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Facile synthesis of Zn(II)-doped g-C3N4 and their enhanced photocatalytic activity under visible light irradiation

  • Zhao-Tian Wang
  • Jun-Li XuEmail author
  • Hui Zhou
  • Xia Zhang
Article
  • 19 Downloads

Abstract

Zn(II)-doped graphitic carbon nitride (g-C3N4) with high photodegradation activity was prepared by one facile step. The morphology and structure of the prepared Zn(II)-doped g-C3N4 were investigated, and the results showed that Zn(II) could self-disperse during the pyrolysis process and Zn–N bond was formed between g-C3N4 and Zn. The dope of Zn(II) influenced the structure of g-C3N4. The performance of photocatalytic activity of Zn(II)-doped g-C3N4 series indicated that the doped g-C3N4 with a small quantity of Zn (0.10 wt%) exhibits the best photocatalytic performance. The photodegradation activity for methyl orange was 2 times higher than that of pure g-C3N4. However, the photocatalytic activity decreased with the further increased content of Zn, which may be attributed to the structure change of g-C3N4 and the interaction of Zn–N bond between Zn and g-C3N4. Moreover, Zn(II)-doped g-C3N4 showed good recycling photocatalytic stability.

Keywords

Zn(II) dope g-C3N4 Visible light irradiation Photodegradation Photocatalytic stability 

Notes

Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (No. 51574071).

