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Nano Research

, Volume 10, Issue 12, pp 4298–4304 | Cite as

Embedding CoS2 nanoparticles in N-doped carbon nanotube hollow frameworks for enhanced lithium storage properties

  • Jintao Zhang
  • Le Yu
  • Xiong Wen David Lou
Research Article

Abstract

The construction of metal sulfides-carbon nanocomposites with a hollow structure is highly attractive for various energy storage and conversion technologies. Herein, we report a facile two-step method for preparing a nanocomposite with CoS2 nanoparticles in N-doped carbon nanotube hollow frameworks (NCNTFs). Starting from zeolitic imidazolate framework-67 (ZIF-67) particles, in situ reduced metallic cobalt nanocrystals expedite the formation of the hierarchical hollow frameworks from staggered carbon nanotubes via a carbonization process. After a follow-up sulfidation reaction with sulfur powder, the embedded cobalt crystals are transformed into CoS2 nanoparticles. Benefitting from the robust hollow frameworks made of N-doped carbon nanotubes and highly active CoS2 ultrafine nanoparticles, this advanced nanocomposite shows greatly enhanced lithium storage properties when evaluated as an electrode for lithium-ion batteries. Impressively, the resultant CoS2/NCNTF material delivers a high specific capacity of ∼937 mAh·g–1 at a current density of 1.0 A·g–1 with a cycle life longer than 160 cycles.

Keywords

CoS2 carbon nanotube metal-organic framework lithium-ion batteries 

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Embedding CoS2 nanoparticles in N-doped carbon nanotube hollow frameworks for enhanced lithium storage properties

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Copyright information

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  1. 1.School of Chemical and Biomedical EngineeringNanyang Technological UniversitySingaporeSingapore

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