Journal of the Geological Society of India

, Volume 86, Issue 2, pp 223–232 | Cite as

Zircon U-Pb age and geochemical characteristics of ore-bearing granodiorite porphyry in the Duobuza porphyry copper deposit, Tibet

  • Guangchun Fei
  • Xiong Zhou
  • Ji Duo
  • Yu Zhou
  • Chun-Qi Wen
  • Quan Wen
  • Yangyang He
  • Yan Huo
  • Zhengxi Yang
  • Jinshu Zhang
  • Hongfei Liu
Research Articles

Abstract

The Duobuza deposit is the first porphyry-type copper deposit discovered with giant prospect in the Bangongco metallogenic belt. Geochemical data indicates that the ore-bearing Duobuza granodiorite porphyry is high-K calc-alkaline to shoshonitic and peraluminous composition. The ore-bearing granodiorite porphyry is enriched in large-ion lithophile elements(LILE) such as Rb, K, Th, La, Ce and Sr, and depleted in high-field-strength elements(HFSE) such as Nb, Ta, P, and Ti. The rare-earth element (REE) patterns show enrichment in light REEs relative to heavy REEs. The major, rareearth, and trace elements of the ore-bearing granodiorite porphyry show characteristics of adakites, formed in an island arc setting. The laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) zircon U–Pb age of the orebearing granodiorite porphyry is 123.4±1.2 Ma (MSWD = 1.7), which also represents the age of the copper-mineralization. Together with the age data of the early Cretaceous magmatic rocks in the Bangongco–Nujiang suture zone and the middle-northern Gangdese, it indicates that there was bidirectional (northward and southward) subduction of the Bangongco–Nujiang ocean during 120 Ma, and the Duobuza deposit was related to this event.