References

  1. [1]
    She XJ, Liu L, Ji HY, Mo Z, Li YP, Huang LY, Du DL, Xu H, Li HM. Template-free synthesis of 2D porous ultrathin nonmetal-doped g-C3N4 nanosheets with highly efficient photocatalytic H2 evolution from water under visible light. Appl Catal B. 2016;187:144.CrossRefGoogle Scholar
  2. [2]
    Christoforidis KCC, Montini T, Bontempi E, Zafeiratos S, Jaen JJD, Fornasiero P. Synthesis and photocatalytic application of visible-light active β-Fe2O3/g-C3N4 hybrid nanocomposites. Appl Catal B. 2016;187:171.CrossRefGoogle Scholar
  3. [3]
    Wang GL, Shan LW, Wu Z, Dong LM. Enhanced photocatalytic properties of molybdenum-doped BiVO4 prepared by sol–gel method. Rare Met. 2017;36(2):129.CrossRefGoogle Scholar
  4. [4]
    Hao RR, Wang GH, Jiang CJ, Tang H, Xu QC. In situ hydrothermal synthesis of g-C3N4/TiO2 heterojunction photocatalysts with high specific surface area for Rhodamine B degradation. Appl Surf Sci. 2017;411:400.CrossRefGoogle Scholar
  5. [5]
    Dong F, Zhao ZW, Xiong T, Ni ZL, Zhang WD, Sun YJ, Ho WK. In situ construction of g-C3N4/g-C3N4 metal-free heterojunction for enhanced visible-light photocatalysis. ACS Appl Mater Interfaces. 2013;5(21):11392.CrossRefGoogle Scholar
  6. [6]
    Meng YL, Shen J, Xin G. Photodegradation performance of methylene blue aqueous solution on Ag/g-C3N4 catalyst. Rare Met. 2011;30(1s):276.CrossRefGoogle Scholar
  7. [7]
    Zhou C, Shi R, Shang L, Wu LZ, Tung CH, Zhang T. Template-free large-scale synthesis of g-C3N4 microtubes for enhanced visible light-driven photocatalytic H2 production. Nano Res. 2018;11(6):3462.CrossRefGoogle Scholar
  8. [8]
    Shi L, Liang L, Wang FX, Jun M, Sun JM. Polycondensation of guanidine hydrochloride into a graphitic carbon nitride semiconductor with a large surface area as a visible light photocatalyst. Catal Sci Technol. 2014;4:3235.CrossRefGoogle Scholar
  9. [9]
    Yu HG, Chen FY, Chen F, Wang XF. In situ self-transformation synthesis of g-C3N4-modified CdS heterostructure with enhanced photocatalytic activity. Appl Surf Sci. 2015;358(part A):385.CrossRefGoogle Scholar
  10. [10]
    Wang Y, Wang XC, Antonietti M. Polymeric graphitic carbon nitride as a heterogeneous organocatalyst: from photochemistry to multipurpose catalysis to sustainable chemistry. Angew Chem Int Ed. 2012;51(1):68.CrossRefGoogle Scholar
  11. [11]
    Liang DM, Jing T, Ma YC, Hao JX, Sun GY, Deng MS. Photocatalytic properties of g-C6N6/g-C3N4 heterostructure: a theoretical study. J Phys Chem C. 2016;120(42):24023.CrossRefGoogle Scholar
  12. [12]
    Zhang JS, Chen XF, Takanabe K, Maeda K, Domen K, Epping JD, Fu XZ, Antonietti M, Wang XC. Synthesis of a carbon nitride structure for visible-light catalysis by copolymerization. Angew Chem Int Ed. 2010;49(2):441.CrossRefGoogle Scholar
  13. [13]
    Wu SZ, Li K, Zhang WD. On the heterostructured photocatalysts Ag3VO4/g-C3N4 with enhanced visible light photocatalytic activity. Appl Surf Sci. 2015;324:324.CrossRefGoogle Scholar
  14. [14]
    Thomas A, Fischer A, Goettmann F, Antonietti M, Muller JO, Schlogl R, Carlsson JM. Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts. J Mater Chem. 2008;18(41):4893.CrossRefGoogle Scholar
  15. [15]
    Cao SW, Yuan YP, Barber J, Loo SCJ, Xue C. Noble-metal-free g-C3N4/Ni(dmgH)2 composite for efficient photocatalytic hydrogen evolution under visible light irradiation. Appl Surf Sci. 2014;319:344.CrossRefGoogle Scholar
  16. [16]
    Zhang GG, Zhang JS, Zhang MW, Wang XC. Polycondensation of thiourea into carbon nitride semiconductors as visible light photocatalysts. J Mater Chem. 2012;22(16):8083.CrossRefGoogle Scholar
  17. [17]
    Feng LL, He F, Liu B, Yang GX, Gai SL, Yang PP, Li CX, Dai YL, Lv RC, Lin J. g-C3N4 coated upconversion nanoparticles for 808 nm near-infrared light triggered phototherapy and multiple imaging. Chem Mater. 2016;28(21):7935.CrossRefGoogle Scholar
  18. [18]
    Xin G, Pan HF, Chen D, Zhang ZH, Wen B. Synthesis and photocatalytic activity of N-doped TiO2 produced in a solid phase reaction. J Phys Chem Solids. 2013;74(2):286.CrossRefGoogle Scholar
  19. [19]
