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, Volume 12, Issue 1, pp 41–48 | Cite as

Synthesis of New 2-Amino-3-(2-Oxothiazol-Methyl)-Substituted-1,4-Naphthoquinone Derivatives Based on Silica Nanoparticles as a Reusable Heterogeneous Catalyst

  • Hassan Vasheghani Farahani
  • Mohammad BayatEmail author
  • Shima Nasri
Original Paper
  • 38 Downloads

Abstract

A novel series of 2-amino-3-(2-oxothiazol-methyl)-substituted-1,4-naphthoquinone compounds were designed and prepared, by the three-component one-pot reaction of 2-aminothiazole, 2-hydroxy-1-4-naphthoquinone and aromatic aldehydes using of nano-SiO2 (20% mol) as an efficient Lewis acid and heterogeneous nano-catalyst in acetonitrile at room temperature in the period of time 2–5 h. Silica-based materials used for developing an environmental friendly methodology for the preparation of potential biologically active molecular scaffolds. The direction of product formation and the structure of all the synthesized compounds were identified by spectroscopic methods. The remarkable superiorities of this procedure include good yields (70–89%), use of an inexpensive and commercially available catalyst, regioselectivity and simple work-up.

Keywords

2-Aminothiazole 2-amino-oxothiazol-methyl-naphthoquinone Silica-based nanoparticle Nano-SiO2 Heterogeneous catalyst 

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Hassan Vasheghani Farahani
    • 1
  • Mohammad Bayat
    • 1
    Email author
  • Shima Nasri
    • 1
  1. 1.Department of Chemistry, Faculty of ScienceImam Khomeini International UniversityQazvinIran

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