, Volume 8, Issue 1, pp 57–63 | Cite as

POSS in Tight Places

  • Henry W. Milliman
  • Matthew M. Herbert
  • David A. SchiraldiEmail author
Original Paper


The nature of polymer/POSS interactions and associated thermo-mechanical properties are discussed, and found to be consistent with small-molecule interactions associated with POSS, rather than a bottom-up self-assembly or any other method of classical reinforcement. Hansen solubility parameters are shown to accurately predict polymer/POSS combinations which are capable of successful interactions; such interactions are necessary, but insufficient for polymer property enhancement, since in many cases compatibility simply leads to plasticization by POSS. In the presence of stong additive/polymer interactions, such as via hydrogen bonding and/or π- π stacking, moduli, strength and glass transitions can all be increased, but only up to the solubility limit for the POSS in the polymer, which typically is reached at approximately 2.5-3 wt % POSS. Beyond the solubility limit, phase separation and rapid degradation of properties is observed.


POSS Properties Interactions Polymer 


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  1. 1.
    Wu J, Mather PT (2009) Polym Rev 49(1):25–63CrossRefGoogle Scholar
  2. 2.
    Li G, Wang L, Ni H, Pittman CU Jr (2001) J Inorg Organomet Polym 11(3):123–154CrossRefGoogle Scholar
  3. 3.
    Zheng L, Waddon AJ, Farris RJ, Coughlin EB (2002) Macromolecules 35:2375CrossRefGoogle Scholar
  4. 4.
    Fu BX, Namani M, Lee A (2003) Polymer 44:7739CrossRefGoogle Scholar
  5. 5.
    Iacono ST, Budy SM, Mabry JM, Smith DW (2007) Macromolecules 40:9517CrossRefGoogle Scholar
  6. 6.
    Yoon KW, Polk MB, Park JH, Min BG, Schiraldi DA (2005) Polym Int 54(1):47–53CrossRefGoogle Scholar
  7. 7.
    Iyer S, Schiraldi DA (2007) Macromolecules 40:4942–4952CrossRefGoogle Scholar
  8. 8.
    Sanchez-Soto M, Illescas S, Milliman H, Schiraldi DA, Arostegui A (2010) Macromol Mater Eng 295:846–856CrossRefGoogle Scholar
  9. 9.
    Milliman HW, Sanchez-Soto M, Arostegui A, Schiraldi DA (2012) J Appl Polym Sci 125:2914–2919CrossRefGoogle Scholar
  10. 10.
    Zheng L, Farris RJ, Coughlin EB (2001) J Polym Sci, Part A: Polym Chem 39:2920–2928CrossRefGoogle Scholar
  11. 11.
    Zheng L, Hong S, Cardoen G, Burgaz E, Gido SP, Coughlin EB (2001) Macromolecules 37:8606–8611CrossRefGoogle Scholar
  12. 12.
    Misra R, Alidedeoglu AH, Jarrett WJ, Morgan SE (2009) Polymer 50(13):2906–2918CrossRefGoogle Scholar
  13. 13.
    Fu BX, Gelfer MY, Hsiao BS, Phillips S, Viers B, Blanski R, Ruth P (2003) Polymer 44:1499–1506CrossRefGoogle Scholar
  14. 14.
    Fina A, Monticelli O, Camino G (2010) J Mater Chem 20:9297–9305CrossRefGoogle Scholar
  15. 15.
    Misra R, Fu BX, Plagge A, Morgan SE (2009) J Polym Sci, Part B: Polym Phys 47:1088CrossRefGoogle Scholar
  16. 16.
    Lim S, Hong E, Song Y, Choi HJ, Chin I (2011) J Mater SciGoogle Scholar
  17. 17.
    Lim S, Hong E, Song Y, Choi H J, Chin I (2010) J Mater Sci 45:5984CrossRefGoogle Scholar
  18. 18.
    Zhou Y, Schiraldi DA (2005) Polymer 46:11640–7CrossRefGoogle Scholar
  19. 19.
    Roy S, Lee Bj, Kakish ZM, Jana SC (2012) Macromolecules 45(5):2420–2433CrossRefGoogle Scholar
  20. 20.
    Schiraldi DA, Iyer S (2010) What Does it Take to Make a Stable POSS/Polymer Composite?. In: ACS Symposium Series, Advances in Silicones and Silicone-Modified Materials Chapter 17, vol 1051. ACS Symposium Series, pp 211–226Google Scholar
  21. 21.
    Zeng J, Iyer S, Gonzalez R, Kumar S, Schiraldi DA (2005) High Perform Polym 17:403–424CrossRefGoogle Scholar
  22. 22.
    Milliman HW, Boris D, Schiraldi DA (2012) Macromolecules 45:1931–1936CrossRefGoogle Scholar
  23. 23.
    Milliman HW, Ishida H, Schiraldi DA (2012) Macromolecules 45:4650–4657CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  • Henry W. Milliman
    • 1
  • Matthew M. Herbert
    • 1
  • David A. Schiraldi
    • 1
    Email author
  1. 1.Department of Macromolecular Science & EngineeringCase Western Reserve UniversityClevelandUSA

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