PCB substrate for advanced packaging applications. J Korean Phys Soc 54(3):1096–1099CrossRefGoogle Scholar
  25. 25.
    Rayssi Ch, El Kossi S, Dhahri J, Khirouni K (2018) Frequency and temperature-dependence of dielectric permittivity and electric modulus studies of the solid solution Ca0.85Er0.1Ti1−xCo4x/3O3 (0 ≤ x ≤ 0.1), RSC adv., 8, 17139–17150Google Scholar
  26. 26.
    Majerováa M, Dvurečenskija A, Cigáňa A, Škráteka M, Prnováb A, Kraxnerb J, Galusekb D, Maňkaa J (2017) Magnetic properties of synthetic Gehlenite glass microspheres. Acta Phys Pol A 131(4):699–701CrossRefGoogle Scholar
  27. 27.
    Lanci L (2010) Detection of multi-axial magnetite by remanence effect on anisotropy of magnetic susceptibility. Geophys J Int 181(3):1362–1366Google Scholar
  28. 28.
    Tauxe T, Bertram HN, Seberino C (2002) Physical interpretation of hysteresis loops: micromagnetic modeling of fine particle magnetite, the American Geophysical Union. Geochemistry Geophysics Geosystems G3 3(10):1–22CrossRefGoogle Scholar
  29. 29.
    Fujii M, Hiroshi Sato H, Eri Togawa E, Kazuhiko Shimada K, Ishibashi J (2018) Seafloor hydrothermal alteration affecting magnetic properties of abyssal basaltic rocks: insights from back-arc lavas of the Okinawa trough. Earth, Planets and Space 70:196CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2020

Authors and Affiliations

  • G. A. Khater
    • 1
    Email author
  • Bassem S. Nabawy
    • 2
  • Junfeng Kang
    • 3
  • Yunlong Yue
    • 3
  • M. A. Mahmoud
    • 1
    • 4
  1. 1.Glass Research DepartmentNational Research CentreCairoEgypt
  2. 2.Geophysical Sciences DepartmentNational Research CentreCairoEgypt
  3. 3.School of Materials Science and EngineeringUniversity of JinanJinanChina
  4. 4.FunGlass - Centre for Functional and Surface Functionalized GlassAlexander Dubček University of TrenčínTrenčínSlovakia

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