Fibers and Polymers

, Volume 18, Issue 3, pp 434–444 | Cite as

Polyester modification through synthesis of copper nanoparticles in presence of triethanolamine optimized with response surface methodology

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Abstract

In this paper, polyester fabric was modified through synthesis and fabrication of Cu/Cu2O nanoparticles using a facile and cost-effective method at boil by chemical reduction through exhaustion route. Triethanolamine (TEA) was used for aminolysis of polyester fabric and pH adjusting, copper sulfate (CuSO4) as metal salt, sodium hypophosphite (SHP) as reducing agent and polyvinylpyrrolidone (PVP) as stabilizer. A response surface methodology was also employed to optimize the reaction conditions and study the effects of SHP, PVP and TEA concentrations in the processing. The images of field-emission scanning electron microscopy (FESEM), the patterns of energy-dispersive spectroscopy (EDX) and X-ray diffraction (XRD) patterns confirmed successfully synthesis of Cu and Cu2O nanoparticles on the polyester fabric. Further, the thermal behavior of the untreated and treated fabrics was studied by using thermogravimetric analysis (TGA) and differential scanning colorimetry (DSC). The treated fabrics indicated good properties regarding wettability and flame-retardant along with high tensile strength.

Keywords

Copper nanoparticles Polyester fabric Triethanolamine Response surface methodology Flame-retardant 
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References

