Food Analytical Methods

, Volume 6, Issue 3, pp 900–905 | Cite as

Sesquiterpene Fingerprinting by Headspace SPME–GC–MS: Preliminary Study for a Simple and Powerful Analytical Tool for Traceability of Olive Oils

Article

Abstract

Solid-phase microextraction combined with gas chromatography–mass spectrometry is employed to characterise the head space composition of extra virgin olive oil with particular emphasis on some sesquiterpenes useful for oil classification. It is demonstrated that α-muurolene and α-farnesene contents (normalised to α-copaene), besides discriminating between Apulian and foreign oils, is even capable of differentiating between different sub-brands of Terra di Bari (protected denomination of origin) oils, produced in neighbouring, very restricted areas of the Apulian region.

Keywords

SPME GC–MS Sesquiterpenes Olive oils 

References

  1. Montealegre C, Alegre MLM, Garcia-Ruiz C (2010) J Agric Food Chem 58:28CrossRefGoogle Scholar
  2. Council Regulation (EEC) (1992) Council Regulation (EEC) No. 2081/92 of 14 July 1992 on the protection of geographical indications and designations of origin for agricultural products and foodstuffs. Off J Eur Union L 208:1–8Google Scholar
  3. Council Regulation (EEC) (2006) Council Regulation (EC) No. 510/2006 of 20 March 2006 on the protection of geographical indications and designations of origin for agricultural products and foodstuffs. Off J Eur Union L 93:12–25Google Scholar
  4. Council Regulation (EEC) (2002) Commission Regulation (EC) No. 1019/2002 of 13 June 2002 on marketing standards for olive oil. Off J Eur Communities L 155:27–31Google Scholar
  5. Sacco A, Brescia MA, Liuzzi V, Reniero F, Guillou C, Ghelli S, van der Meer P (2000) J Am Oil Chem Soc 77:619CrossRefGoogle Scholar
  6. Gazzetta Ufficiale della Repubblica Italiana (1998) Decreto of 4 September 1998 on annessione al disciplinare di produzione della denominazione di origine controllata dell'olio extravergine di oliva Terra di Bari 227:13–15Google Scholar
  7. Araghipour N, Colineau J, Koot A, Akkermans W, Moreno Rojas JM, Beauchamp J, Wisthaler A, Märk TD, Downey G, Guillou C, Mannina L, van Ruth S (2008) Food Chem 108:374CrossRefGoogle Scholar
  8. Lorenzo M, Pérez Pavón JL, Fernández Laespada ME, Pinto CG, Corsero BM (2001) J Chromatogr A 945:221Google Scholar
  9. Dhifi W, Angerosa F, Serraiocco A, Oumar I, Hamrouni I, Marzouk B (2005) Food Chem 93:697CrossRefGoogle Scholar
  10. Runcio A, Sorgonà L, Mincione A, Santacaterina S, Poiana M (2008) Food Chem 106:735CrossRefGoogle Scholar
  11. Tura D, Prenzler PD, Bedgood DR Jr, Antolovich M, Robards K (2004) Food Chem 84:341CrossRefGoogle Scholar
  12. Angerosa F, Servili M, Selvaggini R, Taticchi A, Esposto S, Montedoro GF (2004) J Chromatogr A 1054:17Google Scholar
  13. Angerosa F, Mostallino R, Basti C, Vito R (2001) Food Chem 72:19CrossRefGoogle Scholar
  14. Degenhardt J, Köllner T, Gershenzon J (2009) Phytochem 70:1621CrossRefGoogle Scholar
  15. Kant MR, Ament K, Sabelis MW, Haring MA, Schuurink RC (2004) Plant Physiol 135:483CrossRefGoogle Scholar
  16. Koprivnjak O, Moret S, Populin T, Lagazio C, Conte LS (2005) Food Chem 90:603CrossRefGoogle Scholar
  17. Ben Temime S, Campeol E, Cioni PL, Daoud D, Zarrouk M (2006) Food Chem 99:315CrossRefGoogle Scholar
  18. Zunin P, Boggia R, Lanteri S, Leardi R, De Andreis R, Evangelisti F (2004) J Chromatogr A 1023:271CrossRefGoogle Scholar
  19. Bortolomeazzi R, Berno P, Pizzale L, Conte LS (2001) J Agric Food Chem 49:3278CrossRefGoogle Scholar
  20. Zunin P, Boggia R, Salvadeo P, Evangelisti F (2005) J Chromatogr A 1089:243CrossRefGoogle Scholar
  21. Vichi S, Guadayol JM, Caixach J, López-Tamames E, Buxaderas S (2006) J Chromatogr A 1125:117CrossRefGoogle Scholar
  22. Guinda A, Lanzón A, Albi T (1996) J Agric Food Chem 44:1723CrossRefGoogle Scholar
  23. Pawlinzyn J (1999) Application of solid phase microextraction. MPG Book Ltd, BodminCrossRefGoogle Scholar
  24. Lanzón A, Albi T, Cert A, Gracián J (1994) J Am Oil Chem Soc 71:285CrossRefGoogle Scholar
  25. Vichi S, Lazzez A, Grati Kamoun N, Lopez-Tamames E, Buxaderas S (2010) J Agric Food Chem 58:6972CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  1. 1.Dipartimento di ChimicaUniversità degli Studi di Bari “Aldo Moro”BariItaly
  2. 2.Istituto di Scienze delle Produzioni Alimentari (ISPA)Consiglio Nazionale delle RicercheBariItaly

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