Abstract
The reorganization of fumed silica gel formed in sulphuric acid medium after being broken has been studied using rheological measurements including thixotropy, gelling time, and gel strength determination according to the falling rod method. The original gel formed by fumed silica particles was also studied for comparison. The results showed that the segments yielded after the original gel was broken can reorganize into a new gel although its ability was weaker than that of fresh particles. The dispersed size of silica particles influenced both the formation of the original gel and the reorganization behavior. The smaller silica particles favored a prolonged gelling time but yielded a gel with relatively low strength. Comparatively, the tendency to reorganize was weaker than in the original gel formation. The standing temperature during the fresh gel formation showed less of an effect on the reorganization process.
Similar content being viewed by others
References
Garche J (2001) Advanced battery systems-the end of the lead-acid battery? Phys Chem Chem Phys 3:356–367
Moseley PT, Garche J, Parker CD, Rand DAJ (2004) Valveregulated lead-acid batteries. Elsevier, Amsterdam
Lambert DWH, Greenwood PHJ, Reed MC (2002) Advances in gelled-electrolyte technology for valve-regulated lead-acid batteries. J Power Sources 107:173–179
Toniazzo V (2006) The key to success: Gelled-electrolyte and optimized separators for stationary lead-acid batteries. J Power Sources 158:1124–1132
Tantichanakul T, Chailapakul O, Tantavichet N (2011) Gelled electrolytes for use in absorptive glass mat valve-regulated lead-acid (AGM VRLA) batteries working under 100 % depth of discharge conditions. J Power Sources 196:8764– 8772
Liu CC, Maciel GE (1996) The Fumed Silica Surface: A Study by NMR. J Am Chem Soc 118:5103–5119
Barnes HA (1997) Thixotropy-a review. J Non-Newtonian Fluid Mech 70:1–33
Mewis J, Wagner NJ (2009) Thixotropy. Adv Colloid Interface Sci 147:214–227
Chen MQ, Chen HY, Shu D, Li AJ, Finlow DE (2008) Effects of preparation condition and particle size distribution on fumed silica gel valve-regulated lead-acid batteries performance. J Power Sources 181:161–171
Kamiya H, Mitsui M, Takano H, Miyazawa S (2000) Influence of Particle Diameter on Surface Silanol Structure, Hydration Forces, and Aggregation Behavior of Alkoxide-Derived Silica Particles. J Am Ceram Soc 83:287–293
Barthel H, Rosch L, Weis J (1996) Fumed silica-production, properties, and applications. In: Auner N, Weis J (eds) Organosilicon Chemistry Set: From Molecules to Materials. Wiley-VCH Verlag GmbH, Weinheim
Gun’ko VM, Zarko VI, Leboda R, Chibowski E (2001) Aqueous suspension of fumed oxides: particle size distribution and zeta potential. Adv Colloid Interface Sci 91:1–112
Acknowledgments
Fund support from Zhejiang Chaowei Power Co., Ltd. is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sun, X., Zhao, J. Reformation of Fumed Silica Gel After Being Broken. Silicon 9, 879–884 (2017). https://doi.org/10.1007/s12633-016-9517-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12633-016-9517-6