Skip to main content
Log in

Reduction of heavy metals and organic materials by atomized slag barrier in contaminated groundwater

  • Environmental Engineering
  • Published:
KSCE Journal of Civil Engineering Aims and scope

Abstract

Atomized slag is a residual waste product of steel manufacturing. The use of atomized slag as a recycled material is widespread in Korea, especially for filter media, ceramic filters, coagulate, construction materials, abrasives, and desulfurizing agents. The absorptivity of atomized slag as a reactive media for a permeable reactive barrier to eliminate pollutants inflowing from landfills was investigated in this study. Physical tests were performed to analyze the engineering properties of the atomized slag. The absorptive performance of the atomized slag against heavy metals and organics was examined in batch and column tests. Pilot-scaled and field tests were performed and monitored to evaluate the absorptivity of the atomized slag in the permeable reactive barrier against heavy metals and organics. The pilot-scaled test results showed the removal efficiencies of more than 94.9% for organics and more than 99.9% for heavy metals passing into the atomized media. The field test results indicated that the removal efficiencies of the atomized slag applied in the permeable reactive barrier were measured to be from 82 to 85% for organics and from 90 to 95% for heavy metals. The implications of the results are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Dimitrova, S. V. and Mehanjiev, D. R. (2000). “Interaction of blastfurnace slag with heavy metal ions in water solutions.” Water Research, Vol. 34,Issue 6, pp. 1957–1961.

    Article  Google Scholar 

  • Garrels, R. M. and Mackenzie, F. T. (1971). Evolution of sedimentary rocks, Norton, New York.

    Google Scholar 

  • Guo, Q. and Blowes, D. W. (2009). “Biogeochemistry of two types of permeable reactive barriers, organic carbon and iron-bearing organic carbon for mine drainage treatment: Column experiments.” Journal of Contaminant Hydrology, Vol. 107,Issues 3–4, pp. 128–139.

    Article  Google Scholar 

  • Lindsay, M. J., Ptacek, C. J., Blowes, D. W., and Gould, W. D. (2008). “Zero-valent iron and organic carbon mixtures for remediation of acid mine drainage: batch experiments.” Appl. Geochem., Vol. 23, No. 8, pp. 2214–2225.

    Article  Google Scholar 

  • McBride, M. B. (1994). Environmental chemistry of soils, Oxford University Press, New York, pp. 122–127.

    Google Scholar 

  • Morrison, S. J., Metzler, D. R., and Dwyer, B. P. (2002). “Removal of As, Mn, Mo, Se, U, V and Zn from groundwater by zero-valent iron in a passive treatment cell: Reaction progress modelling.” Journal of Contaminant Hydrology, Vol. 56,Issues 1–2, pp. 96–116.

    Google Scholar 

  • O’Hannesin, S. F. and Gillham, R. W. (1998). “Long-term performance of an in situ iron wall for remediation of VOCs.” Ground Water, Vol. 36, No. 1, pp. 164–170.

    Article  Google Scholar 

  • Orth, W. S. and Gillham, R. W. (1996). “Dechlorination of trichloroethene in aqueous solution using Fe0.” Environmental Science Technology, Vol. 30, No. 1, pp. 66–71.

    Article  Google Scholar 

  • Park, D. H., Lim, S. R., Lee, H. W., and Park, J. M. (2008). “Mechanism and kinetics of Cr(VI) reduction by waste slag generated from iron making industry.” Hydrometallurgy, Vol. 93,Issues 1–2, pp. 72–75.

    Article  Google Scholar 

  • Roberts, A. L., Tottern, L. A., and Campbell, T. J. (1996). “Reductive elimination of chlorinated ethylenes by zero-valent iron metal.” Environmental Science & Technology, Vol. 30, No. 8, pp. 2654–2659.

    Article  Google Scholar 

  • Smith, J. V. (1953). “Reexamination of the crystal structure of melilite.” American Mineralogist, Vol. 38, No. 1, pp. 643–661.

    Google Scholar 

  • Stumm, W. and Sulzberger, B. (1992). “The cycling of iron in natural environments: Considerations based on laboratory studies of heterogeneous redox processes.” Geochimical et cosmochimica acta, Vol. 56, No. 8, pp. 3233–3257.

    Article  Google Scholar 

  • US EPA. (1998). Permeable reactive barrier technologies for contaminant remediation, Office of Research and Development, Washington, D.C., EPA/600/R-98/125, pp. 1–7.

    Google Scholar 

  • Wanaratna, P., Christodoulatos, C., and Sidhoum, M. (2006). “Kinetics of RDX degradation by Zero-Valent Iron (ZVI).” J. Hazard. Mater., Vol. 136,Issue 1, pp. 68–74.

    Article  Google Scholar 

  • Wilkin, R. T. and McNeil, M. S. (2003). “Laboratory evaluation of zerovalent iron to treat water impacted by acid drainage.” Chemosphere, Vol. 53, No. 7, pp. 715–725.

    Article  Google Scholar 

  • Wu, Y., Versteeg, R., Slater, L., and LaBrecque, D. (2009). “Calcite precipitation dominates the electrical signatures of zero valent iron columns under simulated field conditions.” Journal of Contaminant Hydrology, Vol. 106,Issues 3–4, pp. 131–143.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jae-Suk Ryou.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jung, HS., Park, JS., Lee, YJ. et al. Reduction of heavy metals and organic materials by atomized slag barrier in contaminated groundwater. KSCE J Civ Eng 17, 1578–1586 (2013). https://doi.org/10.1007/s12205-013-0104-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12205-013-0104-8

Keywords

Navigation