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Nano Research

, Volume 8, Issue 1, pp 156–164 | Cite as

Uniform MnO2 nanostructures supported on hierarchically porous carbon as efficient electrocatalysts for rechargeable Li-O2 batteries

  • Xiaopeng Han
  • Fangyi Cheng
  • Chengcheng Chen
  • Yuxiang Hu
  • Jun Chen
Research Article

Abstract

Through in situ redox deposition and growth of MnO2 nanostructures on hierarchically porous carbon (HPC), a MnO2/HPC hybrid has been synthesized and employed as cathode catalyst for non-aqueous Li-O2 batteries. Owing to the mild synthetic conditions, MnO2 was uniformly distributed on the surface of the carbon support, without destroying the hierarchical porous nanostructure. As a result, the as-prepared MnO2/HPC nanocomposite exhibits excellent Li-O2 battery performance, including low charge overpotential, good rate capacity and long cycle stability up to 300 cycles with controlling capacity of 1,000 mAh·g−1. A combination of the multi-scale porous network of the shell-connected carbon support and the highly dispersed MnO2 nanostructure benefits the transportation of ions, oxygen and electrons and contributes to the excellent electrode performance.

Keywords

lithium-oxygen batteries manganese oxide nanocomposite catalyst oxygen electrochemistry 

