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Fibers and Polymers

, Volume 19, Issue 11, pp 2284–2289 | Cite as

Antibacterial Coating of Cellulose by Iso-bifunctional Reactive N-halamine with the Dyeing Process of Reactive Dye

  • Tong Mu
  • Nengyu Pan
  • Yingfeng Wang
  • Xuehong RenEmail author
  • Tung-Shi Huang
Article
  • 40 Downloads

Abstract

In this study, we synthesized a novel N-halamine precursor, sulfuric acid mono-[2-(4-[4-chloro-6-(2-[4,4- dimethyl-2,5-dioxo-imidazolidin-1-yl]-ethylamino)-[1,3,5]triazin-2-ylamino]-benzenesulfonyl)-ethyl] ester sodium (TB), which contains two reactive groups of monochloro triazine reactive groups and bis-sulphatoethylsolphone reactive groups. The structure of TB is similar to iso-bifunctional group reactive dyes and could be coated on cotton fabrics by covalent bonds through a reactive dyeing process. The cotton coated with TB was characterized by FTIR and SEM. After chlorination, the treated cotton fabrics showed excellent antibacterial efficacy and inactivated all inoculated S. aureus (ATCC 6538) and E. coli O157: H7 (ATCC 43895) within 1 min of contact. Over 85 % of tensile strength retained both in warp and weft directions after treatment and chlorination. Almost 80 % of active chlorine can be regained by treating with household bleach after extensive washing and long time storage.

Keywords

Iso-bifunctional group N-halamine Antibacterial Cellulose Dyeing process 

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References

  1. 1.
    D. Chmielewska and B. Sartowska, Radiat. Phys. Chem., 81, 1244 (2012).CrossRefGoogle Scholar
  2. 2.
    X. H. Ren, H. B. Kocer, S. D. Worley, R. M. Broughton, and T. S. Huang, Carbohydr. Polym., 75, 683 (2009).CrossRefGoogle Scholar
  3. 3.
    X. H. Ren, A. Akdag, H. B. Kocer, S. D. Worley, R. M. Broughton, and T. S. Huang, Carbohydr. Polym., 78, 220 (2009).CrossRefGoogle Scholar
  4. 4.
    J. Liang, K. Barnes, A. Akdag, S. D. Worley, J. Lee, R. M. Broughton, and T. S. Huang, Ind. Eng. Chem. Res., 46, 1861 (2007).CrossRefGoogle Scholar
  5. 5.
    I. Cerkez, H. B. Kocer, S. D. Worley, R. M. Broughton, and T. S. Huang, Langmuir, 27, 4091 (2011).CrossRefGoogle Scholar
  6. 6.
    Z. Q. Jie, X. F. Yan, L. H. Zhao, S. D. Worley, and J. Liang, React. Funct. Polymers, 73, 1580 (2013).CrossRefGoogle Scholar
  7. 7.
    H. B. Kocer, S. D. Worley, R. M. Broughton, and T. S. Huang, React. Func. Poly., 71, 561 (2011).CrossRefGoogle Scholar
  8. 8.
    I. Cerkez, S. D. Worley, R. M. Broughton, and T. S. Huang, React. Func. Poly., 73, 1412 (2013).CrossRefGoogle Scholar
  9. 9.
    T. C. Tsao, D. E. Williams, C. G. Worley, and S. D. Worley, Biotechnol. Progr., 7, 60 (1991).CrossRefGoogle Scholar
  10. 10.
    Z. M. Jiang, K. K. Ma, J. M. Du, R. Li, X. H. Ren, and T. S. Huang, Appl. Surf. Sci., 288, 518 (2014).CrossRefGoogle Scholar
  11. 11.
    Y. Gao and R. Cranston, Text. Res. J., 78, 60 (2008).CrossRefGoogle Scholar
  12. 12.
    Z. M. Jiang, B. Demir, R. M. Broughton, X. H. Ren, T. S. Huang, and S. D. Worley, J. Appl. Polym. Sci., 133 (2016).Google Scholar
  13. 13.
    Y. F. Wang, L. Li, Y. Liu, X. H. Ren, and J. Liang, Mat. Sci. Eng. C–Mater., 69, 1075 (2016).CrossRefGoogle Scholar
  14. 14.
    N. Y. Pan, Y. Liu, X. Y. Fan, Z. M. Jiang, X. H. Ren, and J. Liang, J. Mater. Sci., 52, 1996 (2017).CrossRefGoogle Scholar
  15. 15.
    S. D. Worley, Y. Chen, J. W. Wang, and R. Wu, Surf. Coat. Int. B–C., 88, 93 (2005).CrossRefGoogle Scholar
  16. 16.
    X. H. Ren, L. Kou, J. Liang, S. D. Worley, Y. M. Tzou, and T. S. Huang, Cellulose, 15, 593 (2008).CrossRefGoogle Scholar
  17. 17.
    G. Sun, T. Y. Chen, and S. D. Worley, Polymer, 37, 3753 (1996).CrossRefGoogle Scholar
  18. 18.
    G. Sun, L. C. Allen, E. P. Luckie, W. B. Wheatley, and S. D. Worley, Ind. Eng. Chem. Res., 34, 4106 (1995).CrossRefGoogle Scholar
  19. 19.
    Z. M. Jiang, Y. Liu, R. Li, X. H. Ren, and T. S. Huang, Polym. Adv. Technol., 27, 460 (2016).CrossRefGoogle Scholar
  20. 20.
    A. Akdag, S. Okur, M. L. McKee, and S. D. Worley, J. Chem. Theory Comput., 2, 879 (2006).CrossRefGoogle Scholar
  21. 21.
    Z. B. Cao and Y. Y. Sun, ACS Appl. Mater. Inter., 1, 494 (2009).CrossRefGoogle Scholar
  22. 22.
    M. Braun, W. Frank, and C. Ganter, J. Organomet. Chem., 696, 3580 (2011).CrossRefGoogle Scholar
  23. 23.
    F. Hamon, G. Prie, F. Lecornue, and S. Papot, Tetrahedron Lett., 50, 6800 (2009).CrossRefGoogle Scholar
  24. 24.
    J. Lee, R. M. Broughton, A. Akdag, S. D. Worley, and T. S. Huang, Fiber. Polym., 8, 148 (2007).CrossRefGoogle Scholar
  25. 25.
    T. K. Kim, S. H. Yoon, and Y. A. Son, Dyes Pigm., 60, 121 (2004).CrossRefGoogle Scholar
  26. 26.
    G. Sun, X. J. Xu, J. R. Bickett, and J. F. Williams, Ind. Eng. Chem. Res., 40, 1016 (2001).CrossRefGoogle Scholar
  27. 27.
    B. Zhang, Y. C. Jiao, Z. Z. Kang, K. K. Ma, X. H. Ren, and J. Liang, Cellulose, 20, 3067 (2013).CrossRefGoogle Scholar
  28. 28.
    C. M. Feng, Y. Zhang, S. W. Liu, Z. G. Chi, and J. R. Xu, J. Appl. Polym. Sci., 123, 3208 (2012).CrossRefGoogle Scholar

Copyright information

© The Korean Fiber Society, The Korea Science and Technology Center 2018

Authors and Affiliations

  • Tong Mu
    • 1
  • Nengyu Pan
    • 1
  • Yingfeng Wang
    • 1
  • Xuehong Ren
    • 1
    Email author
  • Tung-Shi Huang
    • 2
  1. 1.Key Laboratory of Eco-textiles of Ministry of Education, College of Textiles and ClothingJiangnan UniversityJiangsuChina
  2. 2.Department of Poultry ScienceAuburn UniversityAuburnUSA

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