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Petroleum Science

, Volume 5, Issue 1, pp 67–72 | Cite as

Progress in studies of natural gas conversion in China

  • Changchun Yu
  • Shikong Shen
Article

Abstract

Progress in natural gas conversion in China is presented in this paper, including processes of natural gas to synthesis gas (syngas), syngas to liquid hydrocarbons, oxygenates synthesis, methanol to olefins (MTO), methane to aromatics and oxidative coupling of methane (OCM).

Key words

Methane natural gas conversion GTL synthesis gas hydrocarbons alcohols olefins methanol dimethyl ether 

References

  1. Ashcroft A T, Cheetham A K and Green M L H. Direct catalytic oxidation of methane to synthesis gas. Nature. 1990. 344: 319–320CrossRefGoogle Scholar
  2. Bakkerud P K, Gol J N, Aasberg-Petersen K, et al. Preferred synthesis gas production routes for GTL. Studies in Surface Science and Catalysis. 2004. 147: 13–17CrossRefGoogle Scholar
  3. Bone W A. Formation of methyl alcohol by direct oxidation of methane over molybdenum oxide supported on silica. Nature. 1931. 127: 481–482CrossRefGoogle Scholar
  4. Chen C M, Bennett D L and Carolan M F. ITM syngas ceramic membrane technology for synthesis gas production. Studies in Surface Science and Catalysis. 2004. 147: 55–60CrossRefGoogle Scholar
  5. Chen J G and Sun Y H. The structure and reactivity of coprecipitated Co-ZrO2 catalysts for Fischer-Tropsch synthesis. Studies in Surface Science and Catalysis. 2004. 147: 277–282CrossRefGoogle Scholar
  6. Eisenberg B, Fiato R A, Kaufman T G, et al. The Evolution of Advanced Gas-to-Liquids Technology. Chemtech. 1999. 29: 32–38Google Scholar
  7. Fleisch T H and Sills R A. Large-scale gas conversion through oxygenates: Beyond GTL-FT. Studies in Surface Science and Catalysis. 2004. 147: 31–36CrossRefGoogle Scholar
  8. Fould G A and Gray B F. Homogeneous gas-phase partial oxidation of methane to methanol and formaldehyde. Fuel Process Technology. 1995. 42: 129–159CrossRefGoogle Scholar
  9. Gradassi M J and Green N W. Economics of natural gas conversion processes. Fuel Process Technology. 1995. 42: 65–83CrossRefGoogle Scholar
  10. Hall T J, Hargreaves J S J and Hutchings G J. Direct oxidation of methane to methanol and formaldehyde. Fuel Process Technology. 1995. 42: 151–178CrossRefGoogle Scholar
  11. Hickman D A and Schmidt L D. Syngas formation by direct catalytic oxidation of methane. Science. 1993. 259: 342–346CrossRefGoogle Scholar
  12. Huang L Q, Yuan Y Z and Zhang H B. Dehydro-aromatization of CH4 over W-Mn(or Zn, Ga, Mo, Co)/HZSM-5(or MCM-22) catalysts. Studies in Surface Science and Catalysis. 2004. 147: 565–570CrossRefGoogle Scholar
  13. Ji S F, Xiao T C and Li S B. The critical role of the surface WO4 tetrahedron on the performance of Na-W-Mn/SiO2 catalysts for the oxidative coupling of methane. Studies in Surface Science and Catalysis. 2004. 147: 607–612CrossRefGoogle Scholar
  14. Kong F H and Wu G J. Present situation and suggestions of Petrochina’ s natural gas chemical engineering development. Chemical Engineering of Oil and Gas. 2004. 33(Supplement): 1–4Google Scholar
  15. Li C Y, Yu C C and Shen S K. Studies on the Reasons for Carbon Deposition over Ni/Al2O3 Catalyst in partial oxidation of CH4 to syngas with TPO technique. Chinese Journal of Catalysis. 2001. 22(4): 377–382Google Scholar
  16. Li R J, Yu C C, Shen S K, et al. Methane oxidation to synthesized gas using lattice oxygen in La1−xSrxFeO3 perovskite oxides instead of molecular oxygen. Studies in Surface Science and Catalysis. 2004. 147: 199–204CrossRefGoogle Scholar
  17. Li S B. Reaction chemistry of W-Mn/SiO2 catalyst for the oxidative coupling of methane. Journal of Natural Gas Chemistry. 2003. 12(1): 1–9Google Scholar
  18. Li Y G, Liu H M, Xu Y D, et al. Combined single-pass conversion of methane via oxidative coupling and dehydroaromatization: A combination of La2O3/BaO and Mo/HZSM-5 catalysts. Studies in Surface Science and Catalysis. 2004. 147: 583–588CrossRefGoogle Scholar
  19. Liu H F, Liu R S, Lunsford J H, et al. Partial oxidation of methane by nitrous oxide over molybdenum on silica. Journal of the American Chemical Society. 1984. 106: 4117–4121CrossRefGoogle Scholar
  20. Liu R S, Iwamoto M and Lunsford J H. Partial oxidation of methane by nitrous oxide over molybdenum on silica. Chemical Communications. 1982. 11: 78–79CrossRefGoogle Scholar
  21. Liu S L, Dong Q, Ohnishi R and Ichikawa M. Unique promotion effect of CO and CO2 on the catalytic stability for benzene and naphthalene production from methane on Mo/HZSM-5 catalysts. Chemical Communications. 1998. 11: 1217–1218CrossRefGoogle Scholar
  22. Liu Z M, Sun C L, Wang G W, et al. New progress in R&D of lower olefin synthesis. Fuel Process Technology. 2000. 62(2–3): 161–172CrossRefGoogle Scholar