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Supplementary material

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References

  1. [1]
    Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. M. Li-O2 and Li-S batteries with high energy storage. Nat. Mater. 2012, 11, 19–29.CrossRefGoogle Scholar
  2. [2]
    Black, R.; Adams, B.; Nazar, L. F. Non-aqueous and hybrid Li-O2 batteries. Adv. Energy Mater. 2012, 2, 801–815.CrossRefGoogle Scholar
  3. [3]
    Cheng, F. Y.; Chen, J. Metal-air batteries: From oxygen reduction electrochemistry to cathode catalysts. Chem. Soc. Rev. 2012, 41, 2172–2192.CrossRefGoogle Scholar
  4. [4]
    Zhang, K.; Han, X. P.; Hu, Z.; Zhang, X. L.; Tao, Z. L.; Chen, J. Nanostructured Mn-based oxides for electrochemical energy storage and conversion. Chem. Soc. Rev., in press, DOI: 10.1039/C4CS00218K.Google Scholar
  5. [5]
    Li, F. J.; Zhang, T.; Zhou, H. S. Challenges of non-aqueous Li-O2 batteries: Electrolytes, catalysts, and anodes. Energy Environ. Sci. 2013, 6, 1125–1141.CrossRefGoogle Scholar
  6. [6]
    Cao, R. G.; Lee, J. S.; Liu, M. L.; Cho, J. Recent progress in non-precious catalysts for metal-air batteries. Adv. Energy Mater. 2012, 2, 816–829.CrossRefGoogle Scholar
  7. [7]
    Guo, Z. Y.; Zhou, D. D.; Dong, X. L.; Qiu, Z. J.; Wang, Y. G.; Xia, Y. Y. Ordered hierarchical mesoporous/macroporous carbon: A high-performance catalyst for rechargeable Li-O2 batteries. Adv. Mater. 2013, 25, 5668–5672.CrossRefGoogle Scholar
  8. [8]
    Xu, J. J.; Wang, Z. L.; Xu, D.; Zhang, L. L.; Zhang, X. B. Tailoring deposition and morphology of discharge products towards high-rate and long-life lithium-oxygen batteries. Nat. Commun. 2013, 4, 2438.Google Scholar
  9. [9]
    Yan, Y.; Yin, Y. X.; Guo, Y. G.; Wan, L. J. A sandwich-like hierarchically porous carbon/graphene composite as a high-performance anode material for sodium-ion batteries. Adv. Energy Mater. 2014, 4, 1301584.Google Scholar
  10. [10]
    Tang, Y. X.; Zhang, Y. Y.; Deng, J. Y.; Qi, D. P.; Leow, W. R.; Wei, J. Q.; Yin, S. Y.; Dong, Z. L.; Yazami, R.; Chen, Z. et al. Unravelling the correlation between the aspect ratio of nanotubular structures and their electrochemical performance to achieve high-rate and long-life lithium-ion batteries. Angew. Chem. Int. Ed., in press, DOI: 10.1039/C4CS00218K.Google Scholar
  11. [11]
    Tang, Y. X.; Zhang, Y. Y.; Deng, J. Y.; Wei, J. Q.; Tam, H. L.; Chandran, B. K.; Dong, Z. L.; Chen, Z.; Chen, X. D. Mechanical force-driven growth of elongated bending TiO2-based nanotubular materials for ultrafast rechargeable lithium ion batteries. Adv. Mater. 2014, 26, 6111–6118.CrossRefGoogle Scholar
  12. [12]
    Zhang, K.; Zhao, Q.; Tao, Z. L.; Chen, J. Composite of sulfur impregnated in porous hollow carbon spheres as the cathode of Li-S batteries with high performance. Nano Res. 2013, 6, 38–46.CrossRefGoogle Scholar
  13. [13]
    Peng, Z. Q.; Freunberger, S. A.; Chen, Y. H.; Bruce, P. G. A reversible and higher-rate Li-O2 battery. Science 2012, 337, 563–566.CrossRefGoogle Scholar
  14. [14]
    Lu, Y. C.; Xu, Z. C.; Gasteiger, H. A.; Chen, S.; Hamad-Schifferli, K.; Shao-Horn, Y. Platinum-gold nanoparticles: A highly active bifunctional electrocatalyst for rechargeable lithium-air batteries. J. Am. Chem. Soc. 2010, 132, 12170–12171.CrossRefGoogle Scholar
  15. [15]
    Lim, B.; Jiang, M. J.; Yu, T.; Camargo, P. H. C.; Xia, Y. N. Nucleation and growth mechanisms for Pd-Pt bimetallic nanodendrites and their electrocatalytic properties. Nano Res. 2010, 3, 69–80.CrossRefGoogle Scholar
  16. [16]
    Wu, J. B.; Yang, H. Synthesis and electrocatalytic oxygen reduction properties of truncated octahedral Pt3Ni nanoparticles. Nano Res. 2011, 4, 72–82.CrossRefGoogle Scholar
  17. [17]