Keywords

Granodiorite Porphyry zircon LA-ICP-MS U-Pb age Duobuza tectonic setting Tibet 

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References

  1. Batchelor, R.B. and Bowden, P. (1985) Petrogenetic interpretation of granitoid rock series using multicationic parameters. Chem. Geol, v.48, pp.43–55.CrossRefGoogle Scholar
  2. Ben, O.D., White, W.M. and Patchett, J. (1989) Geochemistry of marine sediments, island arc magma genesis, and crustmantle recycling. Earth Planet. Sci. Lett, v.94, pp.1–21.CrossRefGoogle Scholar
  3. Castillo, P.R. (2006) An overview of adakite petrogenesis. Chinese Sci. Bull., v. 51, pp. 257–268.CrossRefGoogle Scholar
  4. Defant, M.J. and Drummond, M.S. (1990) Derivation of some modern arc magmas by melting of young subducted lithosphere. Nature, v.347, pp.662–665.CrossRefGoogle Scholar
  5. Defant, M.J., Xu, J.F., Kepezhinskas, P., Wang, Q., Zhang, Q. and Xiao, L.(2002) Adakites: some variations on a theme. Acta. Petrol. Sin, v.18, pp.129–142.Google Scholar
  6. Ding, L., Kapp, P., Yin, A., Deng, W.M. and Zhong, D.L. (2003) Early Tertiary volcanism in the Qiangtang terrane of central Tibet: evidence for a transition from oceanic to continental subduction. Jour. Petrol., v.44, pp.1833–1865.CrossRefGoogle Scholar
  7. Du, D.D., Qu, X.M., Wang, G.H., Xin, H.B. and Liu, Z.B. (2011) Bidirectional subduction of the Middle Tethys oceanic basin in the west segment of Bangongco-Nujiang suture£¬Tibet: Evidence from zircon U-Pb LA-ICP MS dating and petrogeochemistry of arc granites. Acta. Petrol. Sin., v.27, pp.1993–2002.Google Scholar
  8. Fei, G.C., Wen, C.Q., Wang, C.S., Zhou, X., Wu, P.Y., Wen, Q. and Zhou, Y.(2010a) Zircon SHRIMP U-Pb age of porphyry granite in Dongzhongla lead-zinic deposit, Mozhugongka County, Tibet. Geol. China, v.37, pp.470–476.Google Scholar
  9. Fei, G. C., Wen, C.Q., Wang, C.S., Wu, P.Y., Wen, Q. and Zhou, X. (2010b) Zircon SHRIMP U-Pb age of allgovite in Dongzhongla, east gangdise, and it’s geological significance. Geol. Bull. China, v.29, pp.1138–1142.Google Scholar
  10. GrifFin, W.L., Wang, X., Jackson, S.E., Pearson, N.J., O’Reilly, S.Y., Xu, X. and Zhou, X.(2002) Zircon chemistry and magma mixing, SE China: in-situ analysis of Hf isotopes. Tonglu and Pingtan igneous complexes. Lithos, v.61, pp.237–269.CrossRefGoogle Scholar
  11. Hou, Z.Q., Gao, Y.F., Qu, X.M., Rui, Z.Y. and Mo, X.X. (2004) Origin of adakitic intrusives generated during mid-Miocene East-west extension in southern Tibet. Earth Planet. Sci. Lett., v.220, pp.139–155.CrossRefGoogle Scholar
  12. Hawkesworth, C.J., Gallagher, K., Hergt, J.M. and Mcdermott, F. (1993) Mantle and slab contributions in arc magmas. Ann. Rev. Earth Planet. Sci., v.21, pp.175–204.CrossRefGoogle Scholar
  13. Huang, J.Q and Chen, B.W. (1987) Geological evolution of Tethys sea around China and its adjacent areas. Beijing Geological Publishing House, pp.1–78.Google Scholar
  14. Kapp, P., Murphy, M.A., Yin, A., Harrison, M.T., Ding, L. and Guo, J.H. (2003) Mesozoic and Cenozoic tectonic evolution of the Shiquanhe area of western Tibet. Tectonics, v.22, pp.10–29.Google Scholar
  15. Li, G.M., Li, J.X., Qin, K.Z., Duo, J., Zhang, T. P., Xiao B. and Zhao, J.X. (2012) Geology and Hydrothermal Alteration of the Duobuza Gold-Rich Porphyry Copper District in the Bangongco Metallogenetic Belt, Northwestern Tibet. Resour. Geol., v.62, pp. 99–118.CrossRefGoogle Scholar
  16. Li, G.M., Li, J.X., Qin, K.Z., Duo, J., Zhang, T.P. and Xiao, B.(2007) High temperature, salinity and strong oxidation oreforming fluid at Duobuza gold-rich porphyry copper in the Bangongco tectonic belt, Tibet: evidence from fluid inclusions study. Acta. Petrol. Sin., v.23, pp.935–52.Google Scholar
