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Synthesis and Characterization of High Heat Resistant Hydroxyl Silicone Oil with Boron and Sulfoxide in Backbone

  • Fengmei Ren
  • Qiang Xu
  • Zhengfa Zhou
  • Weibing XuEmail author
  • Haihong Ma
Original Paper


High heat resistant hydroxyl silicone oil with boron and sulfoxide in backbone (HSOBS) was synthesized by copolymerizing of hydroxyl polyborosiloxane oil (HPBSO) with thionyl chloride (SOCl2). The molecular structure of HSOBS was confirmed by Fourier-transform infrared spectroscopies (FT-IR) and nuclear magnetic resonance (1H-, 11B- and 29Si-NMR) spectroscopies. The thermogravimetric analysis (TGA) results showed that incorporation of sulfoxide group in backbone obviously improved the heat resistant of HSOBS. The temperature at 5% mass loss (T5) and maximum decomposition rate (Tmax) of HSOBS-1 were 490 °C and 590 °C, respectively. The thermal degradation activation energy (Ea) was systematically studied by the Flynn-Wall-Ozawa method, and the Ea of HSOBS was higher than that of HPBSO.


Heat resistant Sulfoxide Boron Hydroxyl silicone oil 


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The authors acknowledge general support from the Major Project of Anhui Province Science and Technology (17030901076).


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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.School of Chemistry and Chemical EngineeringHefei University of TechnologyHefeiPeople’s Republic of China

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