    Li, J. Y.; Wang, G. X.; Wang, J.; Miao, S.; Wei, M. M.; Yang, F.; Yu, L.; Bao, X. H. Architecture of PtFe/C catalyst with high activity and durability for oxygen reduction reaction. Nano Res. 2014, 7, 1519–1527.CrossRefGoogle Scholar
  18. [18]
    Chen, S. G.; Wei, Z. D.; Qi, X. Q.; Dong, L. C.; Guo, Y. G.; Wan, L. J.; Shao, Z. G.; Li, L. Nanostructured polyaniline-decorated Pt/C@PANI core-shell catalyst with enhanced durability and activity. J. Am. Chem. Soc. 2012, 134, 13252–13255.CrossRefGoogle Scholar
  19. [19]
    Guo, S. J.; Li, D. G.; Zhu, H. Y.; Zhang, S.; Markovic, N. M.; Stamenkovic, V. R.; Sun, S. H. FePt and CoPt nanowires as efficient catalysts for the oxygen reduction reaction. Angew. Chem. Int. Ed. 2013, 52, 3465–3468.CrossRefGoogle Scholar
  20. [20]
    Débart, A.; Paterson, A. J.; Bao, J. L.; Bruce, P. G. α-MnO2 nanowires: A catalyst for the O2 electrode in rechargeable lithium batteries. Angew. Chem. Int. Ed. 2008, 47, 4521–4524.CrossRefGoogle Scholar
  21. [21]
    Wang, H. L.; Yang, Y.; Liang, Y. Y.; Zheng, G. Y.; Li, Y. G.; Cui, Y.; Dai, H. J. Rechargeable Li-O2 batteries with a covalently coupled MnCo2O4-graphene hybrid as an oxygen cathode catalyst. Energy Environ. Sci. 2012, 5, 7931–7935.CrossRefGoogle Scholar
  22. [22]
    Cao, Y.; Wei, Z. K.; He, J.; Zang, J.; Zhang, Q.; Zheng, M. S.; Dong, Q. F. α-MnO2 nanorods grown in situ on graphene as catalysts for Li-O2 batteries with excellent electrochemical performance. Energy Environ. Sci. 2012, 5, 9765–9768.CrossRefGoogle Scholar
  23. [23]
    Xu, J. J.; Xu, D.; Wang, Z. L.; Wang, H. G.; Zhang, L. L.; Zhang, X. B. Synthesis of perovskite-based porous La0.75Sr0.25MnO3 nanotubes as a highly efficient electrocatalyst for rechargeable lithium-oxygen batteries. Angew. Chem. Int. Ed. 2013, 52, 3887–3890.CrossRefGoogle Scholar
  24. [24]
    Cheng, F. Y.; Shen, J.; Peng, B.; Pan, Y. D.; Tao, Z. L.; Chen, J. Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts. Nat. Chem. 2011, 3, 79–84.CrossRefGoogle Scholar
  25. [25]
    Feng, J.; Liang, Y. Y.; Wang, H. L.; Li, Y. G.; Zhang, B.; Zhou, J. G.; Wang, J.; Regier, T.; Dai, H. J. Engineering manganese oxide/nanocarbon hybrid materials for oxygen reduction electrocatalysis. Nano Res. 2012, 5, 718–725.CrossRefGoogle Scholar
  26. [26]
    Han, X. P.; Hu, Y. X.; Yang, J. G.; Cheng, F. Y.; Chen, J. Porous perovskite CaMnO3 as an electrocatalyst for rechargeable Li-O2 batteries. Chem. Commun. 2014, 50, 1497–1499.CrossRefGoogle Scholar
  27. [27]
    Zhang, G. Q.; Xia, B. Y.; Xiao, C.; Yu, L.; Wang, X.; Xie, Y.; Lou, X. W. General formation of complex tubular nanostructures of metal oxides for the oxygen reduction reaction and lithium-ion batteries. Angew. Chem. Int. Ed. 2013, 52, 8643–8647.CrossRefGoogle Scholar
  28. [28]
    Jian, Z. L.; Liu, P.; Li, F. J.; He, P.; Guo, X. W.; Chen, M. W.; Zhou, H. S. Core-shell-structured CNT@RuO2 composite as a high-performance cathode catalyst for rechargeable Li-O2 batteries. Angew. Chem. Int. Ed. 2014, 53, 442–446.CrossRefGoogle Scholar
  29. [29]
    Sun, B.; Liu, H.; Munroe, P.; Ahn, H.; Wang, G. X. Nanocomposites of CoO and a mesoporous carbon (CMK-3) as a high performance cathode catalyst for lithium-oxygen batteries. Nano Res. 2012, 5, 460–469.CrossRefGoogle Scholar
  30. [30]
    Zhou, W. J.; Wu, X. J.; Cao, X. H.; Huang, X.; Tan, C. L.; Tian, J.; Liu, H.; Wang, J. Y.; Zhang, H. Ni3S2 nanorods/Ni foam composite electrode with low overpotential for electrocatalytic oxygen evolution. Energy Environ. Sci. 2013, 6, 2921–2924.CrossRefGoogle Scholar
  31. [31]
    Jung, H. G.; Hassoun, J.; Park, J. B.; Sun, Y. K.; Scrosati, B. An improved high-performance lithium-air battery. Nat. Chem. 2012, 4, 579–585.CrossRefGoogle Scholar
  32. [32]