  1. 1.
    B. Khodashenas and H. R. Ghorbani, Korean J. Chem. Eng., 31, 1105 (2014).CrossRefGoogle Scholar
  2. 2.
    M. N. K. Chowdhury, M. D. H. Beg, M. R. Khan, and M. F. Mina, Mater. Lett., 98, 26 (2013).CrossRefGoogle Scholar
  3. 3.
    X. Zhang, J. Song, J. Jiao, and X. Mei, Solid State Sci., 12, 1215 (2010).CrossRefGoogle Scholar
  4. 4.
    R. H. Guo, S. X. Jiang, C. W. M. Yuen, M. C. F. Ng, J. W. Lan, Y. L. Yeung, and S. J. Lin, Fiber. Polym., 14, 752 (2013).CrossRefGoogle Scholar
  5. 5.
    Z. Komeily-Nia, M. Montazer, and M. Latifi, Colloid Surf. A-Physicochem. Eng. Asp., 439, 167 (2013).CrossRefGoogle Scholar
  6. 6.
    N. A. Dhas, C. P. Raj, and A. Gedanken, Chem. Mater., 10, 1446 (1998).CrossRefGoogle Scholar
  7. 7.
    H. H. Huang, F. Q. Yan, Y. M. Kek, C. H. Chew, G. Q. Xu, W. Ji, P. S. Oh, and S. H. Tang, Langmuir, 13, 172 (1997).CrossRefGoogle Scholar
  8. 8.
    N. Cioffi, L. Torsi, N. Ditaranto, G. Tantillo, L. Ghibelli, L. Sabbatini, T. Bleve-Zacheo, M. D'Alessio, P. G. Zambonin, and E. Traversa, Chem. Mater., 17, 5255 (2005).CrossRefGoogle Scholar
  9. 9.
    S. H. Wu and D. H. Chen, J. Colloid Interface Sci., 273, 165 (2004).CrossRefGoogle Scholar
  10. 10.
    R. Zhou, X. Wu, X. Hao, F. Zhou, H. Li, and W. Rao, Nucl. Instrum. Methods Phys. Res., Sect. B, 266, 599 (2008).CrossRefGoogle Scholar
  11. 11.
    I. Capek, Adv. Colloid Interface Sci., 110, 49 (2004).CrossRefGoogle Scholar
  12. 12.
    L. M. Liz-Marzán, Mater. Today, 7, 26 (2004).CrossRefGoogle Scholar
  13. 13.
    M. Salavati-Niasari and F. Davar, Mater. Lett., 63, 441 (2009).CrossRefGoogle Scholar
  14. 14.
    X. Ge, H. Hu, C. Deng, Q. Zheng, M. Wang, and G. Chen, Mater. Lett., 141, 214 (2015).CrossRefGoogle Scholar
  15. 15.
    A. Sedighi, M. Montazer, and N. Samadi, Carbohydr. Polym., 110, 489 (2014).CrossRefGoogle Scholar
  16. 16.
    W. Qin and R. Guo, Fiber. Polym., 16, 1671 (2015).CrossRefGoogle Scholar
  17. 17.
    K. Cheirmadurai, S. Biswas, R. Murali, and P. Thanikaivelan, RSC Adv., 4, 19507 (2014).CrossRefGoogle Scholar
  18. 18.
    M. Montazer, M. Dastjerdi, M. Azdaloo, and M. M. Rad, Cellulose, 22, 4049 (2015).CrossRefGoogle Scholar
  19. 19.
    D. Lai, T. Liu, G. Jiang, and W. Chen, J. Appl. Polym. Sci., 128, 1443 (2013).CrossRefGoogle Scholar
  20. 20.
    L. Bech, T. Meylheuc, B. Lepoittevin, and P. Roger, J. Polym. Sci., Part A: Polym. Chem., 45, 2172 (2007).CrossRefGoogle Scholar
  21. 21.
    T. Harifi and M. Montazer, J. Mater. Chem. B, 2, 272 (2014).CrossRefGoogle Scholar
  22. 22.
    T. Harifi and M. Montazer, Ind. Eng. Chem. Res., 53, 1119 (2014).CrossRefGoogle Scholar
  23. 23.
    N. Ibrahim, E. El-Zairy, M. El-Zairy, and H. Khalil, J. Ind. Text., 42, 269 (2013).CrossRefGoogle Scholar
  24. 24.
    K. N. Pandiyaraj, R. R. Deshmukh, R. Mahendiran, P.-G. Su, E. Yassitepe, I. Shah, S. Perni, P. Prokopovich, and M. N. Nadagouda, Mater. Sci. Eng., C, 36, 309 (2014).CrossRefGoogle Scholar
  25. 25.
    J. Dave, R. Kumar, and H. C. Srivastava, J. Appl. Polym. Sci., 33, 455 (1987).CrossRefGoogle Scholar
  26. 26.
    N. A. Ibrahim, B. Eid, M. Youssef, H. Ameen, and A. Salah, J. Ind. Text., 42, 353 (2013).CrossRefGoogle Scholar
  27. 27.
    N. A Ibrahim, E. El-Zairy, M. El-Zairy, and H. Khalil, AATCC Rev., 11, 52 (2011).Google Scholar
  28. 28.
    F. Chen, Q. Zhou, R. Bu, F. Yang, and W. Li, Fiber. Polym., 16, 1213 (2015).CrossRefGoogle Scholar
  29. 29.
    I. Shahidul and F. Mohammad, Ind. Eng. Chem. Res., 54, 3727 (2015).CrossRefGoogle Scholar
  30. 30.
    Y. Zhu, Z. Mao, and C. Gao, RSC Adv., 3, 2509 (2013).CrossRefGoogle Scholar
  31. 31.
    H. Poortavasoly, M. Montazer, and T. Harifi, Mater. Sci. Eng., C, 58, 495 (2016).CrossRefGoogle Scholar
  32. 32.
    H. Poortavasoly, M. Montazer, and T. Harifi, RSC Adv., 4, 46250 (2014).CrossRefGoogle Scholar
  33. 33.
    K. Fukatsu, J. Appl. Polym. Sci., 45, 2037 (1992).CrossRefGoogle Scholar
  34. 34.
    L. Azfarniam and M. Norouzi, Fiber. Polym., 17, 298 (2016).CrossRefGoogle Scholar
  35. 35.
    M. Montazer, F. Alimohammadi, A. Shamei, and M. K. Rahimi, Carbohydr. Polym., 87, 1706 (2012).CrossRefGoogle Scholar
  36. 36.
    S. Gaan and G. Sun, J. Anal. Appl. Pyrol., 84, 108 (2009).CrossRefGoogle Scholar
  37. 37.
    F. Lessan, M. Montazer, and M. Moghadam, Thermochim Acta., 520, 48 (2011).CrossRefGoogle Scholar
  38. 38.
    Y. Lee, J.-R. Choi, K. J. Lee, N. E. Stott, and D. Kim, Nanotechnology, 19, 415604 (2008).CrossRefGoogle Scholar
  39. 39.
    S. A. Holmes, J. Appl. Polym. Sci., 61, 255 (1996).CrossRefGoogle Scholar
  40. 40.
    C. E. Hoppe, M. Lazzari, I. Pardiñas-Blanco, and M. A. López-Quintela, Langmuir, 22, 7027 (2006).CrossRefGoogle Scholar

Copyright information

© The Korean Fiber Society and Springer Science+Business Media Dordrecht 2017

Authors and Affiliations

  1. 1.Department of Textile Engineering, Amirkabir University of TechnologyFunctional Fibrous Structures & Environmental Enhancement (FFSEE)TehranIran

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