Metals and Materials International

, Volume 22, Issue 1, pp 26–33 | Cite as

Surface and cut-edge corrosion behavior of Zn-Mg-Al alloy-coated steel sheets as a function of the alloy coating microstructure

  • Min-Suk OhEmail author
  • Sang-Heon Kim
  • Jong-Sang Kim
  • Jae-Won Lee
  • Je-Ha Shon
  • Young-Sool Jin


The effects of Mg and Al content on the microstructure and corrosion resistance of hot-dip Zn-Mg-Al alloycoated steel sheets were investigated. Pure Zn and Zn-based alloy coatings containing Mg (0-5 wt%) and Al (0.2-55 wt%) were produced by a hot-dip galvanizing method. Mg and Al addition induced formation of intermetallic microstructures, like primary Zn, Zn/MgZn2 binary eutectic, dendric Zn/Al eutectoid, and Zn/Al/MgZn2/ternary eutectic structures in the coating layer. MgZn2-related structures (Zn/MgZn2, Zn/Al/MgZn2, MgZn2) played an important role in increasing the corrosion resistance of Zn-Mg-Al alloy-coated steel sheets. Zn-3%Mg-2.5%Al coating layer containing a large volume of lamellar-shaped Zn/MgZn2 binary eutectic structures showed the best cut-edge corrosion resistance. The analysis indicated that Mg dissolved from MgZn2 in the early stage of corrosion and migrated to the cathodic region of steel-exposed cut-edge area to form dense and ordered protective corrosion products, leading to prolonged cathodic protection of Zn-Mg-Al alloy-coated steel sheets.


Zn-Mg-Al alloy-coated steel sheet microstructure corrosion galvanization coating 


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Copyright information

© The Korean Institute of Metals and Materials and Springer Science+Business Media Dordrecht 2016

Authors and Affiliations

  • Min-Suk Oh
    • 1
    Email author
  • Sang-Heon Kim
    • 1
  • Jong-Sang Kim
    • 1
  • Jae-Won Lee
    • 2
  • Je-Ha Shon
    • 2
  • Young-Sool Jin
    • 3
  1. 1.POSCO Technical Research LaboratoriesJeonnamSouth Korea
  2. 2.POMIA (Pohang Institute of Metal Industry Advancement)PohangSouth Korea
  3. 3.GIFT, Pohang University of Science and Technology (POSTECH)PohangSouthKorea

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