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Nano Research

, Volume 5, Issue 7, pp 460–469 | Cite as

Nanocomposites of CoO and a mesoporous carbon (CMK-3) as a high performance cathode catalyst for lithium-oxygen batteries

  • Bing Sun
  • Hao Liu
  • Paul Munroe
  • Hyojun Ahn
  • Guoxiu WangEmail author
Research Article

Abstract

A nanocomposite of CoO and a mesoporous carbon (CMK-3) has been studied as a cathode catalyst for lithium-oxygen batteries in alkyl carbonate electrolytes. The morphology and structure of the as-prepared nanocomposite were characterized by field emission scanning electron microscopy, transmission electron microscopy and high resolution transmission electron microscopy. The electrochemical properties of the mesoporous CoO/CMK-3 nanocomposite as a cathode catalyst in lithium-oxygen batteries were studied using galvanostatic charge-discharge methods. The reaction products on the cathode were analyzed by Fourier transform infrared spectroscopy. The CoO/CMK-3 nanocomposite exhibited better capacity retention than bare mesoporous CMK-3 carbon, Super-P carbon or CoO/Super-P nanocomposite. The synergistic effects arising from the combination of CoO nanoparticles and the mesoporous carbon nanoarchitecture may be responsible for the optimum catalytic performance in lithium-oxygen batteries.

Keywords

Mesoporous carbon CMK-3 CoO catalyst Lithium-oxygen battery 

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Supplementary material

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Copyright information

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  • Bing Sun
    • 1
  • Hao Liu
    • 1
  • Paul Munroe
    • 2
  • Hyojun Ahn
    • 3
  • Guoxiu Wang
    • 1
    Email author
  1. 1.Centre for Clean Energy Technology, School of Chemistry and Forensic ScienceUniversity of TechnologySydneyAustralia
  2. 2.Electron Microscope UnitThe University of New South WalesSydneyAustralia
  3. 3.School of Materials Science and EngineeringGyeongsang National UniversityJinju, GyeongnamRepublic of Korea

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