    Chen, P.; Xiao, T. Y.; Qian, Y. H.; Li, S. S.; Yu, S. H. A nitrogen-doped graphene/carbon nanotube nanocomposite with synergistically enhanced electrochemical activity. Adv. Mater. 2013, 25, 3192–3196.CrossRefGoogle Scholar
  33. [33]
    Liang, J.; Du, X.; Gibson, C.; Du, X. W.; Qiao, S. Z. N-doped graphene natively grown on hierarchical ordered porous carbon for enhanced oxygen reduction. Adv. Mater. 2013, 25, 6226–6231.CrossRefGoogle Scholar
  34. [34]
    Liu, Z. Y.; Zhang, G. X.; Lu, Z. Y.; Jin, X. Y.; Chang, Z.; Sun, X. M. One-step scalable preparation of N-doped nanoporous carbon as a high-performance electrocatalyst for the oxygen reduction reaction. Nano Res. 2013, 6, 293–301.CrossRefGoogle Scholar
  35. [35]
    McCloskey, B. D.; Speidel, A.; Scheffler, R.; Miller, D. C.; Viswanathan, V.; Hummelshøj, J. S.; Nørskov, J. K.; Luntz, A. C. Twin problems of interfacial carbonate formation in nonaqueous Li-O2 batteries. J. Phys. Chem. Lett. 2012, 3, 997–1001.CrossRefGoogle Scholar
  36. [36]
    Gallant, B. M.; Mitchell, R. R.; Kwabi, D. G.; Zhou, J. G.; Zuin, L.; Thompson, C. V.; Shao-Horn, Y. Chemical and morphological changes of Li-O2 battery electrodes upon cycling. J. Phys. Chem. C 2012, 116, 20800–20805.CrossRefGoogle Scholar
  37. [37]
    Liu, J. P.; Jiang, J.; Cheng, C. W.; Li, H. X.; Zhang, J. X.; Gong, H.; Fan, H. J. Co3O4 nanowire@MnO2 ultrathin nanosheet core/shell arrays: A new class of high-performance pseudocapacitive materials. Adv. Mater. 2011, 23, 2076–2081.CrossRefGoogle Scholar
  38. [38]
    Cheng, F. Y.; Zhang, T. R.; Zhang, Y.; Du, J.; Han, X. P.; Chen, J. Enhancing electrocatalytic oxygen reduction on MnO2 with vacancies. Angew. Chem. Int. Ed. 2013, 52, 2474–2477.CrossRefGoogle Scholar
  39. [39]
    Han, X. P.; Cheng, F. Y.; Zhang, T. R.; Yang, J. G.; Hu, Y. X.; Chen, J. Hydrogenated uniform Pt clusters supported on porous CaMnO3 as a bifunctional electrocatalyst for enhanced oxygen reduction and evolution. Adv. Mater. 2014, 26, 2047–2051.CrossRefGoogle Scholar
  40. [40]
    Cui, Y. M.; Wen, Z. Y.; Liang, X.; Lu, Y.; Jin, J.; Wu, M. F.; Wu, X. W. A tubular polypyrrole based air electrode with improved O2 diffusivity for Li-O2 batteries. Energy Environ. Sci. 2012, 5, 7893–7897.CrossRefGoogle Scholar
  41. [41]
    Gorlin, Y.; Jaramillo, T. F. A bifunctional nonprecious metal catalyst for oxygen reduction and water oxidation. J. Am. Chem. Soc. 2010, 132, 13612–13614.CrossRefGoogle Scholar
  42. [42]
    El-Deab, M. S.; Ohsaka, T. Manganese oxide nanoparticles electrodeposited on platinum are superior to platinum for oxygen reduction. Angew. Chem. Int. Ed. 2006, 45, 5963–5966.CrossRefGoogle Scholar
  43. [43]
    Cheng, F. Y.; Su, Y.; Liang, J.; Tao, Z. L.; Chen, J. MnO2-based nanostructures as catalysts for electrochemical oxygen reduction in alkaline media. Chem. Mater. 2010, 22, 898–905.CrossRefGoogle Scholar
  44. [44]
    Roche, I.; Chaînet, E.; Chatenet, M.; Vondrák, J. Carbon-supported manganese oxide nanoparticles as electrocatalysts for the oxygen reduction reaction (ORR) in alkaline medium: Physical characterizations and ORR mechanism. J. Phys. Chem. C 2007, 111, 1434–1443.CrossRefGoogle Scholar
  45. [45]
    Han, X. P.; Zhang, T. R.; Du, J.; Cheng, F. Y.; Chen, J. Porous calcium-manganese oxide microspheres for electrocatalytic oxygen reduction with high activity. Chem. Sci. 2013, 4, 368–376.CrossRefGoogle Scholar
  46. [46]
    Black, R.; Lee, J. H.; Adams, B.; Mims, C. A.; Nazar, L. F. The role of catalysts and peroxide oxidation in lithium-oxygen batteries. Angew. Chem. Int. Ed. 2013, 52, 392–396.CrossRefGoogle Scholar

Copyright information

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  1. 1.Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Collaborative Innovation Center of Chemical Science and EngineeringNankai UniversityTianjinChina

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