  17. Li, J.X., Li, G.M., Qin, K.Z. and Xiao, B. (2011a) High temperature primarymagmatic fluid directly exsolved from magma at Duobuza gold-rich porphyry copper deposit, Northern Tibet. Geofluids, v.11, pp.134–143.CrossRefGoogle Scholar
  18. Li, J.X., Li, G.M., Qin, K.Z. and Xiao, B. (2008) Geochemistry of porphyries and volcanic rocks and ore-forming geochronology of Duobuza gold-rich porphyry copper deposit in Bangongco belt, Tibet: Constraints on metallogenetic tectonic settings. Acta. Petrol. Sin., v.24, pp.531–543.Google Scholar
  19. Li, J.X., Li, G.M., Qin, K.Z. and Xiao, B., Zhao, J. X. and Chen, L. (2011b) Magma-hydrothermal evolution of the Cretaceous Duolong gold-rich porphyry copper deposit in the Bangongco metallogenetic belt, Tibet: evidence from U-Pb and 40Ar/39Ar geochronology. Jour. Asian Earth Sci., v.41, pp.525–536.CrossRefGoogle Scholar
  20. Li, J.X., Li, G.M., Qin, K. Z., Xiao, B., Chen, L. and Zhao, J. X. (2012) Mineralogy andmineral chemistry of the Cretaceous Duolong gold-rich porphyry copper deposit in the Bangongco arc,Northern Tibet. Resource Geol., v.62, pp.19–41.CrossRefGoogle Scholar
  21. Li, Y.B., Duo, J., Zhong, W.T., Li, Y.C., Qiangba, W.D., Chen, H.Q., Liu, H.F., Zhang, J.S., Zhang, T.P., Xu, Z.Z., Fan, A.H. and Suo Lang, W.Q. (2012) An exploration model of the Duobuza porphyry copper deposit in Gerze Couty, northern Tibet. Geol. Explor., v.48, pp.274–287.Google Scholar
  22. Ludwig, K.R.(2003) Isoplot 3.0-A geochronological toolkit for Microsoft Excel[M]. Berkeley Geochronology Center, pp.1–70.Google Scholar
  23. Martin, H. (1999) The adakitic magmas: modern analogues of Archaean granitoids. Lithos, v.46, pp.411–429.CrossRefGoogle Scholar
  24. Martin, H., Smithies, R.H., Rapp, R., Moyen, J.F. and Champion, D. (2005) An overview of adakite, tonalite–trondhjemite–granodiorite (TTG), and sanukitoid: relationships and some implications for crustal evolution. Lithos, v.79, pp.1–24.CrossRefGoogle Scholar
  25. Mcculloch, M.T. and Gamble, J.A. (1991) Geochemical and geodynamical constraints on subduction zone magmatism. Earth Planet. Sci. Lett, v.102, pp.358–374.CrossRefGoogle Scholar
  26. Mo, X.X., Dong, G.C., Zhao, Z.D., Zhou, S., Wang, L.L., Qiu, R.Z. and Zhang, F.Q. (2005) Spatial and temporal distribution and characteristics of granitoids in the Gangdese, Tibet and implication for crustal growth and evolution. Geol. Jour. China Universities, v.11, pp.281–290.Google Scholar
  27. Murphy, M.A., Harrison, T.M., Durr, S.B., Chen, Z., Ryerson, F.J., Kidd, W.S.F., Wang, X. and Zhou, X. (1997) Significant crustal shortening in south central Tibet prior to the Indo-Asian collision. Geology, v.25, pp.719–722.CrossRefGoogle Scholar
  28. Pan, G.T., Wang, L.Q. and Zhu, D.C. (2004) Thoughts on some important scientific problems in regional geological survey of the Qinghai-Tibet Plateau. Geol. Bull. China, v.23, pp.12–19.Google Scholar
  29. Pan, G.T., Chen, Z.L., Li, X.Z., Yang, Y.J., Xu, X.S., Xu, Q., Jiang, X.S., Wu, Y.L., Luo, J.N., Zhu, T.X. and Peng, Y.M. (1997) Geological–Tectonic Evolution in the Eastern Tethys. Geological Publishing House, pp.1–218.Google Scholar
  30. Peccerillo, A. and Taylor, S.R. (1976) Geochemistry of Eocene calc–alkaline volcanic rocks from the Kastamonu area, Northern Turkey. Contrib. Mineral. Petrol., v.1, pp.63–81.CrossRefGoogle Scholar
  31. Qu, X.M. and Xin, H.B. (2006) Ages and tectonic environment of the Bangong Co porphyry copper belt in western Tibet, China. Geol. Bull. China, v.25, pp.792–799.Google Scholar
