Nano Research

, Volume 11, Issue 3, pp 1500–1519 | Cite as

Application of yolk–shell Fe3O4@N-doped carbon nanochains as highly effective microwave-absorption material

  • Mingtao Qiao
  • Xingfeng Lei
  • Yong Ma
  • Lidong Tian
  • Xiaowei He
  • Kehe Su
  • Qiuyu ZhangEmail author
Research Article


Yolk–shell Fe3O4@N-doped carbon nanochains, intended for application as a novel microwave-absorption material, have been constructed by a three-step method. Magnetic-field-induced distillation-precipitation polymerization was used to synthesize nanochains with a one-dimensional (1D) structure. Then, a polypyrrole shell was uniformly applied to the surface of the nanochains through oxidant-directed vapor-phase polymerization, and finally the pyrolysis process was completed. The obtained products were characterized by X-ray diffraction (XRD), X-ray photoelectron spectra (XPS), and thermogravimetric analyses (TGA) to confirm the compositions. The morphology and microstructure were observed using an optical microscope, scanning electron microscope (SEM), and transmission electron microscope (TEM). The N2 absorption–desorption isotherms indicate a Brunauer–Emmett–Teller (BET) specific surface area of 74 m2/g and a pore width of 5–30 nm. Investigations of the microwave absorption performance indicate that paraffin-based composites loaded with 20 wt.% yolk–shell Fe3O4@N-doped carbon nanochains possess a minimum reflection loss of −63.09 dB (11.91 GHz) and an effective absorption bandwidth of 5.34 GHz at a matching layer thickness of 3.1 mm. In addition, by tailoring the layer thicknesses, the effective absorption frequency bands can be made to cover most of the C, X, and Ku bands. By offering the advantages of stronger absorption, broad absorption bandwidth, low loading, thin layers, and intrinsic light weight, yolk–shell Fe3O4@N-doped carbon nanochains will be excellent candidates for practical application to microwave absorption. An analysis of the microwave absorption mechanism reveals that the excellent microwave absorption performance can be explained by the quarter-wavelength cancellation theory, good impedance matching, intense conductive loss, multiple reflections and scatterings, dielectric loss, magnetic loss, and microwave plasma loss.


yolk–shell nanochains Fe3O4 polypyrrole N-doped carbon microwave absorption 


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The authors are grateful for the financial support provided by the National Natural Science Foundation of China (Nos. 51433008 and 51673156).

Supplementary material

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Application of yolk–shell Fe3O4@N-doped carbon nanochains as highly effective microwave-absorption material


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Copyright information

© Tsinghua University Press and Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Mingtao Qiao
    • 1
  • Xingfeng Lei
    • 1
  • Yong Ma
    • 1
  • Lidong Tian
    • 1
  • Xiaowei He
    • 1
  • Kehe Su
    • 1
  • Qiuyu Zhang
    • 1
    Email author
  1. 1.Department of Applied Chemistry, Key Laboratory of Space Applied Physics and Chemistry of Ministry of Education, School of ScienceNorthwestern Polytechnical UniversityXi’anChina

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