  23. Lu Y, Liu Y and Shen S K. Design of stable Ni catalysts for partial oxidation of methane to syngas. Journal of Catalysis. 1998. 177: 368–388CrossRefGoogle Scholar
  24. Lunsford J H. Catalytic conversion of methane to more useful chemicals and fuels: A challenge for the 21st century. Catalysis Today. 2000. 63: 165–174CrossRefGoogle Scholar
  25. Mazanec T J, Prasad R, Odegard R, et al. Oxygen transport membranes for syngas production. Studies in Surface Science and Catalysis. 2001. 136: 147–152CrossRefGoogle Scholar
  26. Periana R A, Taube D J, Gamble S, et al. A novel, high yield system for oxidation of methane to methanol. Science. 1998. 280: 560–561CrossRefGoogle Scholar
  27. Qi H J, Li D B, Zhong B, et al. Performance of Mn-modified Ni/K/MoS2 catalysts for higher alcohol synthesis. Journal of Fuel Chemistry and Technology. 2003. 31(2): 119–123Google Scholar
  28. Shanxi Institute of Coal Chemistry of Chinese Academy of Sciences. A Methanol Synthesis Route. China Patent, CN 95115889.9. 2000Google Scholar
  29. Shen S K, Pan Z Y and Dong C Y. A novel two-stage process for catalytic oxidation of methane to synthesis gas. Studies in Surface Science and Catalysis. 2001. 136: 99–104CrossRefGoogle Scholar
  30. Shu Y Y and Ichikawa M. Catalytic dehydrocondensation of methane towards benzene and naphthalene on transition metal supported zeolite catalysts: Templating role of zeolite micropores and characterization of active metallic sites. Catalysis Today, 2001. 71: 55–67CrossRefGoogle Scholar
  31. Wang H H, You C and Yang W S. Investigation of partial oxidation of methane to syngas in a tubular Ba0.5Sr0.5Co0.8Fe0.2O3 membrane reactor. Catalysis Today. 2003. 82: 157–166CrossRefGoogle Scholar
  32. Wang H P. Advances in one-step synthesis of dimethyl ether from syngas. Chinese Industrial Catalysis. 2003. 11(5): 78–82Google Scholar
  33. Wang J F, Ren F, Wang D Z, et al. Research of DME synthesis in slurry reactor by one step process. Chemical Engineering of Oil and Gas. 2004. 33(Supplement): 42–43Google Scholar
  34. Wang L S, Tao L X, Xie M S, et al. Dehydrogenation and aromatization of methane under non-oxidizing conditions. Catalysis Letters. 1993. 21: 35–41CrossRefGoogle Scholar
  35. Wei W, Sun Y H and Zhong B. Applied fundamental research on supercritical fluids. Journal of Fuel Chemistry and Technology. 1999. 27(Supplement): 41–50Google Scholar
  36. Xie H J, Cui H T, Tan Y S, et al. Research of modified methanol catalyst using in dimethyl ether synthesis by slurry bed reactor. Chemical Engineering of Oil and Gas. 2004. 33(Supplement): 44–46Google Scholar
  37. Xu X M, Xu H Y, Wang S W, et al. Research of the catalyst used to synthesize dimethyl ether by one-step process. Chemical Engineering of Oil and Gas. 2004a. 33(Supplement): 58–60Google Scholar
  38. Xu X, Fua G, Periana R A, et al. Selective oxidation of CH4 to CH3OH using the catalytic (bpym)PtCl2 Catalyst. Studies in Surface Science and Catalysis. 2004b. 147: 499–504CrossRefGoogle Scholar
  39. Xu Y D, Bao X H and Lin L W. Direct conversion of methane under nonoxidative conditions. Journal of Catalysis. 2003. 216: 386–395CrossRefGoogle Scholar
  40. Yang Y L, Li W Z and Xu H Y. Influence of CeO2 and Co3O4 promoters on carbon deposition and carbon elimination over Ni-based catalysts, Chinese Journal of Catalysis. 2002. 23(5): 517–520Google Scholar
  41. Yarlagadda P S, Morton L, Hnuter N R, et al. Direct conversion of methane to methanol in a flow reactor. Industrial and Engineering Chemistry Research. 1988. 27: 252–256CrossRefGoogle Scholar
  42. Yin H M. Investigation of CO hydrogenation on Rh-based catalysts for the synthesis of C2-oxygenates. PhD Thesis. Dalian Institute of Chemical Physics of Chinese Academy of Sciences. 2003Google Scholar
  43. Yin H M, Ding Y J and Luo H Y. Influence of iron promoter on catalytic properties of Rh-Mn-Li/SiO2 for CO hydrogenation. Applied Catalysis A. 2003a. 243: 155–164CrossRefGoogle Scholar
  44. Yin H M, Ding Y J, Luo H Y, et al. The performance of C2 oxygenates synthesis from syngas over Rh-Mn-Li-Fe/SiO2 catalysts with various Rh loadings. Energy Fuels. 2003b. 17(6): 1401–1406CrossRefGoogle Scholar
  45. Zhang X, He D H, Zhang Q J, et al. Methanol from oxidation of methane over MoOx/La-Co-oxide catalysts. Studies in Surface Science and Catalysis. 2004. 147: 541–546CrossRefGoogle Scholar
  46. Zhang Z B, Yu C C and Shen S K. Partial oxidation of CH4 to syngas on La2O3 promoted Ni/MgAl2O4. Chinese Journal of Catalysis. 2000. 21(1): 14–18(in Chinese)Google Scholar

Copyright information

© China University of Petroleum 2008

Authors and Affiliations

  1. 1.Key Laboratory of Catalysis under CNPCChina University of PetroleumBeijingChina

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