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, Volume 7, Issue 2, pp 211–216 | Cite as

Synthesis of Fluorine-Containing-Organosilicon Oligomer in Trifluoroacetic Acid as Active Medium

  • Mikhail A. SoldatovEmail author
  • Natalia A. Sheremetyeva
  • Olga A. Serenko
  • Aziz M. Muzafarov
Original Paper

Abstract

In the current work we synthesized statistical fluorine-containing copolymers in trifluoroacetic acid as an active medium. Also, epoxy resin compositions containing these copolymers were prepared. It was shown that the use of trifluoroacetic acid as opposed to acetic acid makes it possible to obtain the product with a higher molecular weight and compositional homogeneity.

Keywords

Hydrophobic coatings Siloxane Fluorine-containing Hydrolytic polycondensation Active medium 

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References

  1. 1.
    Boinovich LB, Emelyanenko AM (2008) Russ Chem Rev 77:583–600CrossRefGoogle Scholar
  2. 2.
    Nosonovsky M (2007) Langmuir 23:3157–3161CrossRefGoogle Scholar
  3. 3.
    Patankar NA (2003) Langmuir 19:1249–1253CrossRefGoogle Scholar
  4. 4.
    Celia E, Darmanin T, Taffin de Givenchy E, Amigoni S, Guittard F (2013) J Colloid Interface Sci 402:1–18CrossRefGoogle Scholar
  5. 5.
    Cao L, Jones AK, Sikka VK, Wu J, Gao D (2009) Langmuir 25:12444–12448CrossRefGoogle Scholar
  6. 6.
    Guittard F, Geribaldi S (2001) J Fluor Chem 107:363–374CrossRefGoogle Scholar
  7. 7.
    Krukovsky SP, Yarosh AA, Glazkov AA, Batizat DV, Redina TN (1999) J Fluor Chem 96:31–33CrossRefGoogle Scholar
  8. 8.
    Boinovich LB, Emel’yanenko AM, Muzafarov AM, Myshkovskii AM, Pashinin AS, Tsivadze A, Yarova DI (2008) Nanotechnologies in Russia 3:587–592CrossRefGoogle Scholar
  9. 9.
    Khananashvili LM, Andrianov KA (1983) Tekhnologiya elementorganicheskikh monomerov i polimerov (Technology of Organoelement Monomers and Polymers) Khimiya, MoscowGoogle Scholar
  10. 10.
    Egorova EV, Vasilenko NG, Demchenko NV, Tatarinova EA, Muzafarov AM (2009) Dokl Chem 424:15–18CrossRefGoogle Scholar
  11. 11.
    Bychkova AA, Soskov FV, Demchenko AI, Storozhenko PA, Muzafarov AM (2011) Russ Chem Bull 60:2384–2389CrossRefGoogle Scholar
  12. 12.
    Milenin SA, Kalinina AA, Demchenko NV, Vasilenko NG, Muzafarov AM (2013) Russ Chem Bull 62:1–5CrossRefGoogle Scholar
  13. 13.
    Soldatov M A, Sheremetyeva N A, Kalinina A A, Demchenko N V, Serenko O A, Muzafarov A M (2014) Russ Chem Bull, vol 1Google Scholar
  14. 14.
    Oner D, McCarthy TJ (2000) Langmuir 16:7777–7782CrossRefGoogle Scholar
  15. 15.
    Li HJ, Wang XB, Song YL, Liu YQ, Li QS, Jiang L, Zhu DB (2001) Angew Chem Int Ed 40:1743–1746CrossRefGoogle Scholar
  16. 16.
    Widawski G, Rawiso M, Francois B (1994) Nature 369:387–389CrossRefGoogle Scholar
  17. 17.
    Srinivasarao M, Collings D, Philips A, Patel S (2001) Science 292:79–83CrossRefGoogle Scholar
  18. 18.
    Haupt M, Miller S, Sauer R, Thonke K, Mourran A, Moeller M (2004) J Appl Phys 96:3065–3069CrossRefGoogle Scholar
  19. 19.
    Samuel AZ, Umapathy S, Ramakrishnan S (2011) ACS Appl Mater Interfaces 3:3293–3299CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  • Mikhail A. Soldatov
    • 1
    Email author
  • Natalia A. Sheremetyeva
    • 1
  • Olga A. Serenko
    • 2
  • Aziz M. Muzafarov
    • 1
    • 2
  1. 1.Institute of Synthetic Polymeric Materials, a Foundation of the Russian Academy of SciencesMoscowRussia
  2. 2.Institute of Organoelement Compounds, a Foundation of the Russian Academy of SciencesMoscowRussia

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