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Metal-organic frameworks-derived nitrogen-doped carbon supported nanostructured PtNi catalyst for enhanced hydrosilylation of 1-octene

  • Junfeng Wen
  • Yuanjun Chen
  • Shufang JiEmail author
  • Jian Zhang
  • Dingsheng Wang
  • Yadong LiEmail author
Research Article
  • 65 Downloads

Abstract

Here, we successfully developed nanostructured PtNi particles supported on nitrogen-doped carbon (NC), which were obtained by carbonization of metal-organic frameworks under different temperatures, forming the nano-PtNi/NC-600, nano-PtNi/NC-800, nano-PtNi/NC-900 and nano-PtNi/NC-1000 catalysts. For hydrosilylation of 1-octene, we found that the nano-PtNi/NC-1000 catalyst exhibits higher activity for anti-Markovnikov hydrosilylation of 1-octene than those of nano-PtNi/NC-600, nano-PtNi/NC-800, nano-PtNi/NC-900 catalysts. Experiments have verified that benefiting from obvious charge transfer from nano-PtNi particles to NC support carbonized at 1,000 °C, the nano-PtNi/NC-1000 catalyst achieved almost complete conversion and produce exclusive adduct for anti-Markovnikov hydrosilylation of 1-octene. Importantly, the nano-PtNi/NC-1000 catalyst exhibited good reusability for the hydrosilylation reaction. This work provides a new path to optimize electronic structure of catalysts by support modification to enhance electron transfer between metal active species and supports for highly catalytic performance.

Keywords

metal-organic frameworks nanostructured PtNi particles hydrosilylation nitrogen-doped carbon 

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Notes

Acknowledgements

This work was supported by the National Postdoctoral Program for Innovative Talents (No. BX20180160), the China Postdoctoral Science Foundation (No. 2018M640113), the National Natural Science Foundation of China (No. 21890383) and the Industrial Science and Technology Tackling Program of Shaanxi Province (No. 2016GY-245).

Supplementary material

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Metal-organic frameworks-derived nitrogen-doped carbon supported nanostructured PtNi catalyst for enhanced hydrosilylation of 1-octene

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Copyright information

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of chemistry and chemical engineeringYulin UniversityYulinChina
  2. 2.Department of ChemistryTsinghua UniversityBeijingChina

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