    Yu HJ, Shi R, Zhao YX, Bian T, Zhao YF, Zhou C, Waterhouse GI, Wu LZ, Tung CH, Zhang T. Alkali-assisted synthesis of nitrogen deficient graphitic carbon nitride with tunable band structures for efficient visible-light-driven hydrogen evolution. Adv Sci News. 2017;29(16):1605148.Google Scholar
  20. [20]
    Xia DH, Wang WJ, Yin R, Jiang ZF, An TC, Li GY, Zhao HJ, Wong PK. Enhanced photocatalytic inactivation of Escherichia coli by a novel Z-scheme g-C3N4/m-Bi2O4 hybrid photocatalyst under visible light: the role of reactive oxygen species. Appl Catal B. 2017;214:23.CrossRefGoogle Scholar
  21. [21]
    Zou YJ, Shi JW, Ma DD, Fan ZY, Lu L, Niu CM. In situ synthesis of C-doped TiO2@g-C3N4 core-shell hollow nanospheres with enhanced visible-light photocatalytic activity for H2 evolution. Chem Eng J. 2017;322:435.CrossRefGoogle Scholar
  22. [22]
    Chen TT, Song CJ, Fan MS, Hong YZ, Hu B, Yu LB, Shi WD. In-situ fabrication of CuS/g-C3N4 nanocomposites with enhanced photocatalytic H2-production activity via photoinduced interfacial charge transfer. Int J Hydrogen Energy. 2017;42(17):12210.CrossRefGoogle Scholar
  23. [23]
    Sun SW, Ji CN, Wu LL, Chi SH, Qu RJ, Li Y, Lu YX, Sun CM, Xue ZX. Facile one-pot construction of α-Fe2O3/g-C3N4 heterojunction for arsenic removal by synchronous visible light catalysis oxidation and adsorption. Mater Chem Phys. 2017;194:1.CrossRefGoogle Scholar
  24. [24]
    Wang FL, Chen P, Feng YP, Xie ZJ, Liu Y, Su YH, Zhang QX, Wang YF, Yao K, Lv WY, Liu GG. Facile synthesis of N-doped carbon dots/g-C3N4 photocatalyst with enhanced visible-light photocatalytic activity for the degradation of indomethacin. Appl Catal B. 2017;207:103.CrossRefGoogle Scholar
  25. [25]
    Wang JJ, Tang L, Zeng GM, Deng YC, Liu YN, Wang LL, Zhou YY, Guo Z, Wang JJ, Zhang C. Atomic scale g-C3N4/Bi2WO6 2D/2D heterojunction with enhanced photocatalytic degradation of ibuprofen under visible light irradiation. Appl Catal B. 2017;209:285.CrossRefGoogle Scholar
  26. [26]
    Silva GTSTD, Carvalho KTG, Lopes OF, Ribeiro C. g-C3N4/Nb2O5 heterostructures tailored by sonochemical synthesis: enhanced photocatalytic performance in oxidation of emerging pollutants driven by visible radiation. Appl Catal B. 2017;216:70.CrossRefGoogle Scholar
  27. [27]
    Miao XL, Ji ZY, Wu JJ, Shen XP, Wang JH, Kong LR, Liu MM, Song CS. g-C3N4/AgBr nanocomposite decorated with carbon dots as a highly efficient visible-light-driven photocatalyst. J Colloid Interface Sci. 2017;502:24.CrossRefGoogle Scholar
  28. [28]
    Li YF, Fang L, Jin RX, Xu YY, Fang X, Xing Y, Song SY. Preparation and enhanced visible light photocatalytic activity of novel g-C3N4 nanosheets loaded with Ag2CO3 nanoparticles. Nanoscale. 2015;7:758.CrossRefGoogle Scholar
  29. [29]
    Li QB, Zhao X, Yang J, Jia CJ, Jin Z, Fan WL. Exploring the effects of nanocrystal facet orientations in g-C3N4/BiOCl heterostructures on photocatalytic performance. Nanoscale. 2015;7:18971.CrossRefGoogle Scholar
  30. [30]
    Zhao H, Ding XL, Zhang B, Li YX, Wang CY. Enhanced photocatalytic hydrogen evolution along with byproducts suppressing over Z-scheme CdxZn1−xS/Au/g-C3N4 photocatalysts under visible light. Sci Bull. 2017;62(9):602.CrossRefGoogle Scholar
  31. [31]
    Singh JA, Overbury SH, Dudney NJ, Li MJ, Veith GM. Gold nanoparticles supported on carbon nitride: influence of surface hydroxyls on low temperature carbon monoxide oxidation. ACS Catal. 2012;2(6):1138.CrossRefGoogle Scholar
  32. [32]
    Bu YY, Chen ZY, Li WB. Using electrochemical methods to study the promotion mechanism of the photoelectric conversion performance of Ag-modified mesoporous g-C3N4 heterojunction material. Appl Catal B. 2014;144:622.CrossRefGoogle Scholar
  33. [33]
    Chang C, Fu Y, Hu M, Wang CY, Shan GQ, Zhu LY. Photodegradation of bisphenol A by highly stable palladium-doped mesoporous graphite carbon nitride (Pd/mpg-C3N4) under simulated solar light irradiation. Appl Catal B. 2013;142–143:553.CrossRefGoogle Scholar
  34. [34]
    Zhang GG, Zhang MW, Ye XX, Qiu XQ, Lin S, Wang XC. Iodine modified carbon nitride semiconductors as visible light photocatalysts for hydrogen evolution. Adv Mater. 2014;26(5):805.CrossRefGoogle Scholar
