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Food Analytical Methods

, Volume 12, Issue 12, pp 2730–2741 | Cite as

Development of an Efficient Sample Preparation Method Based on Homogeneous Liquid-Liquid Extraction Combined with Dispersive Liquid-Liquid Microextraction Solidification of Floating Organic Drop for Trace Analysis of Pesticide Residues in Fruit and Fruit Juice Samples

  • Mir Ali FarajzadehEmail author
  • Ali Sadeghi Alavian
  • Masoumeh Sattari Dabbagh
Article

Abstract

In this study, a simple and reliable sample preparation method based on an efficient version of homogeneous liquid-liquid extraction combined with dispersive liquid-liquid microextraction solidification of floating organic drop has been introduced to analyze some pesticide residues in fruit and fruit juice samples with gas chromatography-flame ionization detection. Under the optimum experimental conditions, limits of detection and quantification were in the ranges of 0.20–0.60 and 0.66–2.0 μg L−1, respectively. The repeatability of the method was good and the relative standard deviations were less than 7 % for intra- (n = 6) and inter-day (n = 4) precisions at a concentration of 50 μg L−1 of each analyte. High enrichment factors (3265–3728) and extraction recoveries (82–93 %) were obtained. Finally, the method was applied for determination of pesticides in the selected samples and chlorpyrifos was found in strawberry at ng g−1 concentration. Furthermore, no filtration was used in the cases of the fruit samples.

Keywords

Homogeneous liquid-liquid microextraction Dispersive liquid-liquid microextraction based on solidification of floating organic drop Pesticide Gas chromatography Fruit and fruit juices 

Abbreviations

DLLME

Dispersive liquid-liquid microextraction

EF

Enrichment factor

ER

Extraction recovery

FID

Flame ionization detection

GC

Gas chromatography

HLLE

Homogeneous liquid-liquid extraction

LLE

Liquid-liquid extraction

LOD

Limit of detection

LPME

Liquid-phase microextraction

LOQ

Limit of quantification

MS

Mass spectrometry

RSD

Relative standard deviation

SFO

Solidification of floating organic drop

SPE

Solid-phase extraction

Notes

Acknowledgments

The financial support from University of Tabriz is acknowledged.

Funding

Mir Ali Farajzadeh has received research grants from University of Tabriz.

Compliance with Ethical Standards

Conflict of Interest

Mir Ali Farajzadeh declares that he has no conflict of interest. Ali Sadeghi Alavian declares that he has no conflict of interest. Masoumeh Sattari Dabbagh declares that she has no conflict of interest.

Ethical Approval

This article does not contain any studies with human or animals.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Analytical Chemistry, Faculty of ChemistryUniversity of TabrizTabrizIran
  2. 2.Engineering FacultyNear East UniversityNicosiaTurkey

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