Fibers and Polymers

, Volume 16, Issue 8, pp 1803–1811 | Cite as

Polymer based fabrics as transducers in ammonia & ethanol gas sensing

Article

Abstract

Chemically synthesized Intrinsically conductive Polymers (ICP’s), mainly Polypyrrole (PPy) and Polyaniline, coated cotton fabrics has been utilized as transducers in ammonia and ethanol sensing in broad range of concentrations. The response, in terms of decrease or increase in dc current on exposure to ammonia, ethanol and moisture is observed. It is found that, PPy coated fabric shows exactly opposite responses to each other when used for ammonia (decrease in current) and ethanol gas (increase in current) detection. Its response and recovery rate toward ethanol gas is higher as compared to ammonia gas. PANi coated fabric shows effective sensing towards ethanol vapor and less response towards ammonia sensing. The effect of variation in monomer concentrations and use of different sulphonic acid dopants on sensing mechanism of PPy and PANi coated cotton is studied towards one fixed concentration of ammonia and ethanol gas. Threshold concentration for ammonia and ethanol detection by PPy and PANi coated fabric is studied. Rate of change of conduction with time is analyzed for both PPy and PANi coated fabrics for deciding the selectivity of gas.

Keywords

Chemical polymerization Intrinsically conducting polymers Transducers Dopants 

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References

  1. 1.
    A. Harlin in “Intelligent Textiles and Clothing” (H. R. Mattilla Ed.), pp.17–237, Woodhead Publishing Limited, England, 2006.Google Scholar
  2. 2.
    S. Sadki, P. Schottland, N. Brodie, and C. Sabouraced, Chem. Soc. Rev., 29, 283 (2000).CrossRefGoogle Scholar
  3. 3.
    L. X. Wang, X. G. Li, and Y. L. Yang, React. Funct. Polym., 47, 125 (2001).CrossRefGoogle Scholar
  4. 4.
    N. V. Bhat, D. T. Seshadri, M. M. Nate, and A. V. Gore, J. Appl. Polym. Sci., 102, 4690 (2006).CrossRefGoogle Scholar
  5. 5.
    H. H. Kuhn, A. D. Child, and W. C. Kimbrell, Synth. Met., 71, 2139 (1995).CrossRefGoogle Scholar
  6. 6.
    A. Varesano and C. Tonin, Text. Res. J., 78, 1110 (2008).CrossRefGoogle Scholar
  7. 7.
    L. Ruangchuay, A. Sirivat, and J. Schwank, Synth. Met., 140, 15 (2004).CrossRefGoogle Scholar
  8. 8.
    V. V. Chabukswar, S. Pethkar, and A. A. Athawale, Sens. Actuator B-Chem., 77, 657 (2001).CrossRefGoogle Scholar
  9. 9.
    H. K. Chitte, N. V. Bhat, V. E. Walunj, and G. N. Shinde, J. Sens. Technol., 1, 47 (2011).CrossRefGoogle Scholar
  10. 10.
    H. J. Kharat, K. P. Kakde, P. A. Savle, K. Datta, P. Ghosh, and M. D. Shrisat, Polym. Adv. Technol., 18, 397 (2007).CrossRefGoogle Scholar
  11. 11.
    G. G. Wallace, G. M. Spinks, L. A. P. Kane-Maguire, and P. R. Teasdole, “Conductive Electro active Polymers”, 2nd ed., pp.1–17, CRC Press, New York, USA, 2003.Google Scholar
  12. 12.
    J. Y. Lec, S. H. Cho, and K. T. Song, “Handbook of Conductive Polymers”, 3rd ed., pp.8–12, CRC Press, New York, 2007.Google Scholar
  13. 13.
    A. J. Patil and S. C. Deogaonkar, J. Appl. Polym. Sci., 125, 844 (2012).CrossRefGoogle Scholar
  14. 14.
    A. J. Patil and A. K. Pandey, Ind. J. Fibre Text. R, 37, 107 (2012).Google Scholar
  15. 15.
    A. J. Patil and S. C. Deogaonkar, Text. Res. J., 82, 1517 (2012).CrossRefGoogle Scholar
  16. 16.
    D. Y. Kim, J. B. Yu, C. B. Lim, H. G. Byun, D. D. Lee, and J. S. Huh, “IEEE Sensors 2006”, pp.51–254, IEEE Conference Publications, Daegu, 2006.Google Scholar
  17. 17.
    H. Bai and G. Shi, Sensors, 7, 267 (2007).CrossRefGoogle Scholar
  18. 18.
    G. Anitha and E. Subramanian, Sens. Actuator B-Chem., 107, 605 (2005).CrossRefGoogle Scholar
  19. 19.
    H. Bai, L. Zhao, C. Lu, and G. Shi, Polymer, 50, 3292 (2009).CrossRefGoogle Scholar
  20. 20.
    T. Kim and D. Kwak, Fiber. Polym., 13, 471 (2012).CrossRefGoogle Scholar
  21. 21.
    S. A. Wagule, S. M. Yenorkar, S. S. Yawale, and S. P. Yawale, “Sensors & Transducers”, pp.180–1185, International Frequency Sensor Association Publication, USA, 2007.Google Scholar
  22. 22.
    R. Turcu, M. Brie, G. Leising, V. Tosa, A. Mihut, A. Niko, and A. Bot, Appl. Phys. A, 67, 283 (1998).CrossRefGoogle Scholar
  23. 23.
    S. A. Ibrahim, N. A. Rahman, M. H. Abu Bakar, S. H. Girei, M. H. Yaacob, H. Ahmad, and M. A. Mahdi, Opt. Express, 23, 2837 (2015).CrossRefGoogle Scholar
  24. 24.
    N. Muthukumar, G. Thialgarathi, and T. Kannain, High Perform. Polym., 27, 105 (2015).CrossRefGoogle Scholar

Copyright information

© The Korean Fiber Society and Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  1. 1.Conductive Textiles LaboratoryBombay Textile Research AssociationMumbaiIndia

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