  35. [35]
    Yan SC, Li ZS, Zou ZG. Photodegradation of rhodamine B and methyl orange over boron-doped g-C3N4 under visible light irradiation. Langmuir. 2010;26(6):3894.CrossRefGoogle Scholar
  36. [36]
    Xu JS, Brenner TJK, Chen ZP, Neher D, Antonietti M, Shalom M. Upconversion-agent induced improvement of g-C3N4 photocatalyst under visible light. ACS Appl Mater Interfaces. 2014;6(19):16481.CrossRefGoogle Scholar
  37. [37]
    Liu G, Niu P, Sun CH, Smith SC, Chen ZG, Lu GQ, Cheng HM. Unique electronic structure induced high photoreactivity of sulfur-doped draphitic C3N4. J Am Chem Soc. 2010;132(33):11642.CrossRefGoogle Scholar
  38. [38]
    Zhang LG, Chen XF, Guan J, Jiang YJ, Hou TG, Mu XD. Facile synthesis of phosphorus doped graphitic carbon nitride polymers with enhanced visible-light photocatalytic activity. Mater Res Bull. 2013;48(9):3485.CrossRefGoogle Scholar
  39. [39]
    Fang WJ, Liu JY, Yu L, Jiang Z, Shangguang WF. Novel (Na, O) co-doped g-C3N4 with simultaneously enhanced absorption and narrowed bandgap for highly efficient hydrogen evolution. Appl Catal B. 2017;209:631.CrossRefGoogle Scholar
  40. [40]
    Gao JT, Wang Y, Zhou SJ, Lin W, Kong Y. A facile one-step synthesis of Fe-doped g-C3N4 nanosheets and their improved visible-light photocatalytic performance. Chemcatchem. 2017;9(9):1708.CrossRefGoogle Scholar
  41. [41]
    Wang XC, Chen XF, Thomas A, Fu XZ, Antonietti M. Metal-containing carbon nitride compounds: a new functional organic-metal hybrid material. Adv Mater. 2009;21(16):1609.CrossRefGoogle Scholar
  42. [42]
    Yue B, Li QY, Iwai H, Kako T, Ye JH. Hydrogen production using zinc-doped carbon nitride catalyst irradiated with visible light. Sci Technol Adv Mater. 2011;12(3):034401.CrossRefGoogle Scholar
  43. [43]
    Dong F, Wu LW, Sun YJ, Fu M, Wu ZB, Lee SC. Efficient synthesis of polymeric g-C3N4 layered materials as novel efficient visible light driven photocatalysts. J Mater Chem. 2011;21(39):15171.CrossRefGoogle Scholar
  44. [44]
    Cao SW, Low JX, Yu JG, Jaroniec M. Polymeric photocatalysts based on graphitic carbon nitride. Adv Mater. 2015;27(13):2150.CrossRefGoogle Scholar
  45. [45]
    Tonda S, Kumar S, Kandula S, Shanker V. Fe-doped and -mediated graphitic carbon nitride nanosheets for enhanced photocatalytic performance under natural sunlight. J Mater Chem A. 2014;2:6772.CrossRefGoogle Scholar
  46. [46]
    Futsuhara M, Yoshiokab K, Takaia O. Structural, electrical and optical properties of zinc nitride thin films prepared by reactive rf magnetron sputtering. Thin Solid Films. 1998;322(1–2):274.CrossRefGoogle Scholar
  47. [47]
    Qiu PX, Chen H, Xu CM, Zhou N, Jiang F, Wang X, Fu YS. Fabrication of an exfoliated graphitic carbon nitride as a highly active visible light photocatalyst. J Mater Chem A. 2015;3:24237.CrossRefGoogle Scholar
  48. [48]
    Zhu YM, Xu GY, Guo TC, Hou HL, Tan SJ. Preparation, infrared emissivity and thermochromic properties of Co doped ZnO by solid state reaction. J Alloys Compd. 2017;720:105–15.CrossRefGoogle Scholar
  49. [49]
    Wang DH, Hui SE, Liu CC. Mass loss and evolved gas analysis in thermal decomposition of solid urea. Fuel. 2017;207:268.CrossRefGoogle Scholar
  50. [50]
    Schaber PM, Colson J, Higgins S, Thielen D, Anspach B, Brauer J. Thermal decomposition (pyrolysis) of urea in an open reaction vessel. Thermochim Acta. 2004;424(1–2):131.CrossRefGoogle Scholar
  51. [51]
    Cong CJ, Luo ST, Tao YT, Zhang KL. Kinetics of thermal decomposition of Zn(Ac)2·2H2O in air atmosphere. Chem J Chin Univ. 2005;26(12):2327.Google Scholar
  52. [52]
    Mohamed MB, Abdel-Kader MH, Alhazime AA, Almarashi JQM. Effect of preparation methods and doping on the structural and tunable emissions of CdS. J Mol Struct. 2018;1155:666.CrossRefGoogle Scholar

Copyright information

© The Nonferrous Metals Society of China and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of ScienceNortheastern UniversityShenyangChina

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