  32. Rickwood, P. C. (1989) Boundary lines within petrologic diagrams which use oxides of major and minor elements. Lithos, v.22, pp.247–263.CrossRefGoogle Scholar
  33. Shand, S.J. (1947) Eruptive rocks: their genesis, composition, classification, and their relation to ore-deposits, with a chapter on meteorites, 3rd edition. John Wiley, New York, 488p.Google Scholar
  34. She, H.Q., Li, J.W., Ma, D.F., Li, G.M., Zhang, D.Q., Feng, C.Y., Qu, W.J. and Pan, G. T.(2009) Molybdenite Re-Os and SHRIMP zircon U-Pb dating of Duobuza porphyry copper deposit in Tibet and its geological implications. Miner. Deposit, v.28,pp.737–746.Google Scholar
  35. Simon, E.J., Norman, J.P. and William, L.G.. (2004) The application of laser ablation-inductively coupled plasma-mass spectrometry to in-situ U-Pb zircon geochronolgy. Chem. Geol, v.211, pp.47–69.CrossRefGoogle Scholar
  36. Sun, S.S. and Mcdonough, W.F. (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. In: M.J. Norry and A.D. Saunders (Eds.), Magmatism in the Ocean Basins. Geological Society Special Publication, London, pp.313–345.Google Scholar
  37. Wilson, M. (1989) Igneous Petrogenesis: a global tectonic approach. Uniwin Hyman, London.CrossRefGoogle Scholar
  38. Yuan, H.L., Gao, S., Dai, M.N., Zong, C.L., Günther, D., Fontaine, G.H., Liu, X.M. and Diwu, C.R. (2008) Simultaneous determinations of U–Pb age, Hf isotopes and trace element compositions of zircon by excimer laser ablation quadrupole and multiple collector ICP-MS. Chem. Geol, v.247, pp.100–117.CrossRefGoogle Scholar
  39. Yuan, H.L., Gao, S., Liu, X.M., Li, H.M., Gunther, D. and Wu, F.Y.(2004) Accurate U-Pb age and trace element determinations of zircon by laser ablation-inductively coupled plasma mass spectrometry. Geostandards Newsletter, v.28, pp.353–370.CrossRefGoogle Scholar
  40. Zhang, K.J., Xia, B.D., Wang, G.M., Li, Y.T. and Ye, H.F. (2004) Early Cretaceous stratigraphy, depositional environments, sandstone provenance, and tectonic setting of central Tibet, western China. GSA Bull., v.116, pp.1202–1222.CrossRefGoogle Scholar
  41. Zhang, Q., Qin, K.Z., Wang, Y.L., Zhang, F.Q., Liu, H.T. and Wang, Y.(2004) Study on adakite broadened to challenge the Cu and Au exploration in China. Acta. Petrol. Sin., v.20, pp.195–204.Google Scholar
  42. Zhu, D.C., Pan, G.T., Mo, X.X., Wang, L.Q., Liao, Z.L., Zhao, Z.D., Dong, G.C. and Zhou, C.Y. (2006) Late Jurassic–Early Cretaceous geodynamic setting in middle–northern Gangdese: new insights from volcanic rocks. Acta. Petrol. Sin., v.22, pp.534–546.Google Scholar
  43. Zhu, D.C., Mo, X.X., Niu, Y.L., Zhao, Z.D., Wang, L.Q., Liu, Y.S. and Wu, F.Y. (2009) Geochemical investigation of Early Cretaceous igneous rocks along an east–west traverse throughout the central Lhasa Terrane, Tibet. Chem. Geol., v.268, pp.298–312.CrossRefGoogle Scholar

Copyright information

© Geological Society of India 2015

Authors and Affiliations

  • Guangchun Fei
    • 1
    • 2
  • Xiong Zhou
    • 3
  • Ji Duo
    • 4
  • Yu Zhou
    • 2
    • 3
  • Chun-Qi Wen
    • 2
  • Quan Wen
    • 2
  • Yangyang He
    • 2
  • Yan Huo
    • 2
  • Zhengxi Yang
    • 2
  • Jinshu Zhang
    • 4
  • Hongfei Liu
    • 4
  1. 1.Key Laboratory of Tectonic Controls on Mineralization and Hydrocarbon Accumulation, Ministry of Land and ResourcesChengdu University of TechnologyChengduChina
  2. 2.College of Earth SciencesChengdu University of TechnologyChengduSichuanChina
  3. 3.Institute of Multipurpose Utilization of Mineral ResourcesChinese Academy of Geological SciencesChengduChina
  4. 4.Geological and Mineral Resources Exploration Bureau of TibetLasa, TibetChina

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