Nano Research

, Volume 3, Issue 2, pp 126–137 | Cite as

Microwave synthesis of large few-layer graphene sheets in aqueous solution of ammonia

  • Izabela Janowska
  • Kambiz Chizari
  • Ovidiu Ersen
  • Spyridon Zafeiratos
  • Driss Soubane
  • Victor Da Costa
  • Virginie Speisser
  • Christine Boeglin
  • Matthieu Houllé
  • Dominique Bégin
  • Dominique Plee
  • Marc-Jacques Ledoux
  • Cuong Pham-Huu
Open Access
Research Article

Abstract

Few-layer graphene (FLG) sheets with sizes exceeding several micrometers have been synthesized by exfoliation of expanded graphite in aqueous solution of ammonia under microwave irradiation, with an overall yield approaching 8 wt.%. Transmission electron microscopy (in bright-field and dark-field modes) together with electron diffraction patterns and atomic force microscopy confirmed that this graphene material consisted mostly of mono-, bi- or few-layer graphene (less than ten layers). The high degree of surface reduction was confirmed by X-ray photoelectron and infrared spectroscopies. In addition, the high stability of the FLG in the liquid medium facilitates the deposition of the graphene material onto several substrates via low-cost solution-phase processing techniques, opening the way to subsequent applications of the material.

Keywords

Graphene transmission electron microscopy (TEM) expanded graphite exfoliation microwaves 

Supplementary material

12274_2010_1017_MOESM1_ESM.pdf (1.6 mb)
Supplementary material, approximately 340 KB.

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Copyright information

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  • Izabela Janowska
    • 1
  • Kambiz Chizari
    • 1
  • Ovidiu Ersen
    • 2
  • Spyridon Zafeiratos
    • 1
  • Driss Soubane
    • 1
  • Victor Da Costa
    • 2
  • Virginie Speisser
    • 2
  • Christine Boeglin
    • 2
  • Matthieu Houllé
    • 1
  • Dominique Bégin
    • 1
  • Dominique Plee
    • 3
  • Marc-Jacques Ledoux
    • 1
  • Cuong Pham-Huu
    • 1
  1. 1.Laboratoire des Matériaux, Surfaces et Procédés pour la Catalyse (LMSPC)UMR7515 CNRS-Université de Strasbourg 25Strasbourg Cedex 08France
  2. 2.Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS)UMR7504 CNRS-Université de Strasbourg 23Strasbourg Cedex 02France
  3. 3.Arkema, Groupement de Recherche de Lacq (GRL)LACQFrance

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