Silicon

, Volume 8, Issue 1, pp 105–110 | Cite as

Propeller-Like Chirality of Methyl-Tris (2,6-diisopropylphenoxy)Silylsulfide

  • Aleksander Herman
  • Sylwia Godlewska
  • Łukasz Ponikiewski
  • Tomasz Kruczyński
  • Anna Dołe̹ga
Open Access
Original Paper

Abstract

Two new methylsilylsulfides are synthesized. Propeller-like chirality is described for triaryloxysilanethiol and its methyl derivative. S-methylation of the silanethiol lowers the overall symmetry of the unit cell.

Keywords

Silyl sulfide Chirality 

References

  1. 1.
    Wolf C (2008) Dynamic Stereochemistry of Chiral Compounds. Principles and Applications. The Royal Society of Chemistry, CambridgeGoogle Scholar
  2. 2.
    Chojnacki J, Ciborska A, Wojnowski W (2008) Acta Crystallogr C64:m240Google Scholar
  3. 3.
    Pladzyk A, Baranowska K, Gudat D, Godlewska S, Wieczerzak M, Chojnacki J, Bulman M, Januszewicz K, Dołȩga A (2011) Polyhedron 30:1191CrossRefGoogle Scholar
  4. 4.
    Dołe̹ga A, Marynowski W, Baranowska K, Śmiechowski M, Stangret J (2012) Inorg Chem 51:836CrossRefGoogle Scholar
  5. 5.
    Sheldrick GM (2008) Acta Crystallogr A64:112CrossRefGoogle Scholar
  6. 6.
    te Velde G, Bickelhaupt FM, van Gisbergen SJA, Fonseca Guerra C, Baerends EJ, Snijders JG, Ziegler T (2001) J Comput Chem 22:931CrossRefGoogle Scholar
  7. 7.
    Fonseca Guerra C, Snijders JG, te Velde G, Baerends EJ (1998) Theor Chem Account 99:391Google Scholar
  8. 8.
    Baerends EJ, Ziegler T, Autschbach J, Bashford D, Bérces A, Bickelhaupt FM, Bo C, Boerrigter PM, Cavallo L, Chong DP, Deng L, Dickson RM, Ellis DE, van Faassen M, Fan L, Fischer TH, Fonseca Guerra C, Franchini M, Ghysels A, Giammona A, van Gisbergen SJA, Götz AW, Groeneveld JA, Gritsenko OV, Grüning M, Gusarov S, Harris FE, van den Hoek P, Jacob CR, Jacobsen H, Jensen L, Kaminski JW, van Kessel G, Kootstra F, Kovalenko A, Krykunov MV, van Lenthe E, McCormack DA, Michalak A, Mitoraj M, Morton SM, Neugebauer J, Nicu VP, Noodleman L, Osinga VP, Patchkovskii S, Pavanello M, Philipsen PHT, Post D, Pye CC, Ravenek W, Rodríguez JI, Ros P, Schipper PRT, Schreckenbach G, Seldenthuis JS, Seth M, Snijders JG, Solà M, Swart M, Swerhone D, te Velde G, Vernooijs P, Versluis L, Visscher L, Visser O, Wang F, Wesolowski TA, van Wezenbeek EM, Wiesenekker G, Wolff SK, Woo TK, Yakovlev AL ADF2013, SCM,Theoretical Chemistry, Vrije Universiteit, Amsterdam, The Netherlands. http://www.scm.com
  9. 9.
    Rocha GB, Freire RO, Simas AM, Stewart JJP (2006). J Comput Chem 27:1101CrossRefGoogle Scholar
  10. 10.
    Baker J (1986) J. Comput. Chem 7:385CrossRefGoogle Scholar
  11. 11.
    Piękoś R, Wojnowski W (1962) Z Anorg Allg Chem 318:212Google Scholar
  12. 12.
    Marynowski W, Klucznik T, Baranowska K, Dołe̹ga A, Wojnowski W (2010) Z Anorg Allg Chem 636:685CrossRefGoogle Scholar
  13. 13.
    Gust D, Mislow K (1973) J Am Chem Soc 95:1535CrossRefGoogle Scholar
  14. 14.
    Andreetti GD, Bocelli G, Calestani G, Sgarabotto P (1984) J Organomet Chem 273:31CrossRefGoogle Scholar
  15. 15.
    Jabłońska A, Ponikiewski Ł, Ejsmont K, Herman A, Dołe̹ga A (2013) J Mol Struct 1054-1055:359CrossRefGoogle Scholar
  16. 16.
    Bassindale AR, Lau JC-Y, Taylor PG (1995) J Organomet Chem 499:137CrossRefGoogle Scholar
  17. 17.
    Olszewska T, Sikorski A, Herman A, Połoński T (2013) Org Biomol Chem 11:7522Google Scholar

Copyright information

© The Author(s) 2015

Authors and Affiliations

  • Aleksander Herman
    • 1
  • Sylwia Godlewska
    • 1
  • Łukasz Ponikiewski
    • 1
  • Tomasz Kruczyński
    • 1
    • 2
  • Anna Dołe̹ga
    • 1
  1. 1.Department of Inorganic ChemistryGdansk University, of TechnologyGdańskPoland
  2. 2.Institute of Inorganic ChemistryKarlsruhe Institute of TechnologyKarlsruheGermany

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